4-(4-Nitrobenzyl)Pyridine 4-(4-硝基苄基)吡啶

CAS 1083-48-3 MFCD00006445

化学结构图

1083-48-3
SMILES: O=[N+]([O-])c1ccc(Cc2ccncc2)cc1

化学属性

Mol. FormulaC12H10N2O2
Mol. Weight214.22
Melting Point69-71 °C
TSCAYes
Density1.231
Solubility不溶于水，溶于乙醇，微溶于乙醚。
Stability对空气敏感
Boiling Point354.35 °C at 760 mmHg

别名和识别编码

Chemical Name4-(4-Nitrobenzyl)Pyridine
MDL NumberMFCD00006445
CAS Number1083-48-3
EC Number214-108-2
Beilstein Registry Number20(2)272
PubChem Substance ID87573560
Synonym 4-(4-Nitrobenzyl)pyridine {LY} 4-(4-Nitrobenzyl)pyridine {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {} {} {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {} {} {} {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(4-Nitrobenzyl)pyridine {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation4-(4-硝基苄基)吡啶
Reaxys-RN170877
Wiswesser Line NotationT6NJ D1R DNW
LabNetwork Molecule IDLN00223739
InChIInChI=1S/C12H10N2O2/c15-14(16)12-3-1-10(2-4-12)9-11-5-7-13-8-6-11/h1-8H,9H2
Canonical SMILESO=[N+](C1=CC=C(C=C1)CC2=CC=NC=C2)[O-]
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents TLC, Spectroscopy, TLC Reagents, N-R, TLC Visualization Reagents (alphabetic sort), UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy
  • {SNA} Building Blocks, C12, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
  • {SNA} Derivatization Reagents, Derivatization Reagents TLC, Spectroscopy, TLC Reagents, N-R, TLC Visualization Reagents (alphabetic sort), UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy, 分析/色谱, 分析试剂

产品应用

  • A chemical used for the detection of epoxides and methylating reagents.

相关文献及参考

  • Reagent for the determination of phosgene: Analyst, 84, 463 (1959); and other acylating or alkylating species: Talanta, 13, 1151 (1966); Cancer Research, 30, 1651 (1970); 31, 901 (1971).
  • Beilstein:20(2)272

安全信息

RTECSUT6360000
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word
Hazard Codes Xi
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 89 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#12116

其他信息

  • MSDS 信息:4-硝基苯甲基吡啶(1083-48-3).msds
  • 毒性分级:中毒
  • 上游原料:4-苄基吡啶
  • 可燃性危险特性:明火可燃;高热分解释放有毒的氮氧化物烟雾
  • 4-(4-硝基苄基)吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0183 4-(4-硝基苄基)吡啶 4-(4-Nitrobenzyl)pyridine 1G 111元 2014/06/02 N0183 4-(4-硝基苄基)吡啶 4-(4-Nitrobenzyl)pyridine 25G 995元 2010/06/21 128550100 4-(4-硝基苄基)吡啶 4-(4-Nitrobenzyl)pyridine 98% 10 GR 684元
  • Sigma Aldrich:1083-48-3(sigmaaldrich)
  • 类别:有毒物品
  • Alfa Aesar:4-(4-硝基苯甲基)吡啶,98+% 4-(4-Nitrobenzyl)pyridine, 98+%(1083-48-3)
  • 溶于乙醇、乙醚，不溶于水。水中溶解度:1.04 g/L
  • 外观性质:白色或浅黄色针状结晶。
  • 用途一:用作有机合成中的酰化剂和烷化剂，也可用于测定光气和有机磷农药的分析。该品有毒，有刺激性。
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • 敏感性:Light Sensitive
  • MOL 文件:1083-48-3.mol
  • 急性毒性:静脉-小鼠 LD50: 89 毫克/公斤
  • Used for the detection of epoxides and methylating reagents, and for the spectrophotometric determination of phosphorus-containing pesticides. Also used for the determination of alkylating agents.
  • 方法一:由4-苄基吡啶硝酸盐与浓硫酸反应而得。将两种原料一起加热至50℃，5min后倒入冰中，在冷却下用氨水中和。然后用乙醚提取，将提取液浓缩，结晶，即以50%以上的收率得到成品。
  • 灭火剂:二氧化碳、泡沫、砂土、雾状水。
  • TCI Shanghai:4-(4-硝基苄基)吡啶 4-(4-Nitrobenzyl)pyridine,>;98.0%(T)(1083-48-3)
  • F:10-23
  • 海关编码:29333999
  • 图谱信息:4-(4-硝基苄基)吡啶(1083-48-3)红外图谱(IR2) 4-(4-硝基苄基)吡啶(1083-48-3)核磁图( 13 CNMR) 4-(4-硝基苄基)吡啶(1083-48-3)核磁图( 1 HNMR) 4-(4-硝基苄基)吡啶(1083-48-3)红外图谱(IR1) 4-(4-硝基苄基)吡啶(1083-48-3)红外图谱(IR3) 4-(4-硝基苄基)吡啶(1083-48-3)质谱(MS)
  • Acros Organics:4-(4-硝基苄基)吡啶 4-(4-Nitrobenzyl)pyridine, 98%(1083-48-3)
  • 用途二:用作有机合成中的酰化剂和烷化剂，也可用于测定光气和有机磷农药的分析。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Spectroscopy - Analytical Reagents
  4. UV/Visible (UV/VIS) Spectroscopy - 紫外/可见吸收光谱
  5. UV/Vis Reagents - UV/Visible (UV/VIS) Spectroscopy
  1. C12 - Pyridines
  1. C6 to C7 - Pyridines
  1. C7 and C8
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Analytical Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (alphabetic sort)
  4. TLC Reagents, G-M
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (alphabetic sort)
  5. TLC Reagents, G-M
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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