2,2,6,6-Tetramethyl-4-Oxopiperidine 2,2,6,6-四甲基-4-哌啶酮

CAS 826-36-8 MFCD00005975

化学结构图

826-36-8
SMILES: CC1(C)CC(=O)CC(C)(C)N1

化学属性

Mol. FormulaC9H17NO
Mol. Weight155.24
Boiling Point102-105°C at 760 mmHg
Melting Point34-38°C
Flash Point73°C
Appearance 白色或淡黄色粉末，熔点43℃，沸点205℃，能溶于丙酮，醇，醚和水。
pH:A

别名和识别编码

Chemical Name2,2,6,6-Tetramethyl-4-Oxopiperidine
CAS Number826-36-8
Synonym Triacetonamine {LY} Triacetonamine {} {LY} Triacetonamine {} {} {LY} Triacetonamine {} {} {} {LY} Triacetonamine {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetonamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00005975
PubChem Substance ID13220
EC Number212-554-2
Chemical Name Translation2,2,6,6-四甲基-4-哌啶酮
Wiswesser Line NotationT6N DVTJ B1 B1 F1 F1
Beilstein Registry Number0112665
LabNetwork Molecule IDLN00222518
InChIInChI=1S/C9H17NO/c1-8(2)5-7(11)6-9(3,4)10-8/h10H,5-6H2,1-4H3
Canonical SMILESO=C1CC(C)(C)NC(C)(C)C1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Piperidones
  • {uni_hamburg} no charge; nitrogen heterocycle; alicycle; 6RingOnly; 6ring; ketone; 1fragment
  • Heterocycles
  • Miscellaneous Reagents

相关文献及参考

  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

WGK Germany2
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
RTECSTO0127900
Signal word
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn C,Xn
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Refrigerator (+4°C) {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 385 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   APPFAR Acta Poloniae Pharmaceutica (English Translation).  Translation of
   APPHAX.  (Warsaw, Poland) V.20-29, 1963-72.  Discontinued.
   Volume(issue)/page/year: 24,652,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   APPFAR Acta Poloniae Pharmaceutica (English Translation).  Translation of
   APPHAX.  (Warsaw, Poland) V.20-29, 1963-72.  Discontinued.
   Volume(issue)/page/year: 24,652,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1539 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 28(5),53,1984

其他信息

  • 三丙酮胺:三丙酮胺有抗心律失常及抗心肌缺氧作用。 以三丙酮胺为原料，以乙醇为溶剂，在催化剂作用下加氢(常压或3～4MPa)，可制得受阻胺类光稳定剂原料2，2，6，6-四甲基哌啶醇。
  • MSDS 信息:2,2,6,6-Tetramethyl-4-piperidone(826-36-8).msds
  • 用途二:该品是受阻胺光稳定剂的中间体和制药中间体。
  • MOL 文件:826-36-8.mol
  • 图谱信息:四甲基哌啶酮(826-36-8)核磁图( 13 CNMR) 四甲基哌啶酮(826-36-8)质谱(MS) 四甲基哌啶酮(826-36-8)红外图谱(IR1) 四甲基哌啶酮(826-36-8)红外图谱(IR2) 四甲基哌啶酮(826-36-8)核磁图( 1 HNMR)
  • 用途一:用于合成抗阻胺类光稳定剂
  • Acros Organics:2,2,6,6-四甲基-4-哌啶酮 2,2,6,6-Tetramethyl-4-piperidone monohydrate, 98%(826-36-8)
  • 四甲基哌啶酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1424 2,2,6,6-四甲基-4-哌啶酮 2,2,6,6-Tetramethyl-4-piperidone 500G 1890元 2014/06/02 T1424 2,2,6,6-四甲基-4-哌啶酮 2,2,6,6-Tetramethyl-4-piperidone 25G 278元 2010/06/21 AC42061EA 四甲基哌啶酮 2,2,6,6-tetramethyltetrahydro-4(1H)-pyridinone 10 GR 1065元
  • TCI Shanghai:2,2,6,6-四甲基-4-哌啶酮 2,2,6,6-Tetramethyl-4-piperidone,>;98.0%(T)(826-36-8)
  • Sigma Aldrich:826-36-8(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Homopiperidines 同哌啶
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperidines 哌啶
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperidones 哌啶酮

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