4-Acetylmorpholine 4-乙酰基吗啉

CAS 1696-20-4 MFCD00006171

化学结构图

1696-20-4
SMILES: CC(=O)N1CCOCC1

化学属性

Mol. FormulaC6H11NO2
Mol. Weight129.16
Density1.116
Refractive index1.4810 to 1.4850
Boiling Point255.9°C at 760 mmHg
Melting Point14°C
Flash Point>110°C
TSCAYes
SolubilityMISCIBLE

别名和识别编码

Chemical Name4-Acetylmorpholine
Synonym 1-Morpholinoethanone {LY} 1-Morpholinoethanone {} {LY} 1-Morpholinoethanone {} {} {LY} 1-Morpholinoethanone {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {} {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {} {} {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Morpholinoethanone {} {} {} {} {} {} {} {} {} {
CAS Number1696-20-4
EC Number216-913-4
Beilstein Registry Number111971
MDL NumberMFCD00006171
PubChem Substance ID87561797
Reaxys-RN111971
Chemical Name Translation4-乙酰基吗啉
InChIKeyKYWXRBNOYGGPIZ-UHFFFAOYSA-N
Wiswesser Line NotationT6N DOTJ AV1
LabNetwork Molecule IDLN00221413
Canonical SMILESCC(=O)N1CCOCC1
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; nitrogen heterocycle; alicycle; 6RingOnly; 6ring; amide; ether; 1fragment
  • {Chemicalbook} 农药中间体: 杀菌剂中间体: 吗啉类杀菌剂
  • {SNA} Building Blocks, C4 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Morpholines/Thiomorpholines

产品应用

  • N-乙酰吗啉是非常重要农药中间体,是合成农用杀菌剂烯酰吗啉、氟吗啉的主要原料之一。N-乙酰吗啉和N-甲酰吗啉的混合物是优良的天然气和合成气酸性气体脱除剂。低品质的天然气或合成气的提取需要去除CO2和H2S等微量组分,对于CO2和H2S含量高的气体使用物理溶剂特别有利。

相关文献及参考

  • Beilstein: 27,IV,274
  • Short: EINECS
  • Short: III/38B
  • Short: IV/1a

安全信息

Signal word
GHS Symbol
WGK Germany1
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H315 Causes skin irritation 会刺激皮肤
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSQD7000000
Hazard Codes Xn Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 7500 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 5,287,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6130 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Wash

其他信息

  • 无毒、无腐蚀。可以与水、低级醇混溶,易溶于一般的有机溶剂。N-乙酰吗啉在一般条件下化学性质稳定,热分解温度大于230℃ 。在热和强酸的作用下,可以发生酸解反应,生成吗啉盐和醋酸。
  • 毒性分级:中毒
  • 用途二:4-乙酰吗啉是杀菌剂烯酰吗啉、氟吗啉的中间体。
  • 4-乙酰基吗啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0102 4-乙酰基吗啉 4-Acetylmorpholine 25G 321元 2014/06/02 A0102 4-乙酰基吗啉 4-Acetylmorpholine 500G 2300元 2010/06/21 257200250 4-乙酰基吗啉 N-Acetylmorpholine 98% 25 ML 297元
  • 可燃性危险特性:可燃; 加热分解释放有毒氮氧化物烟雾
  • 类别:有毒物品
  • 爆炸物危险特性:与氧化剂反应激烈
  • Alfa Aesar:N-乙酰基吗啉,98% N-Acetylmorpholine, 98%(1696-20-4)
  • 用途三:N-乙酰吗啉是非常重要农药中间体,是合成农用杀菌剂烯酰吗啉、氟吗啉的主要原料之一。N-乙酰吗啉和N-甲酰吗啉的混合物是优良的天然气和合成气酸性气体脱除剂。低品质的天然气或合成气的提取需要去除CO2和H2S等微量组分,对于CO2和H2S含量高的气体使用物理溶剂特别有利。
  • Acros Organics:N-乙酰基吗啉 N-Acetylmorpholine, 98%(1696-20-4)
  • 刺激数据:皮肤-兔子 500 毫克/24小时 轻度; 眼睛-兔子 500 毫克 中度
  • 储运特性:库房通风低温干燥
  • 方法一:其制备方法是用吗啉与乙酰氯或乙酸酐反应而制得。
  • 用途一:是非常重要的农药中间体,是合成农用杀菌剂烯酰吗啉、氟吗啉的主要原料之一
  • Sigma Aldrich:1696-20-4(sigmaaldrich)
  • MOL 文件:1696-20-4.mol
  • 急性毒性:口服-大鼠 LD50: 6130 毫克/公斤; 非肠-小鼠 LDL0:2400 毫克/公斤
  • MSDS 信息:4-乙酰基吗啉(1696-20-4).msds
  • TCI Shanghai:4-乙酰基吗啉 4-Acetylmorpholine,>;99.0%(GC)(1696-20-4)
  • 上游原料:乙酐
  • 外观性质:黄色液体。
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水

系列性分类


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