4-Bromobenzenesulfonyl Chloride 4-溴苯磺酰氯

CAS 98-58-8 MFCD00007437

化学结构图

98-58-8
SMILES: O=S(=O)(Cl)c1ccc(Br)cc1

化学属性

Mol. FormulaC6H4BrClO2S
Mol. Weight255.52
Density1.422
Boiling Point153
Melting Point73-75
TSCAYes
Solubility分解
Flash Point152-154°C/26mm

别名和识别编码

Chemical Name4-Bromobenzenesulfonyl Chloride
CAS Number98-58-8
Synonym (4-Bromophenyl)chlorosulfone 1-(4-BROMO-BENZENESULFONYL)-4- METHYLPIPERAZINE 4-BROMOBENZENESULFONYL CHLORIDE 4-BROMOBENZENESUNFONYL CHLORIDE 4-Brombenzolsulfonylchlorid 4-Bromo-Benzenesulfonyl 4-Bromo-benzenesulfonyl chloride 4-Bromobenzenesulfonyl Chloride {Chemblink} 4-溴苯磺酰氯; 对溴苯磺酰氯 p-Brombenzol-sulfonylchlorid p-Brombenzolsulfochlorid p-Bromobenzenesulfonyl chloride Benzenesulfonylchloride,4-bromo- Brosyl chloride {} {SNA} 4-溴苯磺酰氯 {} {} {Chemicalbook} 4-溴苯磺酰基氯, 98+% {} {} {} {Chemicalbook} 4-溴苯磺酰( {} {} {} {} {uni_hamburg} 4-bromobenzenesulphonyl chloride {} {} {} {} {} {uni_hamburg} 4-bromobenzene sulfonylchloride {} {} {} {} {} {} {uni_hamburg} 4-bromo-benzene-sulfonyl chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {
EC Number202-683-2
Beilstein Registry Number743518
MDL NumberMFCD00007437
PubChem Substance ID87563569
Merck Number1407
Reaxys-RN743518
Chemical Name Translation4-溴苯磺酰氯
LabNetwork Molecule IDLN00008798
InChIInChI=1S/C6H4BrClO2S/c7-5-1-3-6(4-2-5)11(8,9)10/h1-4H
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分类

  • Sulfur & Selenium Compounds
  • Aromatics
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonyl Halides, Sulfur Compounds

产品应用

  • Used for identification of amines, and also in the synthesis and inhibition studies of substituted N-L-histidinylphenylsulfonyl hydrazide.

相关文献及参考

  • Short: III/35E
  • In the presence of potassium carbonate and a phase-transfer catalyst, N,N'-disubstituted ureas are dehydrated to carbodiimides in high yield: Synthesis, 520 (1987).
  • Alcohols are converted to 4-brombenzenesulfonate ("brosylate") esters with enhanced leaving group ability relative to the commoner tosylate; see, e.g.: Carbohydr. Res., 46, 53 (1976).
  • Merck: 14,1407
  • Short: III/20b
  • Abdo, M., et al.: Bioorg. Med. Chem., 15, 4427 (2007),
  • Merck: 14,1407 Beilstein:11,57
  • Teng, H., et al.: Biochemistry, 1999, 38, 7363 (1999),
  • Used in protection of amines as 4-bromobenzenesulfonamides: Synth. Commun., 18, 1615 (1988); Tetrahedron Lett., 30, 2399 (1989).

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Packing GroupII
UN Number 3261 UN 3261 8/PG 2
Storage condition +4°C Moisture Sensitive
Hazard Codes 8 C
Hazard Class8
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 外观性质:白色结晶。
  • 下游产品:苯基磺酰胺-4-硼酸 --> 4-(氨基磺酰基)苯硼酸
  • 灭火剂:二氧化碳、砂土、干粉
  • Hazard Note:Irritant
  • 海关编码:29049020
  • 可燃性危险特性:明火可燃; 受热分解释出有毒溴化物和氮氧化物气体; 遇水放出毒雾
  • Sigma Aldrich:98-58-8(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与食品原料、氧化剂分开储运
  • MOL 文件:98-58-8.mol
  • TCI Shanghai:4-溴苯磺酰氯 4-Bromobenzenesulfonyl Chloride,>;98.0%(T)(98-58-8)
  • MSDS 信息:4-溴苯磺酰氯(98-58-8).msds
  • 图谱信息:4-溴苯磺酰氯(98-58-8)Raman光谱 4-溴苯磺酰氯(98-58-8)质谱(MS) 4-溴苯磺酰氯(98-58-8)核磁图( 1 HNMR) 4-溴苯磺酰氯(98-58-8)核磁图( 13 CNMR) 4-溴苯磺酰氯(98-58-8)红外图谱(IR1) 4-溴苯磺酰氯(98-58-8)红外图谱(IR2)
  • Acros Organics:4-溴苯磺酰氯 4-Bromobenzenesulfonyl chloride, 98%(98-58-8)
  • 用途一:用作农药、医药中间体
  • 4-溴苯磺酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010310 对溴苯磺酰氯 50g 300元 2011/04/16 B0550 4-溴苯磺酰氯 4-Bromobenzenesulfonyl Chloride 500G 5990元 2011/04/16 B0550 4-溴苯磺酰氯 4-Bromobenzenesulfonyl Chloride 25G 711元
  • 敏感性:Moisture Sensitive
  • Alfa Aesar:4-溴-苯磺酰氯,98+% 4-Bromobenzenesulfonyl chloride, 98+%(98-58-8)
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Gallium - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonyl Halides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonium/Sulfoxonium Compounds
  1. sulfonyl halide

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