4-Amino-2-Methylquinoline 4-氨基-2-甲基喹啉

CAS 6628-04-2 MFCD00006759

化学结构图

6628-04-2
SMILES: Cc1cc(N)c2ccccc2n1

化学属性

Mol. FormulaC10H10N2
Mol. Weight158.20
Melting Point162-166°C
TSCANo
Boiling Point333°C at 760 mmHg
Flash Point333°C
Density1.169

别名和识别编码

Chemical Name4-Amino-2-Methylquinoline
MDL NumberMFCD00006759
CAS Number6628-04-2
Synonym 2-Methylquinolin-4-amine {LY} 2-Methylquinolin-4-amine {} {LY} 2-Methylquinolin-4-amine {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-4-amine {} {} {} {} {} {} {} {} {} {} {
EC Number229-604-4
Beilstein Registry Number118323
PubChem Substance ID81116
Reaxys-RN118323
Chemical Name Translation4-氨基-2-甲基喹啉
InChIKeyCOCFIBRMFPWUDW-UHFFFAOYSA-N
LabNetwork Molecule IDLN00221056
InChIInChI=1S/C10H10N2/c1-7-6-9(11)8-4-2-3-5-10(8)12-7/h2-6H,1H3,(H2,11,12)
Canonical SMILESNC1=CC(C)=NC2=CC=CC=C12
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Mass Spectrometry (MS), Matrix Substances for MALDI-MS, Spectroscopy
  • {SNA} Mass Spectrometry (MS), Matrix Substances for MALDI-MS, Spectroscopy, 分析/色谱, 分析试剂
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Quinaldines

产品应用

  • 用作医药中间体。

相关文献及参考

  • Beilstein:22(3/4)4759

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Warning
Hazard Codes Xi
Packing GroupIII
Hazard Class8
UN Number 3259
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 4-氨基-2-甲基可尼汀价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0415 4-氨基-2-甲基喹啉 4-Amino-2-methylquinoline 5G 396元 2014/06/02 A0415 4-氨基-2-甲基喹啉 4-Amino-2-methylquinoline 25G 1260元 2010/05/25 L14295 4-氨基-2-甲基喹啉, 98% 4-Amino-2-methylquinoline, 98% 25g 672元
  • 外观性质:晶体，溶于苯、乙醚和乙醇。熔点：169-170℃沸点：333℃
  • 方法一:由4-氯喹哪啶经胺化而得。将4-氯喹哪啶和苯混合，回流脱水至无水带出为止，减压蒸干。加入苯酚，通氨，同时加热使其温度逐渐上升至160℃，回收低沸物。于160-180℃继续通氨2h，然后冷至室温并加入苯，过滤，滤饼用苯洗涤，加热水溶解除去油层，水层以活性炭脱色，过滤，滤液用氢氧化钠溶液调至强碱性，析出白色或微黄色固体，得4-氨基喹哪啶。熔点160℃左右。
  • 用途一:用作医药中间体。
  • 溶于苯、乙醚和乙醇。
  • TCI Shanghai:4-氨基-2-甲基喹啉 4-Amino-2-methylquinoline,>;97.0%(T)(6628-04-2)
  • MOL 文件:6628-04-2.mol
  • Sigma Aldrich:6628-04-2(sigmaaldrich)
  • 图谱信息:4-氨基-2-甲基可尼汀(6628-04-2)红外图谱(IR2) 4-氨基-2-甲基可尼汀(6628-04-2)红外图谱(IR1) 4-氨基-2-甲基可尼汀(6628-04-2)质谱(MS)
  • 上游原料:4-氯喹哪啶
  • Alfa Aesar:4-氨基-2-甲基喹啉,98% 4-Amino-2-methylquinoline, 98%(6628-04-2)
  • 4-氨基-2-甲基可尼汀价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A0415 4-氨基-2-甲基喹啉 4-Amino-2-methylquinoline 5G 412元 2011/04/16 A0415 4-氨基-2-甲基喹啉 4-Amino-2-methylquinoline 25G 1250元 2010/05/25 L14295 4-氨基-2-甲基喹啉, 98% 4-Amino-2-methylquinoline, 98% 25g 672元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinaldines 奎纳丁
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinaldines 奎纳丁
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quinolines 喹啉

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