6-Methoxyquinoline 6-甲氧基喹啉

CAS 5263-87-6 MFCD00006800

化学结构图

5263-87-6
SMILES: COc1ccc2ncccc2c1

化学属性

Mol. FormulaC10H9NO
Mol. Weight159.19
Density1.15 g/mL at 20 °C(lit.)
Refractive indexn20/D 1.625(lit.)
Boiling Point295.3°C at 760 mmHg
Melting Point18-20°C
Flash Point113°C
TSCAYes
Solubility不溶
Stability对光敏感

别名和识别编码

Chemical Name6-Methoxyquinoline
CAS Number5263-87-6
Synonym 6-Methoxyquinoline {LY} 6-Methoxyquinoline 6-methoxyquinoline 6-methoxyquinoline hydrochloride {} {LY} 6-Methoxyquinoline {} {} {LY} 6-Methoxyquinoline {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Methoxyquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Methoxyq
MDL NumberMFCD00006800
EC Number226-077-2
Beilstein Registry Number21(3/4)1103
PubChem Substance ID14860
Chemical Name Translation6-甲氧基喹啉
Reaxys-RN115244
LabNetwork Molecule IDLN00194006
InChIInChI=1S/C10H9NO/c1-12-9-4-5-10-8(7-9)3-2-6-11-10/h2-7H,1H3
Canonical SMILESCOC1=CC2=C(C=C1)N=CC=C2
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分类

  • {uni_hamburg} no charge; nitrogen heterocycle; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; ether; 1fragment
  • {SNA} Building Blocks, C8 to C10, Chemical Synthesis, Heterocyclic Building Blocks, M, Quinolines, 生物活性小分子, 细胞生物学
  • {SNA} Bioactive Small Molecules, Building Blocks, C8 to C10, Chemical Synthesis, Heterocyclic Building Blocks, M, Quinolines, 细胞生物学
  • Amines
  • {SNA} Building Blocks, C8 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Quinolines
  • {SNA} Bioactive Small Molecules, Building Blocks, C8 to C10, Cell Biology, Chemical Synthesis,

产品应用

  • A useful sythetic intermediate.

相关文献及参考

  • Short: EINECS
  • Beilstein:21(3/4)1103
  • Short: III/35D3

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {}
Hazard Codes Xi
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • Acros Organics:6-甲氧基喹啉 6-Methoxyquinoline, 98%(5263-87-6)
  • 图谱信息:6-甲氧基喹啉(5263-87-6)红外图谱(IR1) 6-甲氧基喹啉(5263-87-6)核磁图( 1 HNMR) 6-甲氧基喹啉(5263-87-6)质谱(MS) 6-甲氧基喹啉(5263-87-6)核磁图( 13 CNMR)
  • 外观性质:淡黄色透明液体。不溶于水。密度:1.152 熔点:20℃ 沸点:284℃折射nD20:1.617-1.624 闪点: >110℃
  • 存储注意事项:光敏感
  • 6-甲氧基喹啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010162 6-甲氧基喹啉 25g 480元 2011/04/16 M0891 6-甲氧基喹啉 6-Methoxyquinoline 25G 869元 2010/06/21 179340250 6-甲氧基喹啉 6-Methoxyquinoline 98% 25 GR 707元
  • F:8
  • 不溶于水。
  • 海关编码:29334990
  • 下游产品:6-羟基喹啉
  • 检测方法:HPLC
  • MOL 文件:5263-87-6.mol
  • Sigma Aldrich:5263-87-6(sigmaaldrich)
  • TCI Shanghai:6-甲氧基喹啉 6-Methoxyquinoline,>;95.0%(GC)(5263-87-6)
  • 上游原料:氢氧化钠 --> 盐酸 --> 乙酸乙酯 --> 硫酸 --> 甲苯 --> 亚硝酸钠 --> 乙酐 --> 苯 --> 发烟硫酸 --> 甘油 --> 碘化钠 --> 对甲氧基苯胺 --> 硼酸 --> 4-硝基苯甲醚
  • Alfa Aesar:6-甲氧基喹啉,98+% 6-Methoxyquinoline, 98+%(5263-87-6)
  • MSDS 信息:6-Methoxyquinoline(5263-87-6).msds
  • 敏感性:Light Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Isoquinolines 异喹啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinaldines 奎纳丁
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinazolines 喹唑啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinolines 喹啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinolines 喹啉
  5. C8 to C10 - Quinolines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quinolines 喹啉

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