N-Benzylpyridin-2-Amine 2-苄氨基吡啶

CAS 6935-27-9 MFCD00006251

化学结构图

6935-27-9
SMILES: c1ccc(CNc2ccccn2)cc1

化学属性

Mol. FormulaC12H12N2
Mol. Weight184.23708
Flash Point153°(307°F)
TSCAYes
Boiling Point116-131 °C at 0.6 mmHg
Melting Point95-97 °C

别名和识别编码

Chemical NameN-Benzylpyridin-2-Amine
MDL NumberMFCD00006251
Synonym 2-Benzylaminopyridine {LY} 2-Benzylaminopyridine {} {LY} 2-Benzylaminopyridine {} {} {LY} 2-Benzylaminopyridine {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {} {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Benzylaminopyridine {} {} {} {} {} {} {} {} {
EC Number230-060-5
CAS Number6935-27-9
Beilstein Registry Number134309
PubChem Substance ID23362
Chemical Name Translation2-苄氨基吡啶
Reaxys-RN134309
LabNetwork Molecule IDLN00222968
InChIInChI=1S/C12H12N2/c1-2-6-11(7-3-1)10-14-12-8-4-5-9-13-12/h1-9H,10H2,(H,13,14)
Canonical SMILESC1(NCC2=CC=CC=C2)=NC=CC=C1
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分类

  • {SNA} Building Blocks, C12, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

安全信息

RTECSUS2700000
Safety Statements
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+P350
  • P337+P313
  • P305+P351+P338+P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Danger
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 用途一:医药中间体。
  • 上游原料:氢氧化钾 --> 2-氨基吡啶
  • 用途二:医药中间体N-(Phenylmethyl)-2-pyridinamine
  • Acros Organics:2-苄氨基吡啶 2-Benzylaminopyridine, 98%(6935-27-9)
  • MOL 文件:6935-27-9.mol
  • 方法一:由2-氨基吡啶与苄醇缩合而得。将苄醇、2-氨基吡啶和苛性钾加入反应锅，迅速升温至沸，蒸出水分，升温至250℃，反应3min。放料至冷水中，搅拌结晶。过滤、水洗，干燥得2-苄氨基吡啶。
  • Sigma Aldrich:6935-27-9(sigmaaldrich)
  • Alfa Aesar:2-苯甲基氨基吡啶,98% 2-Benzylaminopyridine, 98%(6935-27-9)
  • 海关编码:29333999
  • 图谱信息:2-苄氨基吡啶(6935-27-9)核磁图( 13 CNMR) 2-苄氨基吡啶(6935-27-9)质谱(MS) 2-苄氨基吡啶(6935-27-9)红外图谱(IR2) 2-苄氨基吡啶(6935-27-9)红外图谱(IR1) 2-苄氨基吡啶(6935-27-9)核磁图( 1 HNMR)
  • 2-苄氨基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1209 2-苯甲基氨基吡啶 2-Benzylaminopyridine 500G 1680元 2014/06/02 B1209 2-苯甲基氨基吡啶 2-Benzylaminopyridine 25G 228元 2010/06/21 187140500 2-苄氨基吡啶 2-Benzylaminopyridine 98% 50 GR 231元
  • MSDS 信息:2-Benzylaminopyridine(6935-27-9).msds
  • TCI Shanghai:2-苯甲胺吡啶 2-Benzylaminopyridine,>;97.0%(T)(6935-27-9)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. Solid Supported Synthesis - Specialty Synthesis
  4. Other Resins - Solid Supported Synthesis
  1. C12 - Pyridines
  1. C6 to C7 - Pyridines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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