2,4,6-Trimethoxy-1,3,5,2,4,6-Trioxatriborinane 2,4,6-三甲氧基硼氧六环

CAS 102-24-9 MFCD00005946

化学结构图

102-24-9
SMILES: COB1OB(OC)OB(OC)O1

化学属性

Mol. FormulaC3H9B3O6
Mol. Weight173.53 g/mol
Density1.195 g/mL at 25 °C(lit.)
Flash Point9°C(lit.)
TSCAYes
Boiling Point130 °C(lit.)
Melting Point10 °C(lit.)
Refractive index1.3980 to 1.4020
Vapor Pressure30 mmHg ( 25 °C)
Solubility起反应

别名和识别编码

Chemical Name2,4,6-Trimethoxy-1,3,5,2,4,6-Trioxatriborinane
MDL NumberMFCD00005946
CAS Number102-24-9
Synonym 2,4,6-TRIMETHOXYBOROXIN 2,4,6-Trimethoxy-1,3,5,2,4,6-trioxatriborinane 2,4,6-Trimethoxy-1,3,5-trioxa-2,4,6-triboracyclohexane 2,4,6-Trimethoxy-cyclotriboroxane 2,4,6-Trimethoxyboroxin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number203-016-8
Beilstein Registry Number1709158
PubChem Substance ID87577338
Reaxys-RN1709158
Chemical Name Translation2,4,6-三甲氧基硼氧六环
InChIKeyZFMOJHVRFMOIGF-UHFFFAOYSA-N
Wiswesser Line NotationT6BOBOBOJ AO1 CO1 EO1
LabNetwork Molecule IDLN01746658
InChIInChI=1S/C3H9B3O6/c1-7-4-10-5(8-2)12-6(9-3)11-4/h1-3H3
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分类

  • {SNA} Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Others
  • {SNA} Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Other Boronic Acids and Derivatives
  • {uni_hamburg} no charge; oxygen heterocycle; other heterocycle; alicycle; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: III/20a
  • Short: III/35A
  • Short: III/35E
  • {} {

安全信息

RTECSED8720000
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
Packing GroupII
UN Number UN2924 2924 UN 2924 3/PG 2
Risk Statements
  • R11 Highly flammable 非常易燃
  • R34 Causes burns 会导致灼伤
  • R38 Irritating to skin 刺激皮肤
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Storage condition Flammables area Air & Moisture Sensitive
WGK Germany2
Hazard Codes F,C F;Xi F,C,Xi
GHS Symbol
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P303+P361+P353+P310+P363
  • P403+P235
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P304+P340
  • P303+P361+P353
  • P405 Store locked up. 上锁保管。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
  • P301+P330+P331+P310
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Hazard Class3/8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5160 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

其他信息

  • 蒸气压:30 mm Hg ( 25 °C)
  • 外观性质:无色液体,易分解。
  • 三甲氧基环硼氧烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1581 2,4,6-三甲氧基环硼氧烷 2,4,6-Trimethoxyboroxin 100G 467元 2014/06/02 T1581 2,4,6-三甲氧基环硼氧烷 2,4,6-Trimethoxyboroxin 25G 189元 2010/06/21 139960250 三甲氧基环硼氧烷 Trimethoxyboroxine 25 GR 158元
  • MSDS 信息:三甲氧基硼氧烷(102-24-9).msds
  • MOL 文件:102-24-9.mol
  • 图谱信息:三甲氧基环硼氧烷(102-24-9)核磁图( 13 CNMR) 三甲氧基环硼氧烷(102-24-9)质谱(MS) 三甲氧基环硼氧烷(102-24-9)核磁图( 1 HNMR) 三甲氧基环硼氧烷(102-24-9)红外图谱(IR1)
  • TCI Shanghai:2,4,6-三甲氧基环硼氧烷 2,4,6-Trimethoxyboroxin,>;95.0%(T)(102-24-9)
  • Acros Organics:Trimethoxyboroxine(102-24-9)
  • Alfa Aesar:Trimethoxyboroxine, 95%(102-24-9)
  • F:10-21
  • Sigma Aldrich:102-24-9(sigmaaldrich)

系列性分类


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