1,1-Diphenyl-2-picrylhydrazyl 2,2-联苯基-1-苦基肼基

CAS 1898-66-4 MFCD00007231

化学结构图

1898-66-4
SMILES: O=[N+]([O-])c1cc([N+](=O)[O-])c([N]N(c2ccccc2)c2ccccc2)c([N+](=O)[O-])c1

化学属性

Mol. FormulaC18 H12 N5 O6
Mol. Weight394.32
Melting Point~135 °C (dec.)(lit.)
TSCAYes
SolubilitySoluble in DMF, EtOH, chloroform, ether, carbon disulfinde, acetone, oils, carbon tetrachloride, glacial acetis acid, and toluene. Insoluble in water.
Stability对热敏感

别名和识别编码

Chemical Name1,1-Diphenyl-2-picrylhydrazyl
Synonym 1,1-二苯基-2-苦基肼自由基;1,1-二苯-2-苦基肼;2,2-二苯基-1-苦基肼;DPPH 1,1-二苯基-2-苦肼基自由基 1,1-二苯基-2-苦肼基自由基 2,2-二苯基-1-苦基肼 DPPH 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl 2,2-Diphenyl-1-picrylhydrazyl {} {} {} {} {} {} {} {} {} {} {} {} {} {hazard_com} Diphenylpicrylhydrazyl free radical {} {} {} {} {} {} {} {} {} {} {} {} {} {} {ALF} DPPH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {SNA} 2,2-联苯基-1-苦基肼基 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {SA} 2,2-二苯基-1-苦基肼 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemblink} 2,2-Diphenylpicrylhydrazyl; 1,1-Diphenyl-2-picrylhydrazyl radical; 2,2-Diphenyl-1-picrylhydrazyl
MDL NumberMFCD00007231
PubChem Substance ID172089145
Beilstein Registry Number16(2)363
CAS Number1898-66-4
EC Number217-591-8
Reaxys-RN1834478
Merck Number3330
Alfabeta NameDIPHENYLTRINITROPHENYLHYDRAZYLDPPH 221246(())-----,,,
Chemical Name Translation2,2-联苯基-1-苦基肼基
LabNetwork Molecule IDLN00183813
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分类

  • {SA} Chemical Synthesis, Picrylhydrazyl Derivatives, Radical Chemistry, Stable Radicals, Synthetic Reagents
  • {SNA} Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents TLC, Picrylhydrazyl Derivatives, Radical Chemistry, Stable Radicals, Steroids, Terpenes, Lipids, Bile acids, Synthetic Reagents, TLC Reagents, D-F, TLC Visualization Reagents (alphabetic sort), TLC Visualization Reagents (by application)

产品应用

  • A sensitive colormetric free radical scavenger.

相关文献及参考

  • Merck: 14,3330
  • Merck: 14,3330 Beilstein:16(2)363

安全信息

GHS Symbol
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P302+P352+P333+P313+P362+P364
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P403+P233
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Hazard statements
  • H242 Heating may cause a fire 加热可能会引起火灾
  • H302 Harmful if swallowed 吞食有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
Hazard Codes Xn
WGK Germany1
Signal word Danger
RTECSMW3250000
UN Number 3226 UN2811
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S24 Avoid contact with skin 避免皮肤接触；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R28 Very toxic if swallowed 吞咽极毒
  • R42/43
Packing GroupII
Warnings IRRITANT
Storage condition -20°C -20℃ 0-10 0-10°C 储存温度 2-8°C
Hazard Class4.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1800 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#06207

其他信息

  • DPPH, Free Radical is a cell-permeable, stable free radical that acts as a hydrogen radical scavenger. Originally developed to detect melanin metabolites in the urine of subjects with malignant melanoma, it has found numerous applications as a general antioxidant detector. Useful in inducing free-radical injury to tissues and as a screening tool for detecting free radical scavenging activity of antioxidants. The ability of a compound to decolorize DPPH free radical signifies the reactivity of the tested compound. Used in the quantitative determination of aliphatic and aromatic thiols by indirect spectroscopy and for photometric determination of tocopherol.

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Radical Chemistry - Synthetic Reagents
  4. Stable Radicals - Radical Chemistry
  5. Picrylhydrazyl Derivatives - Stable Radicals
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Radical Chemistry - Synthetic Reagents
  4. Stable Radicals - Radical Chemistry
  5. Picrylhydrazyl Derivatives - Stable Radicals

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