4-Amino-Tempo, Free Radical 4-氨基-2,2,6,6-四甲基哌啶氧自由基

CAS 14691-88-4 MFCD00006479

化学结构图

14691-88-4
SMILES: CC1(C)CC(N)CC(C)(C)N1[O]

化学属性

Mol. FormulaC9H19N2O
Mol. Weight171.26
Melting Point37-39
Flash Point39 °C
Boiling Point98°C/4mmHg(lit.)

别名和识别编码

Chemical Name4-Amino-Tempo, Free Radical
CAS Number14691-88-4
Alfabeta NameAMINOTETRAMETHYLPIPERIDINOOXYL 422661-----,,,
MDL NumberMFCD00006479
Synonym 4-Amino-TEMPO Tempamine 4-Amino-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical 4-AMINO-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL FREE RADICAL 97+% 4-Amino-1-oxy-2,2,6,6-tetramethylpiperidine, free radical 4-氨基-TEMPO，自由基 4-AMINO-2,2,6,6-TETRAMETHYLPIPERIDINYLOXY 4-AMINO-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL FREE RADICAL [SPIN LABEL] 4-amino-2,2,6,6-tetramethyl-1-piperidinylox 4-Amino-2,2,6,6-tetramethylpiperidinooxy,free radical 4-AMINO-2,2,6,6-TETRAMETHYLPIPERIDIN-1-OXYL 4-AMINO-TEMPO 4-AMINO-2,2,6,6-TETRAMETHYLPIPERIDINO-1-OXYL 4-Amino-2,2,6,6-tetramethylpiperidine-1-oxyl(4-Amino-TEMPO,freeradical) 4-AMINO-TEMPO (4-AMINO-2,2,6,6-TETRAMETHYLPIPERIDINYLOXY) 4-AMINO-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL 4-amino-2,2,6,6-tetramethylpiperidinyloxy, free radical 4-Aminotempo 4-氨基-2,2,6,6-四甲基哌啶-1-氧 4-氨基-2,2,6,6-四甲基哌啶氧自由基 4-氨基-TEMPO 4-AMINO-2,2,6,6-TETRAMETHYLPIPERIDINOXY FREE RADICAL 4-AMINO-2,2,6,6-TETRAMETHYLPIPERIDINOOXY 4-氨基-TEMPO 6-Tempamine 4-胺-2,2,6,6-四甲基二苯哌酯 4-氨基-2,2,6,6-四甲基哌啶氧自由基 tempamine 4-amino-2,2,6,6-tetramethylpiperidine 1-oxide 4-AMINO-1-OXY-2,2,6,6-TETRAMETHYLPIPERIDINE Tempo-amine 2,2,6,6-TETRAMETHYL-4-AMINO-1-PIPERIDINYLOXY 4-氨基-2,2,6,6-四甲基哌啶-1-氧
Beilstein Registry Number3933966
EC Number238-738-2
Reaxys-RN13265624
PubChem Substance ID87562801
Chemical Name Translation4-氨基-2,2,6,6-四甲基哌啶氧自由基
InChIKeyXUXUHDYTLNCYQQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00176452
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分类

  • {SA} Chemical Synthesis, Radical Chemistry, Stable Radicals, Synthetic Reagents, TEMPO Derivatives
  • {SNA} Analytical Reagents, Analytical/Chromatography, Electron Spin Resonance (ESR/EPR) Spectroscopy, Spectroscopy, Spin Labels
  • Chemical Synthesis, Radical Chemistry, Stable Radicals, Synthetic Reagents, TEMPO Derivatives

产品应用

  • Useful spin label for studying biological systems and polymers.

相关文献及参考

  • Biochemistry, 33, 3855 (1994),
  • 1. Biochemistry 33 , 3855, (1994) 摘要
  • 2. J. Colloid. Interface Sci. 165 , 236, (1994)
  • 3. J. Med. Chem. 50 , 2137, (2007) 摘要
  • FT-IR 1 (2), 908:C / FT-IR 2 (3), 3984:A / IR-Spectra (3), 217:A / IR-Spectra (2), 195:A / RegBook 1 (2), 2673:L / Sigma FT-IR 1 (2), 281:B / Structure Index 1 , 420:E:4

安全信息

Warnings IRRITANT
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
WGK Germany3
Signal word
Storage condition 0-10 0-10°C 2-8°C
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

其他信息

  • MOL 文件:14691-88-4.mol
  • TCI Shanghai:4-氨基-2,2,6,6-四甲基哌啶氧自由基 4-Amino-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical,>;97.0%(GC)(14691-88-4)
  • Sigma Aldrich:14691-88-4(sigmaaldrich)
  • Acros Organics:4-Amino-2,2,6,6-tetramethylpiperidinooxy, free radical, 97%(14691-88-4)
  • 4-胺-2,2,6,6-四甲基二苯哌酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A1343 4-氨基-2,2,6,6-四甲基哌啶1-氧自由基 4-Amino-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical 1G 1020元 2011/04/16 A1343 4-氨基-2,2,6,6-四甲基哌啶1-氧自由基 4-Amino-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical 5G 3020元 2010/06/21 172732500 4-胺-2,2,6,6-四甲基二苯哌酯 4-Amino-2,2,6,6-tetramethylpiperidinooxy 97%, free radical 250 MG 461元
  • Hazard Note:Irritant

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Homopiperidines 同哌啶
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperidines 哌啶
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Spectroscopy - Analytical Reagents
  4. Electron Spin Resonance (ESR/EPR) Spectroscopy - Spectroscopy
  5. Spin Labels - Electron Spin Resonance (ESR/EPR) Spectroscopy
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Radical Chemistry - Synthetic Reagents
  4. Stable Radicals - Radical Chemistry
  5. TEMPO Derivatives - Stable Radicals
  1. Analytical & Chromatography 分析化学与色谱
  2. ESR Spectrometry
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Radical Chemistry - Synthetic Reagents
  4. Stable Radicals
  5. Others

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