Methyl methanethiosulfonate 甲基硫代磺酸甲酯

CAS 2949-92-0 MFCD00007565

化学结构图

2949-92-0
SMILES: CSS(C)(=O)=O

化学属性

Mol. FormulaC2H6O2S2
Mol. Weight126.20
Refractive index1.5110 to 1.5180
Boiling Point69-71 °C at 0.4 mmHg
Density1.337
Flash Point87°C(lit.)
Melting Point117.0-119.0 °C

别名和识别编码

Chemical NameS-Methyl methanethiolsulfonate
CAS Number2949-92-0
Alfabeta NameMETHYLMETHANESULFONOTHIOATE S-
MDL NumberMFCD00007565
Synonym S-Methyl methanesulfonothioate {LY} S-Methyl methanesulfonothioate methyl methanesulfonothioate methyl methanethiolsulfonate methyl methanethiosulfonate {} {LY} S-Methyl methanesulfonothioate {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {} {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {} {} {} {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {} {} {} {} {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {} {} {} {} {} {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {} {} {} {} {} {} {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {} {} {} {} {} {} {} {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} S-Methyl methanesulfonothioate {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID18064
EC Number220-970-0
Beilstein Registry Number1446059
Reaxys-RN1446059
Chemical Name Translation甲基硫代磺酸甲酯
LabNetwork Molecule IDLN00160035
InChIInChI=1S/C2H6O2S2/c1-5-6(2,3)4/h1-2H3
Canonical SMILESO=S(SC)(C)=O
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分类

  • MTS & Sulfhydryl Active Reagents
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonates/Sulfinates, Sulfur Compounds

产品应用

  • Used for the rapid and selective modification of sulfhydryl groups of enzymes. Useful for mapping the pore-lining regions of the ryanodine receptor.

相关文献及参考

  • ########
  • 1. J. Org. Chem. 58 , 6132, (1993)
  • 2. Synth. Commun. 22 , 1359, (1992)
  • 3. J. Chem. Soc. Perkin Trans. I , 3167, (1993)
  • 4. Chem. Commun. , 2075, (2007) 摘要
  • Beil. 4 ,IV,31
  • Fieser 5 ,454 / Fieser 7 ,243 / Fieser 12 ,325
  • Aldrich MSDS 1 , 1269:C / Corp MSDS 1 (2), 2379:A / FT-IR 1 (1), 881:A / FT-IR 2 (1), 1521:A / FT-NMR 1 (1), 1440:A / IR-Spectra (3), 530:B / NMR-Reference 2 (2), 800:A / RegBook 1 (1), 1069:B / Sigma FT-IR 1 (2), 741:A / Structure Index 1 , 166:B:3
  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oils, paraffins and polyethylenes; Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds. The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005. The calculated values of diamagnetic susceptibility of organic compounds in the present subvolume II/27B are presented along with their experimental values. They have been calculated with the use of st

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany2
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 9
RTECSPB2765000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P302+P350
  • P302+P352
  • P302+P352+P312+P361+P364
  • P304+P340
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number 2810 3334
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Class6.1
Packing GroupIII 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 9110 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   72,513,1984

其他信息

  • Acros Organics:S-甲基甲烷硫代磺酸酯 S-Methyl methanethiolsulfonate, 97%(2949-92-0)
  • TCI Shanghai:甲硫基甲基砜 S-Methyl Methanethiosulfonate,>;95.0%(GC)(2949-92-0)
  • 甲基硫代磺酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1382 甲烷硫代磺酸S-甲酯 S-Methyl Methanethiosulfonate 25G 1560元 2010/06/21 197390010 甲基硫代磺酸甲酯 S-Methyl methanethiolsulfonate 97% 1 GR 282元 2010/06/21 197390050 甲基硫代磺酸甲酯 S-Methyl methanethiolsulfonate 97% 5 GR 896元
  • MOL 文件:2949-92-0.mol
  • F:13
  • Sigma Aldrich:2949-92-0(sigmaaldrich)
  • 图谱信息:甲基硫代磺酸甲酯(2949-92-0)质谱(MS) 甲基硫代磺酸甲酯(2949-92-0)红外图谱(IR1) 甲基硫代磺酸甲酯(2949-92-0)核磁图( 13 CNMR)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiol/Mercaptan Salts - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonates/Sulfinates - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonates/Sulfinates - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonamides/Sulfinamides
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfur Compounds for Organic Synthesis 有机合成硫化物

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