Morpholine-4-carbaldehyde 4-甲酰吗啉

CAS 4394-85-8 MFCD00006170

化学结构图

4394-85-8
SMILES: O=CN1CCOCC1

化学属性

Mol. FormulaC5H9NO2
Mol. Weight115.13
Density1.14
Refractive indexn20/D 1.485(lit.)
Boiling Point236.5°C at 760 mmHg
Melting Point23°C
Flash Point125°C
TSCAYes
Solubility可溶
Appearance 该品为无色透明液体，沸点240℃，熔点23℃，相对密度1.15，闪点 118℃。
pH:A

别名和识别编码

Chemical NameMorpholine-4-carbaldehyde
CAS Number4394-85-8
Alfabeta NameFORMYLMORPHOLINE 4-
MDL NumberMFCD00006170
Synonym Morpholine-4-carbaldehyde {LY} Morpholine-4-carbaldehyde {} {LY} Morpholine-4-carbaldehyde {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {} {} {} {} {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {} {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {} {} {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {} {} {} {} {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Morpholine-4-carbaldehyde {} {} {}
EC Number224-518-3
Beilstein Registry Number110293
PubChem Substance ID20417
Reaxys-RN110293
Chemical Name Translation4-甲酰吗啉
Wiswesser Line NotationT6N DOTJ AVH
LabNetwork Molecule IDLN00008251
InChIInChI=1S/C5H9NO2/c7-5-6-1-3-8-4-2-6/h5H,1-4H2
Canonical SMILESO=CN1CCOCC1
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; nitrogen heterocycle; alicycle; 6RingOnly; 6ring; ether; 1fragment
  • {SNA} Building Blocks, C4 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Morpholines/Thiomorpholines

产品应用

  • N-甲酰吗啉主要作为芳烃及丁烯抽提溶剂，亦是焦化苯加氢精制的萃取溶剂；也可用于天然气及天然气凝析油、汽油、合成气、烟道气的脱硫；也作有机合成反应的溶剂。

相关文献及参考

  • Short: III/47
  • Short: IV/10A
  • Beilstein: 27,IV,274

安全信息

Warnings IRRITANT
Signal word
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P333+P313+P362+P364
  • P332+P313
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P337+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H316 Causes mild skin irritation 会轻微的刺激皮肤
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves
RTECSQD9694000
Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen Hygroscopic Store at room temperature {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under ni 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >16 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6500 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

其他信息

  • Alfa Aesar:4-甲酰基吗啉,99% 4-Formylmorpholine, 99%(4394-85-8)
  • 下游产品:噻唑-4-甲醛
  • MSDS 信息:4-Morpholinecarboxaldehyde(4394-85-8).msds
  • 溶于水。
  • 上游原料:1,4-氧氮六环 --> 甲酸甲酯
  • 用途一:用于天然气、合成气、烟道气、天然气凝析油及汽油等的脱硫
  • N-甲酰吗啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0157 N-甲酰基吗啉 4-Formylmorpholine 25G 265元 2014/06/02 F0157 N-甲酰基吗啉 4-Formylmorpholine 500G 1260元 2010/06/21 133800050 N-甲酰吗啉 N-Formylmorpholine 99+% 5 ML 292元
  • TCI Shanghai:N-甲酰基吗啉 4-Formylmorpholine,>;99.0%(GC)(4394-85-8)
  • 用途二:N-甲酰吗啉主要作为芳烃及丁烯抽提溶剂，亦是焦化苯加氢精制的萃取溶剂；也可用于天然气及天然气凝析油、汽油、合成气、烟道气的脱硫；也作有机合成反应的溶剂。
  • 图谱信息:N-甲酰吗啉(4394-85-8)核磁图( 13 CNMR) N-甲酰吗啉(4394-85-8)核磁图( 1 HNMR) N-甲酰吗啉(4394-85-8)Raman光谱 N-甲酰吗啉(4394-85-8)质谱(MS) N-甲酰吗啉(4394-85-8)红外图谱(IR1) N-甲酰吗啉(4394-85-8)红外图谱(IR2)
  • 敏感性:Hygroscopic
  • MOL 文件:4394-85-8.mol
  • Sigma Aldrich:4394-85-8(sigmaaldrich)
  • 海关编码:29349990
  • Acros Organics:N-甲酰基吗啉 N-Formylmorpholine, 99+%(4394-85-8)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Isoxazoles 异恶唑
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Morpholines/Thiomorpholines 吗啉/硫吗啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Morpholines/Thiomorpholines 吗啉/硫吗啉
  5. C4 to C10 - Morpholines/Thiomorpholines

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