Bis(4-nitrophenyl) carbonate 4-硝基苯基碳酸酯

CAS 5070-13-3 MFCD00007322

化学结构图

5070-13-3
SMILES: O=C(Oc1ccc([N+](=O)[O-])cc1)Oc1ccc([N+](=O)[O-])cc1

化学属性

Mol. FormulaC13H8N2O7
Mol. Weight304.21
Melting Point136-139°C
Density1.422
TSCANo
Boiling Point475.9°C at 760 mmHg

别名和识别编码

Chemical NameBis(4-nitrophenyl) carbonate
Synonym 4,4'-Dinitrodiphenyl carbonate {LY} 4,4'-Dinitrodiphenyl carbonate {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {} {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {} {} {} {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dinitrodiphenyl carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dinitrodiphenyl
Beilstein Registry Number1892897
PubChem Substance ID78756
CAS Number5070-13-3
EC Number225-775-4
MDL NumberMFCD00007322
Chemical Name Translation4-硝基苯基碳酸酯
Reaxys-RN1892897
InChIKeyACBQROXDOHKANW-UHFFFAOYSA-N
LabNetwork Molecule IDLN00007170
InChIInChI=1S/C13H8N2O7/c16-13(21-11-5-1-9(2-6-11)14(17)18)22-12-7-3-10(4-8-12)15(19)20/h1-8H
Canonical SMILESO=C(OC1=CC=C([N+]([O-])=O)C=C1)OC2=CC=C([N+]([O-])=O)C=C2
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分类

  • Active Esters/Additives, Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Synthetic Reagents
  • {SNA} Active Esters/Additives, Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Synthetic Reagents

相关文献及参考

  • 1. R. Glatthard, M. Matter Helv. Chim. Acta 46 , 795, (1963)
  • 2. J.C. Tolle J. Am. Chem. Soc. 104 , 6883, (1982)
  • 3. J. Izdebski, D. Pawlak Synthesis , 423, (1989)
  • T. Wieland Justus Liebigs Ann. Chem. 655 , 189, (1962)
  • B. Piekarska-Bartos., A. Temeriusz Carbohydr. Res. 203 , 302, (1990)
  • Beil. 6 ,III,820
  • Fieser 1 ,330
  • FT-IR 1 (2), 318:A / FT-IR 2 (2), 2896:B / FT-NMR 1 (2), 1300:C / IR-Spectra (3), 1041:F / IR-Spectra (2), 911:A / NMR-Reference 2 (2), 304:C / RegBook 1 (2), 1935:E / Sigma FT-IR 1 (2), 790:B / Structure Index 1 , 311:D:3
  • Reagent for peptide coupling in the presence of triethylamine in DMF, via the p-nitrophenyl active ester: Liebigs Ann. Chem., 655, 189 (1962); Helv. Chim. Acta, 46, 795 (1963). See Appendix 6.
  • Has also been used as a coupling reagent in the synthesis of carbamate linked cytosine oligomers: J. Org. Chem., 52, 4202 (1987), and of ureido sugars: Carbohydr. Res., 203, 302 (1990).

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 二(对硝基苯)碳酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1481 碳酸双(4-硝基苯基)酯 Bis(4-nitrophenyl) Carbonate 5G 519元 2014/06/02 C1481 碳酸双(4-硝基苯基)酯 Bis(4-nitrophenyl) Carbonate 25G 1650元 2010/05/25 L00290 双(对硝基苯)碳酸酯,98% Bis(4-nitrophenyl) carbonate, 98% 5g 473元
  • 上游原料:二(三氯甲基)碳酸酯 --> 4-硝基苯酚
  • TCI Shanghai:二(对硝基苯基)碳酸酯 Bis(4-nitrophenyl) Carbonate,>;97.0%(LC)(5070-13-3)
  • 敏感性:Moisture Sensitive
  • 存储注意事项:湿度敏感
  • Sigma Aldrich:5070-13-3(sigmaaldrich)
  • MOL 文件:5070-13-3.mol
  • Alfa Aesar:双(对硝基苯)碳酸酯,98% Bis(4-nitrophenyl) carbonate, 98%(5070-13-3)
  • F:10-21
  • 检测方法:HPLC,NMR
  • 图谱信息:二(对硝基苯)碳酸酯(5070-13-3)质谱(MS) 二(对硝基苯)碳酸酯(5070-13-3)红外图谱(IR1) 二(对硝基苯)碳酸酯(5070-13-3)核磁图( 13 CNMR) 二(对硝基苯)碳酸酯(5070-13-3)核磁图( 1 HNMR) 二(对硝基苯)碳酸酯(5070-13-3)红外图谱(IR2) 二(对硝基苯)碳酸酯(5070-13-3)Raman光谱

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Coupling - Synthetic Reagents
  4. Active Esters/Additives - Coupling
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Peptide Coupling - Peptide Chemistry
  5. Active Esters/Additives - Peptide Coupling

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