m-Nitrobenzoyl chloride 间硝基苯甲酰氯

CAS 121-90-4 MFCD00007247

化学结构图

121-90-4
SMILES: O=C(Cl)c1cccc([N+](=O)[O-])c1

化学属性

Mol. FormulaC7
Mol. Weight186
Boiling Point275-278
Melting Point31-34
Density1.42
Flash Point>110°(230°F)
TSCAYes
Solubility分解

别名和识别编码

Chemical Namem-Nitrobenzoyl chloride
Synonym m-nitro-benzoylchlorid 3-Nitrobenzoyl chloride m-Nitrobenzoyl chloride 3-NITROBENZOIC ACID CHLORIDE META NITRO BENZOYL CHLORIDE 间硝基苯甲酰氯 Benzoyl chloride, m-nitro- Benzoyl chloride, m-nitro- 3-nitro-benzoyl chloride 3-Nitrobenzoesäurechlorid 3-硝基苄氯 m-Nitrobenzoylchroride 3-nitrobenzoyl chloride 3-Nitrobenzoic acid chloride 間硝基苯甲醯氯 Benzoyl chloride, 3-nitro- Chlorid kyseliny m-nitrobenzoove M-NITROBENZOYL CHLORIDE m-Nitrobenzoyl ch 3-Nitrobenzoylchlorid 3-硝基苯甲酰氯 3-nitro-benzoylchlorid 3-NITROBENZOYL CHLORIDE chloridkyselinym-nitrobenzoove Benzoylchloride,3-nitro-
MDL NumberMFCD00007247
CAS Number121-90-4
EC Number204-505-9
Beilstein Registry Number9,381
PubChem Substance ID8495
Reaxys-RN777186
Chemical Name Translation间硝基苯甲酰氯
InChIKeyNXTNASSYJUXJDV-UHFFFAOYSA-N
Wiswesser Line NotationWNR CVG
LabNetwork Molecule IDLN00220239
InChIInChI=1S/C7H4ClNO3/c8-7(10)5-2-1-3-6(4-5)9(11)12/h1-4H
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carbonyl chloride; 1fragment
  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • Short: IV/20A Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20A Year: 1999 Keyword: organic compounds; vapor pressure ISBN: 3-540-64735-X ISBN: 978-3-540-64735-5 Internet Resource: DOI:10.1007/b71086 RefComment: VIII, 373 pages.
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure ISBN: 3-540-41060-0 ISBN: 978-3-540-41060-7 Internet Resource: DOI:10.1007/b88812 RefComment: VII, 197 pages
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSDM6646000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时，佩带适当的呼吸器；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupIII
UN Number 2923
Risk Statements
  • R5 Heating may cause an explosion 加热会引起爆炸
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R34 Causes burns 会导致灼伤
Storage condition Moisture Sensitive
Hazard Codes C
Hazard Class8/6.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2460 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 790 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 9(Suppl
   9),1,1987

Restrict 危险品

其他信息

  • F:9-19-21
  • 急性毒性:口服-大鼠 LD50: 2460 毫克/公斤
  • 灭火剂:二氧化碳、干粉
  • 毒性分级:低毒
  • 外观性质:黄色结晶或液体，具有刺鼻恶臭。
  • 用途一:用于医药、染料的制备，也用作彩色显影剂的中间体
  • 可燃性危险特性:可燃; 遇水放出有毒氯化氢气体
  • 方法一:由间硝基苯甲酸与光气反应而得。将间硝基苯甲酸、苯和少量二甲基甲酰胺混合后，加热至40-50℃，使之全部溶解。然后通光气至酰氯化完全，再通入氮气驱赶残余的光气。将反应产物蒸馏，回收溶剂苯，再减压蒸馏两次，得间硝基苯甲酰氯。此外，由间基苯甲酸与二氯亚砜加热回流3h，回收过量的二氯亚砜，减压蒸馏，收率153-154℃（1.6kPa）馏分，以90-98%的收率得到间硝基苯甲酰氯。
  • MOL 文件:121-90-4.mol
  • 间硝基苯甲酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0174 3-硝基苯甲酰氯 3-Nitrobenzoyl Chloride 25G 252元 2014/06/02 N0174 3-硝基苯甲酰氯 3-Nitrobenzoyl Chloride 500G 2030元 2010/06/21 155845000 间硝基苯甲酰氯 3-Nitrobenzoyl chloride 98% 500 GR 2507元
  • 用途二:用作医药、当杰彩色显影剂的中间体。
  • 海关编码:29163900
  • 上游原料:氧氯化硫 --> 苯 --> 间硝基苯甲酸
  • 类别:腐蚀物品
  • Sigma Aldrich:121-90-4(sigmaaldrich)
  • Acros Organics:间硝基苯甲酰氯 3-Nitrobenzoyl chloride, 98%(121-90-4)
  • Hazard Note:Corrosive
  • 爆炸物危险特性:遇热可爆
  • TCI Shanghai:间硝基苯甲酰氯 3-Nitrobenzoyl Chloride,>;98.0%(T)(121-90-4)
  • 图谱信息:间硝基苯甲酰氯(121-90-4)质谱(MS) 间硝基苯甲酰氯(121-90-4)红外图谱(IR1) 间硝基苯甲酰氯(121-90-4)核磁图( 13 CNMR)
  • Alfa Aesar:3-硝基苯甲酰氯,98% 3-Nitrobenzoyl chloride, 98%(121-90-4)
  • MSDS 信息:间硝基苯甲酰氯(121-90-4).msds
  • 敏感性:Moisture Sensitive
  • 储运特性:库房通风低温干燥; 与氧化剂、碱分开存放

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. Acyl halide
  2. acyl chloride

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