2-Fluoropyridine 2-氟吡啶

CAS 372-48-5 MFCD00006224

化学结构图

372-48-5
SMILES: Fc1ccccn1

化学属性

Mol. FormulaC5H4FN
Mol. Weight97.09
Boiling Point125.9°C at 760 mmHg
Density1.128
Refractive index1.4660 to 1.4690
Flash Point28.3°C
TSCANo
Appearance 无色透明液体
pH:A

别名和识别编码

Chemical Name2-Fluoropyridine
CAS Number372-48-5
Alfabeta NameFLUOROPYRIDINE 2-
MDL NumberMFCD00006224
Synonym 2-Fluoropyridine {LY} 2-Fluoropyridine {} {LY} 2-Fluoropyridine {} {} {LY} 2-Fluoropyridine {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Fluoropyridine {} {} {} {} {} {} {} {}
EC Number206-757-5
Beilstein Registry Number1515
PubChem Substance ID9746
Chemical Name Translation2-氟吡啶
Reaxys-RN1515
InChIKeyMTAODLNXWYIKSO-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008275
InChIInChI=1S/C5H4FN/c6-5-3-1-2-4-7-5/h1-4H
Canonical SMILESFC1=NC=CC=C1
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分类

  • {SNA} Building Blocks, C5, Chemical Synthesis, Fluorinated Building Blocks, Heterocyclic Building Blocks, Heterocyclic Fluorinated Building Blocks, Other Fluorinated Heterocycles, Pyridines
  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: II/6
  • Short: II/14a
  • Short: II/27C
  • The possibility of metallation at C-3, together with the ready nucleophilic displacement of the activated fluorine makes 2-fluoropyridine a useful precursor of a wide range of 2,3-disubstituted pyridines. See, e.g.: J. Org. Chem., 53, 2740 (1988):

安全信息

Warnings IRRITANT, FLAMMABLE
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
Risk Statements
  • R10 Flammable 易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSUT3900000
Packing GroupIII
UN Number 1993
Hazard Codes 3 Xn
Hazard Class3
Storage condition 2-8°C {LY} 2-8°C Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8° 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 mg/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 176,185,1987

其他信息

  • TCI Shanghai:2-氟吡啶 2-Fluoropyridine,>;97.0%(GC)(372-48-5)
  • Hazard Note:Flammable/Irritant
  • 用途一:用作医药、农药中间体
  • MSDS 信息:2-Fluoropyridine(372-48-5).msds
  • 图谱信息:2-氟吡啶(372-48-5)核磁图( 1 HNMR) 2-氟吡啶(372-48-5)红外图谱(IR1) 2-氟吡啶(372-48-5)核磁图( 13 CNMR) 2-氟吡啶(372-48-5)质谱(MS)
  • 2-氟吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0217 2-氟吡啶 2-Fluoropyridine 25G 526元 2010/06/21 119630500 2-氟吡啶 2-Fluoropyridine 98% 50 ML 1494元 2010/06/21 119632500 2-氟吡啶 2-Fluoropyridine 98% 250 ML 5227元
  • Acros Organics:2-氟吡啶 2-Fluoropyridine, 98%(372-48-5)
  • 海关编码:29333999
  • MOL 文件:372-48-5.mol
  • 下游产品:2-(5-溴-2-噻酚)吡啶 --> 2-氟-3-吡啶硼酸
  • Alfa Aesar:2-氟吡啶,99% 2-Fluoropyridine, 99%(372-48-5)
  • Sigma Aldrich:372-48-5(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  1. C8 to C9 - Pyridines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶