Metanil yellow 间胺黄

CAS 587-98-4 MFCD00007486

化学结构图

587-98-4
SMILES: O=S(=O)(O)c1cccc(/N=N/c2ccc(Nc3ccccc3)cc2)c1.[NaH]

化学属性

Mol. FormulaC18H14N3NaO3S
Mol. Weight375
TSCAYes
Appearance 黄色粉末。易溶于水,呈橙黄色,加入盐酸呈红色并产生沉淀,加入氢氧化钠溶液颜色不变,但过量后有沉淀产生。易溶于乙醇、乙醚、苯和乙二醇乙醚,微溶于丙酮。于浓硫酸中呈紫色,稀释后有红色沉淀产生;于浓硝酸中呈蓝色,后逐渐变为橙色。染色时遇铜离子色泽暗绿;遇铁离子色泽较浅;遇铬离子色泽略有变化。

别名和识别编码

Chemical NameMetanilyellow
MDL NumberMFCD00007486
CAS Number587-98-4
Synonym 11363 Yellow 3-((4-(phenylamino)phenyl)azo)-benzenesulfonicacimonosodiumsalt 3-(4-ANILINOPHENYLAZO)BENZENESULFONIC ACID SODIUM SALT 3-(4-Anilinophenylazo)benzenesulfonic acid, Acid yellow 36 3-(4-苯胺基苯偶氮基)苯磺酸 钠盐 3-[[4 Acid Leather Yellow PRW Acid Metanil Yellow Acid Yellow 36 AcidgoldenyellowG Acidic Metanil Yellow Aizen Metanil Yellow C.I. 13065 C.I. Acid Yellow 36 C.I. Acid Yellow 36 monosodium salt C.I.酸性黄36 Calcocid Yellow MXXX Diacid Metanil Yellow E KI KITON ORANGE MNO Kiton Orange MNO METANIL YELLOW METANIL YELLOW ORANGE Metanil Yellow Metanil Yellow 1955 Metanil Yellow Extra Metanil Yellow Griesbac
PubChem Substance ID3935589
Beilstein Registry Number3831568
EC Number209-608-2
Merck Number5928
Reaxys-RN9824778
Chemical Name Translation间胺黄
Wiswesser Line NotationWSO&R CNUNR DMR &-NA-
LabNetwork Molecule IDLN00195671
InChIInChI=1S/C18H15N3O3S.Na/c22-25(23,24)18-8-4-7-17(13-18)21-20-16-11-9-15(10-12-16)19-14-5-2-1-3-6-14;/h1-13,19H,(H,22,23,24);/q;+1/p-1
Canonical SMILESO=S(C1=CC=CC(/N=N/C2=CC=C(NC3=CC=CC=C3)C=C2)=C1)(O[Na])=O
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分类

  • {SNA} All Alphabetically Sorted, All alphabetical sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Aromatics, Chemical Class, Chromatography, Colors, Food & Beverage Standards, Food Color Additives, M, META - METH, Other banned artificial food dyes, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009)
  • {SNA} Cell Biology, Hematology and Histology, M, Stains & Dyes, A to Z, Stains and Dyes
  • {SNA} M, Stains & Dyes, A to Z, Stains and Dyes, 细胞生物学,

相关文献及参考

  • Merck:14,5928 Beilstein:16,330

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H303 May be harmfully swallowed 吞食可能有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSDB7329500
Precautionary statements
  • P203
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P333+P313+P362+P364
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P318
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P317
  • P333+P313
  • P333+P317
  • P337+P313
  • P337+P317
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R52/53
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Hazard Codes Xi
Storage condition 2-8°C, protect from light 密封阴凉干燥保存。
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1310,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1310,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SRTCDF Scientific Report.  (Dr. C.R. Krishna Murti, Director, Industrial
   Toxicology Research Centre, Luchnow-226001, India)  History unknown.
   Volume(issue)/page/year: -,11,1977

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 22 nmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 249,265,1991

TYPE OF TEST            : Sister chromatid exchange
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 5 mg/kg
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   31,299,1986

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Leukocyte
DOSE/DURATION           : 10 umol/L
REFERENCE :
   IJEBA6 Indian Journal of Experimental Biology.  (Publications & Information
   Directorate, CSIR, Hillside Rd., New Delhi 110 012, India)  V.1-    1963-
   Volume(issue)/page/year: 16,820,1978

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 60 mg/kg/30D (Continuous)
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   30,315,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 162 gm/kg
SEX/DURATION            : male 90 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 15,227,1978

其他信息

  • TCI Shanghai:酸性间胺黄 Metanil Yellow(587-98-4)
  • 图谱信息:丫啶黄(587-98-4)红外图谱(IR1) 丫啶黄(587-98-4)红外图谱(IR2)
  • 丫啶黄价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 71024260 皂黄 25g 60元 2011/04/16 M0490 酸性黄 36 Acid Yellow 36 500G 1350元 2011/04/16 M0490 酸性黄 36 Acid Yellow 36 25G 233元
  • 上游原料:3-氨基苯磺酸 --> 二苯胺
  • Sigma Aldrich:587-98-4(sigmaaldrich)
  • 方法一:以间氨基苯磺酸和二苯胺为原料,将间氨基苯磺酸重氮化,与二苯胺偶合得产物。经盐析、过滤、干燥、粉碎得成品。。
  • 用途二:酸性金黄 G 可用于羊毛染色及羊毛、蚕丝织物的直接印花,还可与酸性嫩黄 2G、酸性红 G 拼染金黄色。多用于肥皂着色,也用于纸张、皮革、油漆、医药、化妆品的着色,以及用于制造色淀颜料。还被用作酸碱指示剂(pH=1-3)。
  • Alfa Aesar:间胺黄 Metanil Yellow(587-98-4)
  • MOL 文件:587-98-4.mol
  • Acros Organics:丫啶黄/间胺黄 Metanil Yellow, pure, 98%(587-98-4)
  • 色指数:13065
  • 下游产品:对氨基二苯胺
  • 溶于水,溶于醇,中度溶于苯和醚,微溶于丙酮,指示剂范围pH 1.2-2.3
  • 用途一:主要用于肥皂的着色和毛、丝、皮革、纸张等的染色

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