4,4'-Bipyridine 4,4’-联吡啶

CAS 553-26-4 MFCD00006416

化学结构图

553-26-4
SMILES: c1cc(-c2ccncc2)ccn1

化学属性

Mol. FormulaC10H8N2
Mol. Weight156.18
Boiling Point304.8°C at 760 mmHg
Melting Point109-112°C
Density1.106
TSCAYes
Stability易吸潮
Flash Point304-305°C
Appearance 无色结晶。熔点111.0—112.0℃。易溶于乙醇和乙醚、不溶于水。
Solubilityslightly soluble

别名和识别编码

Chemical Name4,4'-Bipyridine
Synonym 4,4′-Dipyridyl {LY} 4,4′-Dipyridyl {} {LY} 4,4′-Dipyridyl {} {} {LY} 4,4′-Dipyridyl {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4′-Dipyridyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number553-26-4
PubChem Substance ID11107
EC Number209-036-3
Beilstein Registry Number113176
MDL NumberMFCD00006416
Merck Number3348
Alfabeta NameDIPYRIDYL 44-,'
Reaxys-RN113176
Chemical Name Translation4,4'-联吡啶
Wiswesser Line NotationT6NJ D- DT6NJ
LabNetwork Molecule IDLN00182898
InChIInChI=1S/C10H8N2/c1-5-11-6-2-9(1)10-3-7-12-8-4-10/h1-8H
Canonical SMILESC1(C2=CC=NC=C2)=CC=NC=C1
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分类

  • {SNA} Or
  • {SNA} A-B, Analytical Standards, 农残和代谢标准品,
  • {SNA} A-B, All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, B, BI - BZ, Chromatography, Environmental Standards, Pesticides & Metabolites
  • {SNA} A-B,

产品应用

  • 测定铁的试剂，有机合成，医药中间体。

相关文献及参考

  • Merck:14,3348
  • For reaction with p-Xyl­yl­ene dibromide, A13939, in synthesis of a self-assembling [2]catenane and template directed synthesis of a rigid tetra-cationic cyclophane receptor, see: Synlett, 459, 462 (1991).
  • Merck:14,3348 Beilstein:23,200

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 6.1 T T,Xi
Hazard statements
  • H301+H311
  • H301 Toxic if swallowed 吞食有毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RTECSDW1760000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P350
  • P305+P351+P338
  • P308+P311
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupIII
UN Number 2811 UN 2811 6.1/PG 3
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Warnings IRRITANT
Hazard Class6.1
Restrict 易制毒化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 172 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 10,363,1982

其他信息

  • Alfa Aesar:4,4'-联吡啶 4,4'-Bipyridine, 98%(553-26-4)
  • TCI Shanghai:4,4'-联吡啶 4,4'-Bipyridyl,>;98.0%(GC)(T)(553-26-4)
  • Hazard Note:Irritant
  • Sigma Aldrich:553-26-4(sigmaaldrich)
  • 下游产品:1-甲基-[4,4']联哌啶
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 类别:有毒物品
  • 4,4'-联吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30078221 4，4’-联吡啶 1g 47元 2011/04/16 B0469 4,4'-联吡啶 4,4'-Bipyridyl 25G 785元 2011/04/16 B0469 4,4'-联吡啶 4,4'-Bipyridyl 500G 6580元
  • 图谱信息:4,4'-联吡啶(553-26-4)核磁图( 13 CNMR) 4,4'-联吡啶(553-26-4)红外图谱(IR2) 4,4'-联吡啶(553-26-4)核磁图( 1 HNMR) 4,4'-联吡啶(553-26-4)红外图谱(IR1) 4,4'-联吡啶(553-26-4)红外图谱(IR3)
  • 急性毒性:口服-大鼠 LD50: 172 毫克/公斤
  • 敏感性:Hygroscopic
  • 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
  • 易溶于乙醇和乙醚、不溶于水。
  • 用途一:用于有机合成，医药中间体
  • 检测方法:HPLC,NMR
  • 毒性分级:高毒
  • 用途二:测定铁的试剂，有机合成，医药中间体。
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 海关编码:29333999
  • Acros Organics:4,4'-联吡啶 4,4'-Dipyridyl, anhydrous, 98%(553-26-4)
  • MSDS 信息:4,4'-Dipyridyl(553-26-4).msds
  • MOL 文件:553-26-4.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Zinc 锌催化剂/无机锌化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C9 - Ketones
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. B - Alphabetic
  5. BI - BZ - B
  1. C6 to C7 - Pyridines
  1. Materials Science 材料科学
  2. Products for Organic & Printed Electronics Research
  3. Photonic and Optical Materials - Organic and Printed Electronics
  4. Photochromic and Thermochromic Dyes - Photonic and Optical Materials
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C7 to C8
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Yttrium
  1. Materials Science 材料科学
  2. Photochromic Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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