Tribromoacetaldehyde 三溴乙醛

CAS 115-17-3 MFCD00006961

化学结构图

115-17-3
SMILES: O=CC(Br)(Br)Br

化学属性

Mol. FormulaC2HBr3O
Mol. Weight281
Refractive index1.5840 to 1.5890
Boiling Point174
Density2.665
Flash Point65°C(lit.)
Solubility溶于水、乙醇、乙醚。

别名和识别编码

Chemical NameTribromoacetaldehyde
Synonym 2,2,2-Tribromoacetaldehyde Bromal 三溴乙醛 溴醛
CAS Number115-17-3
PubChem Substance ID87576320
EC Number204-067-9
Beilstein Registry Number1098614
MDL NumberMFCD00006961
Reaxys-RN1098614
Merck Number1383
Chemical Name Translation三溴乙醛
LabNetwork Molecule IDLN00194606
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分类

  • Aldehydes, Building Blocks, C1 to C6, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
  • {uni_hamburg} no charge; aldehyde; 1fragment
  • {SNA} Aldehydes, Building Blocks, C1 to C6, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • Merck 14 ,1383
  • Beil. 1 ,IV,3155
  • Aldrich MSDS 1 , 1726:B / Corp MSDS 1 (2), 3391:C / FT-IR 1 (1), 478:A / FT-IR 2 (1), 749:C / FT-NMR 1 (1), 747:C / IR-Spectra (2), 252:G / IR-Spectra (3), 281:D / NMR-Reference 2 (1), 367:B / RegBook 1 (1), 523:B / Structure Index 1 , 74:D:8 / Vapor Phase 3 , 569:A
  • Short: II/5 Title: Molecular Acoustics Author: Schaaffs, W. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/5 Year: 1967 ISBN: 3-540-03897-3 ISBN: 978-3-540-03897-9 Internet Resource: DOI:10.1007/b19950 RefComment: 321 figs., XII, 286 pages, Hardcover
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/18A Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organometallic and Organononmetallic Liquids, Binary Liquid Mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18A Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures ISBN: 3-540-64584-5 ISBN: 978-3-540-64584-9 Internet Resource: DOI:10.1007/b68239 RefComment: VII, 409 pages.
  • Short: IV/18B Title: Viscosity of Pure Organic Liquids an

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H310 Fatal in contact with skin 皮肤接触致命
  • H301 Toxic if swallowed 吞食有毒
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 T+
RTECSAB3237500
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P302+P350
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2927 UN 2927 6.1/PG 1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R27 Very toxic in contact with skin 与皮肤接触极毒
  • R34 Causes burns 会导致灼伤
Packing GroupI
Hazard Class6.1/8
Storage condition Refrigerator (+4°C)
Warnings 危化品目录(2015) 危险化学品

其他信息

  • 图谱信息:三溴乙醛(115-17-3)红外图谱(IR1)
  • 用途一:用于安眠、镇静等药物的合成及用作有机合成试剂
  • 外观性质:淡黄色油状液体。
  • MSDS 信息:三溴乙醛(115-17-3).msds
  • 方法一:可由乙醇与溴素反应而得；或由三氯乙醛与溴素反应制取，也可由三聚乙醛与溴素反应而得。将69g干燥的三聚乙醛滴入720g溴及1.5g硫的混合物中，反应在自身放热下进行。然后在60-80℃加热2h，将蒸馏收集的粗品再减压蒸馏，取71-74℃（2.4kPa）馏份，得产品溴醛220-240g。
  • 上游原料:三氯乙醛 --> 三聚乙醛
  • 三溴乙醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0350 三溴乙醛 Bromal 500G 3220元 2014/06/02 T0350 三溴乙醛 Bromal 25G 352元 2010/06/21 139291000 三溴乙醛 Tribromoacetaldehyde 97% 100 GR 834元
  • Sigma Aldrich:115-17-3(sigmaaldrich)
  • Hazard Note:Irritant
  • F:3-8-10-19
  • MOL 文件:115-17-3.mol
  • Acros Organics:三溴乙酸酐 Tribromoacetaldehyde, 97%(115-17-3)
  • 三溴乙醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 T0350 三溴乙醛 Bromal 500G 2780元 2011/04/16 T0350 三溴乙醛 Bromal 25G 304元 2010/06/21 139291000 三溴乙醛 Tribromoacetaldehyde 97% 100 GR 834元
  • 用途二:用作有机化工原料、分析试剂。
  • TCI Shanghai:三溴乙醛 Bromal,>;96.0%(GC)(115-17-3)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aldehydes - Carbonyl Compounds
  6. C1 to C6 - Aldehydes

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