3-Methylpiperidine 3-甲基哌啶

CAS 626-56-2 MFCD00005994

化学结构图

626-56-2
SMILES: CC1CCCNC1

化学属性

Mol. FormulaC6H13N
Mol. Weight99
Refractive index1.4450 to 1.4500
Boiling Point123-126
Density0.845
Flash Point8°C(lit.)
TSCAYes
Melting Point-24°
Solubilitymiscible
pH:A

别名和识别编码

Chemical Name3-Methylpiperidine
CAS Number626-56-2
Alfabeta NameMETHYLPIPERIDINE 3-
MDL NumberMFCD00005994
Synonym β-甲基哌啶 3-哌可啉 (R,S)-3-Methyl-piperidine 3-METHYLPIPERIDINE 3-Methylpiperidine ,99% 3-Methylpiperidine,98% 3-PIPECOLINE (BETA-) 97+% 3-PIPECOLINE 3-METHYL PIPERIDINE 3-PIPECOLINE 99.5% 3-Pipecoline 3-Pipecoline;-Pipecoline 3-Pipecoline;β-Pipecoline 3-methyl-piperidin 3-methylpiperidine 3-methylpiperidine(corrosiveliquid,flammable,n.o.s.) 3-pipercoline(beta-) 3-甲基哌啶 3-甲基哌啶,98% 3PPC BETA-PIPECOLIN BETA-PIPECOLINE Hexahydro-3-picoline LABOTEST-BB LTBB000786 β-Pipecoline, 3-Pipecoline β-甲基哌啶 3-哌可啉
PubChem Substance ID79081
EC Number210-953-6
Beilstein Registry Number79807
Chemical Name Translation3-甲基哌啶
Reaxys-RN79807
LabNetwork Molecule IDLN00220864
InChIInChI=1S/C6H13N/c1-6-3-2-4-7-5-6/h6-7H,2-5H2,1H3
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分类

  • {SNA} Building Blocks, C5 to C7, Chemical Synthesis, Heterocyclic Building Blocks, Piperidines

安全信息

Warnings 危化品目录(2015) IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 1993 UN 1993 3/PG 2
Risk Statements
  • R11 Highly flammable 非常易燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Hazard Codes 3
Hazard Class3
Storage condition Flammables area
Restrict 危险品

其他信息

  • 用途一:用于有机合成
  • 图谱信息:3-甲基哌啶(626-56-2)核磁图( 13 CNMR) 3-甲基哌啶(626-56-2)核磁图( 1 HNMR) 3-甲基哌啶(626-56-2)红外图谱(IR1)
  • TCI Shanghai:3-甲基哌啶 3-Pipecoline,>;97.0%(GC)(T)(626-56-2)
  • 3-甲基哌啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0444 3-甲基哌啶 3-Pipecoline 25ML 196元 2014/06/02 P0444 3-甲基哌啶 3-Pipecoline 500ML 1440元 2010/06/21 127501000 3-甲基哌啶 3-Methylpiperidine 99% 100 GR 855元
  • Alfa Aesar:3-甲基哌啶,98% 3-Methylpiperidine, 98%(626-56-2)
  • MSDS 信息:3-甲基六氢吡啶(626-56-2).msds
  • Sigma Aldrich:626-56-2(sigmaaldrich)
  • MOL 文件:626-56-2.mol
  • Acros Organics:3-甲基哌啶 3-Methylpiperidine, 99%(626-56-2)
  • 外观性质:无色液体。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Homopiperidines 同哌啶
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperazines 哌嗪
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperidines 哌啶

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