1-Phenylpiperazine N-苯基哌嗪

CAS 92-54-6 MFCD00005957

化学结构图

92-54-6
SMILES: c1ccc(N2CCNCC2)cc1

化学属性

Mol. FormulaC10H14N2
Mol. Weight162.23
Refractive index1.5880 to 1.5900
Boiling Point286°C at 760 mmHg
Density1.062
Flash Point140°C
TSCAYes
Melting Point17-19 °C
Appearance 浅黄色液体。
SolubilityInsoluble

别名和识别编码

Chemical Name1-Phenylpiperazine
CAS Number92-54-6
Alfabeta NamePHENYLPIPERAZINE 1-
MDL NumberMFCD00005957
Synonym Phenylpiperazine {LY} Phenylpiperazine {} {LY} Phenylpiperazine {} {} {LY} Phenylpiperazine {} {} {} {LY} Phenylpiperazine {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylpiperazine {} {} {} {} {} {} {} {} {}
PubChem Substance ID87575094
EC Number202-165-6
Beilstein Registry Number132157
Chemical Name TranslationN-苯基哌嗪
Reaxys-RN132157
Wiswesser Line NotationT6M DNTJ DR
LabNetwork Molecule IDLN00174129
Canonical SMILESC1(N2CCNCC2)=CC=CC=C1
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分类

  • {SNA} Bioactive Small Molecules, Building Blocks, C10, Chemical Synthesis, Heterocyclic Building Blocks, P, Piperazines, 细胞生物学
  • {SNA} Analytical Standards, EP Standards, EP Standards L - M, Pharmacopeia & Metrological Institutes Standards, 分析/色谱
  • {SNA} Analytical Standards,
  • {SNA} Analytical Standards, Chromatography, EP Standards,
  • {SNA} Bioactive Small Molecules, Building Blocks, C10, Cell Biology,
  • Bioactive Small Molecules, Building Blocks, C10, Cell Biology, Chemical Synthesis, Heterocyclic Building Blocks, P, Piperazines
  • {SN

相关文献及参考

  • Beilstein: 23,V,1,160

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes 8 T T,C T,Xi
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTM2625000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupII
UN Number 2922 3267
Hazard Class8/6.1
Storage condition 2-8°C {LY} 2-8°C Store in dark! {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 210 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JACSAT Journal of the American Chemical Society.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1879-  Volume(issue)/page/year: 76,5091,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 140 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : Micronucleus test
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 900 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 282,99,1992

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 41 ug/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 282,99,1992

其他信息

  • N-苯基哌嗪价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0980 1-苯基哌嗪 1-Phenylpiperazine 25G 366元 2014/06/02 P0980 1-苯基哌嗪 1-Phenylpiperazine 250G 1820元 2010/06/21 130821000 N-苯基哌嗪 1-Phenylpiperazine 97% 100 GR 1036元
  • MOL 文件:771-99-3.mol
  • Sigma Aldrich:92-54-6(sigmaaldrich)
  • 用途一:左羟丙哌嗪的中间体
  • 下游产品:羟丙哌嗪
  • Hazard Note:Irritant
  • F:10
  • MOL 文件:92-54-6.mol
  • 检测方法:GC,NMR
  • Acros Organics:4-苯基哌啶 4-Phenylpiperidine, 98%(771-99-3)
  • 海关编码:29335995
  • 检测方法:GC
  • Alfa Aesar:1-苯基哌嗪,98+% 1-Phenylpiperazine, 98+%(92-54-6)
  • 4-苯基哌啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 164770010 4-苯基哌啶 4-Phenylpiperidine 98% 1 GR 638元 2010/06/21 164770050 4-苯基哌啶 4-Phenylpiperidine 98% 5 GR 1538元
  • Hazard Note:Toxic/Corrosive
  • TCI Shanghai:1-苯基哌嗪 1-Phenylpiperazine,>;98.0%(GC)(92-54-6)
  • 上游原料:氧氯化硫 --> 甲苯 --> 氢氧化钾 --> 氨基钠 --> 苯乙炔 --> 二异辛胺
  • MSDS 信息:4-Phenylpiperidine(771-99-3).msds
  • 下游产品:
  • 图谱信息:4-苯基哌啶(771-99-3)核磁图( 13 CNMR) 4-苯基哌啶(771-99-3)红外图谱(IR2) 4-苯基哌啶(771-99-3)红外图谱(IR1) 4-苯基哌啶(771-99-3)质谱(MS) 4-苯基哌啶(771-99-3)核磁图( 1 HNMR)
  • 图谱信息:N-苯基哌嗪(92-54-6)Raman光谱 N-苯基哌嗪(92-54-6)核磁图( 13 CNMR) N-苯基哌嗪(92-54-6)红外图谱(IR1) N-苯基哌嗪(92-54-6)核磁图( 1 HNMR) N-苯基哌嗪(92-54-6)质谱(MS)
  • Acros Organics:N-苯基哌嗪 1-Phenylpiperazine, 97%(92-54-6)
  • MSDS 信息:1-Phenylpiperazine(92-54-6).msds
  • Sigma Aldrich:771-99-3(sigmaaldrich)

系列性分类


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