8-Hydroxyquinoline-5-sulfonic acid 8-羟基喹啉-5-磺酸

CAS 84-88-8 MFCD00006795

化学结构图

84-88-8
SMILES: O=S(=O)(O)c1ccc(O)c2ncccc12

化学属性

Mol. FormulaC9H7NO4S
Mol. Weight225.22
Appearance 淡黄色针状结晶或结晶性粉末。熔点213℃（分解）。易溶于水，微溶于有机溶剂。 crystalline
Melting Point311-313 °C

别名和识别编码

Chemical Name8-Hydroxy-5-quinolinesulfonic acid
MDL NumberMFCD00006795
PubChem Substance ID6792
CAS Number84-88-8
EC Number201-570-5
Synonym 8-Hydroxyquinoline-5-sulfonic acid {LY} 8-Hydroxyquinoline-5-sulfonic acid 8-hydroxyquinoline-5-sulfonate 8-hydroxyquinoline-5-sulfonic acid 8-hydroxyquinoline-5-sulfonic acid, monopotassium salt 8-hydroxyquinoline-5-sulfonic acid, monosodium salt 8-quinolinol-5-sulfonic acid copper 8-oxyquinoline sulfonate oxine-5-sulfonic acid {} {LY} 8-Hydroxyquinoline-5-sulfonic acid {} {} {LY} 8-Hydroxyquinoline-5-sulfonic acid {} {} {} {LY} 8-Hydroxyquinoline-5-sulfonic acid {} {} {} {} {LY} 8-Hydroxyquinoline-5-sulfonic acid {} {} {} {} {} {LY} 8-Hydroxyquinoline-5-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 8-Hydroxyquinoline-5-sulfonic acid {} {} {} {} {} {} {} {LY} 8-Hydroxyquinoline-5-sulfonic acid {} {} {} {} {} {} {} {} {LY} 8-Hydroxyquinoline-5-sulfonic acid {} {} {} {} {} {} {} {} {} {LY} 8-Hydroxyquinoline-5-sulfonic acid {} {} {} {} {} {} {} {} {} {} {LY} 8-Hydroxyquinoline-5-sulf
Reaxys-RN195247
Beilstein Registry Number22,407
Merck Number4844
Chemical Name Translation8-羟基喹啉-5-磺酸
LabNetwork Molecule IDLN00193379
InChIInChI=1S/C9H7NO4S/c11-7-3-4-8(15(12,13)14)6-2-1-5-10-9(6)7/h1-5,11H,(H,12,13,14)
Canonical SMILESO=S(C1=C2C=CC=NC2=C(O)C=C1)(O)=O
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分类

  • Building Blocks, C8 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Quinolines
  • {uni_hamburg} no charge; nitrogen heterocycle; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; alcohol; 1fragment
  • {SA} Building Blocks, C8 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Quinolines

相关文献及参考

  • Merck 14 ,4844
  • Short: II/3 Title: Luminescence of Organic Substances Author: Schmillen, A.; Legler, R. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/3 Year: 1967 ISBN: 3-540-03895-7 ISBN: 978-3-540-03895-5 Internet Resource: DOI:10.1007/b86158 RefComment: 270 figs., VIII, 416 pages. Hardcover Abstract: For more than 1000 luminescent organic substances the most important data are represented as wave numbers of absorption and emission bands, decay times and quantum efficiencies. Additional tables contain further information for restricted groups of substances (figures on typical spectra, wave numbers of sharp single bands, influence of surrounding molecules, etc.).
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSVC2570000
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn Xn,Xi Xi
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
  • R22 Harmful if swallowed 吞咽有害
Packing GroupIII
Hazard Class6.1(b)
UN Number 2811 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 196,478,1976

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 mg/L
REFERENCE :
   CUMIDD Current Microbiology.  (Springer-Verlag New York, Inc., Service
   Center, 44 Hartz Way, Secaucus, NJ 07094)  V.1-    1978-
   Volume(issue)/page/year: 11,59,1984

Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 8-羟基喹啉-5-磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0306 8-羟基喹啉-5-磺酸 8-Hydroxyquinoline-5-sulfonic Acid Monohydrate 500G 2600元 2014/06/02 H0306 8-羟基喹啉-5-磺酸 8-Hydroxyquinoline-5-sulfonic Acid Monohydrate 25G 308元
  • 用途一:用作医药中间体
  • 图谱信息:8-羟基喹啉-5-磺酸(84-88-8)核磁图( 13 CNMR) 8-羟基喹啉-5-磺酸(84-88-8)质谱(MS) 8-羟基喹啉-5-磺酸(84-88-8)核磁图( 1 HNMR) 8-羟基喹啉-5-磺酸(84-88-8)红外图谱(IR1) 8-羟基喹啉-5-磺酸(84-88-8)红外图谱(IR2)
  • MOL 文件:84-88-8.mol
  • color:yellow to green
  • 用途二:用作有机合成中间体和分析试剂。
  • 上游原料:发烟硫酸 --> 8-羟基喹啉
  • 海关编码:29334990
  • 用途三:荧光检测金属离子，测定铋、铜、铁、银、钒和锌。
  • Sigma Aldrich:84-88-8(sigmaaldrich)
  • 方法一:由8-羟基喹啉磺化而得。将发烟硫酸在搅拌下冷却至10℃以下，逐渐加入8-羟基喹啉，保持温度在15℃以下。加完后升温，在30℃以下搅拌反应5h。放置过夜。次日将反应液放入8-10倍量水中（按8-羟基喹啉计），控制温度60℃，析出结晶，再放置过夜。过滤，洗涤，100℃干燥，得8-羟基喹啉-5-磺酸。收率87%。
  • TCI Shanghai:8-羟基喹啉-5-磺酸 8-Hydroxyquinoline-5-sulfonic Acid,>;98.0%(T)(84-88-8)
  • MSDS 信息:8-Hydroxyquinoline-5-sulfonic acid(84-88-8).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Isoquinolines 异喹啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinaldines 奎纳丁
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinolines 喹啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinolines 喹啉
  5. C8 to C10 - Quinolines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quinolines 喹啉

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