1,2-Dinitrobenzene 1,2-二硝基苯

CAS 528-29-0 MFCD00007093

化学结构图

528-29-0
SMILES: [O-][N+](=O)C1C=CC=CC=1[N+]([O-])=O

化学属性

Mol. FormulaC6H4N2O4
Mol. Weight168.11
Boiling Point319
Melting Point114-117
TSCANo
Flash Point150 ºC
Solubility150 MG/L (20 ºC)
Density1.31

别名和识别编码

Chemical Name1,2-Dinitrobenzene
Synonym 1,1'-二十八烷-3,3,3‘,3‘-四甲基茚羧酸 1,2-DINITROBENZENE 1,2-DINITROBENZENE OEKANAL, 250 MG 1,2-DINITROBENZENE, 99+% 1,2-DNB 1,2-Dinitrobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00007093
CAS Number528-29-0
PubChem Substance ID87567438
EC Number208-431-8
Beilstein Registry Number5(4)738
Merck Number3273
Chemical Name Translation1,2-二硝基苯
Reaxys-RN642224
Wiswesser Line NotationWNR BNW
LabNetwork Molecule IDLN00337903
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Building Blocks,
  • {SNA} Alphabetical Index of Analytical Standards, Chemical Class, Alpha Sort, Analytical Standards, Analytical/Chromatography, Aromatics, Chromatography, D, DID - DIN, Environmental Standards, Nitro Compounds, Volatiles/ Semivolatiles
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Aromatics, Chemical Class, Chromatography, D, DID - DIN, Environmental Standards, Nitro Compounds, Volatiles/ Semivolatiles
  • {SNA} Building Blocks,

产品应用

  • 用于有机合成。测定蔗糖。

相关文献及参考

  • Short: II/25D
  • Merck: 14,3273 Beilstein:5(4)738
  • Merck: 14,3273
  • Short: II/27B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H300 Fatal if swallowed 吞食致命
  • H300+H310+H330
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P310+P330
  • P302+P350
  • P302+P352+P310+P361+P364
  • P304+P340+P310
  • P305+P351+P338+P337+P313
  • P308+P311
  • P337+P313
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Packing GroupII
UN Number 3443 UN 3443 6.1/PG 2
Risk Statements
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R50/53
RTECSCZ7450000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes 6.1 T+,N
Hazard Class6.1
Storage condition 储存温度2-8℃
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 250 ug/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

其他信息

  • 职业标准:TLV-TWA 0.15 PPM
  • Sigma Aldrich:528-29-0(sigmaaldrich)
  • 爆炸物危险特性:与氧化剂混合可爆
  • 储运特性:库房通风低温干燥; 与氧化剂分开存放
  • 上游原料:铜 --> 2-硝基苯胺 --> 氟硼酸钠
  • MSDS 信息:1,2-二硝基苯(528-29-0).msds
  • MOL 文件:528-29-0.mol
  • 急性毒性:口服- 猫 LD50: 29 毫克/ 公斤
  • 下游产品:1,3-二硝基苯
  • 海关编码:29042000
  • 用途一:用于有机合成。
  • 类别:易燃固体
  • 溶于乙醇、苯、氯仿、甲醇、甲苯、乙酸乙酯，不溶于水。能随水蒸气挥发。
  • 1,2-二硝基苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80054981 1，2-二硝基苯;邻二硝基苯 25g 413元 2011/04/16 D0818 1,2-二硝基苯 1,2-Dinitrobenzene 5G 790元
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
  • Alfa Aesar:1,2-Dinitrobenzene, 99%(528-29-0)
  • 图谱信息:1,2-二硝基苯(528-29-0)核磁图( 13 CNMR) 1,2-二硝基苯(528-29-0)红外图谱(IR2) 1,2-二硝基苯(528-29-0)红外图谱(IR3) 1,2-二硝基苯(528-29-0)Raman光谱 1,2-二硝基苯(528-29-0)质谱(MS) 1,2-二硝基苯(528-29-0)核磁图( 1 HNMR) 1,2-二硝基苯(528-29-0)红外图谱(IR1)
  • 灭火剂:水、干砂、二氧化碳、泡沫、1211灭火剂
  • TCI Shanghai:1,2-二硝基苯 1,2-Dinitrobenzene,>;98.0%(GC)(528-29-0)
  • 毒性分级:高毒
  • 用途二:用于有机合成。测定蔗糖。
  • 外观性质:无色到黄色片状结晶，有苦杏仁味，有挥发性。
  • 方法一:由邻硝基苯胺经重氮化、置换而得。将邻硝基苯胺加入盐酸溶液中溶解，在7℃以下滴加亚硝酸钠溶液。然后加入氟硼酸钠溶液，搅拌10min，过滤出邻硝基苯氟硼酸重氮盐，立即依次用冷的5%氟硼酸钠溶液、甲醇、乙醚洗涤。将其加入亚硝酸钠、铜粉、水的混合物中，一边慢慢加入，一边搅拌。然后用水蒸气蒸馏，馏出液冷却后滤出结晶，空气干燥，得邻二硝基苯。收率69%。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Application Specific Reagents - Analytical Reagents
  4. Fatty Acid Analysis in Blood - Application Specific Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DID - DIN - D

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