Methyl vinyl sulfone 甲基乙烯基砜

CAS 3680-02-2 MFCD00007567

化学结构图

3680-02-2
SMILES: C=CS(C)(=O)=O

化学属性

Mol. FormulaC3H6O2S
Mol. Weight106.14
Refractive indexn20/D 1.463(lit.)
Boiling Point115-117 °C/19 mmHg(lit.)
Density1.212 g/mL at 25 °C(lit.)
Flash Point>109°(228°F)
TSCANo

别名和识别编码

Chemical NameVinyl methyl sulfone
CAS Number3680-02-2
PubChem Substance ID19354
EC Number222-958-0
MDL NumberMFCD00007567
Synonym Methyl vinyl sulfone {LY} Methyl vinyl sulfone methyl vinyl sulfone {} {LY} Methyl vinyl sulfone {} {} {LY} Methyl vinyl sulfone {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {} {} {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {} {} {} {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl vinyl sulfone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl vinyl sulfone
Beilstein Registry Number0878198
Chemical Name Translation甲基乙烯基砜
Wiswesser Line NotationWS1&1U1
InChIKeyWUIJTQZXUURFQU-UHFFFAOYSA-N
LabNetwork Molecule IDLN01995744
Canonical SMILESO=S(C=C)(C)=O
InChIInChI=1S/C3H6O2S/c1-3-6(2,4)5/h3H,1H2,2H3
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分类

  • {SNA} Building Blocks, Chemical Synthesis, M, Organic Building Blocks, Sulfones, Sulfur Compounds, 生物活性小分子, 细胞生物学
  • {SNA} Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, M, Organic Building Blocks, Sulfones, Sulfur Compounds
  • Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, M, Organic Building Blocks,
  • {uni_hamburg} no charge; sulfone; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfones, Sulf

相关文献及参考

  • 1. Synthesis , 3495, (2006)
  • Beil. 1 ,III,1866
  • Corp MSDS 1 (2), 2463:D / FT-IR 2 (1), 1495:B / FT-IR 1 (1), 881:D / FT-NMR 1 (1), 1420:A / NMR-Reference 2 (2), 783:C / RegBook 1 (1), 1045:A / Sax 6 , 1944 / Structure Index 1 , 162:C:4 / Vapor Phase 3 , 831:C
  • Short: II/24B Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24B Year: 2000 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-65345-7 ISBN: 978-3-540-65345-5 Internet Resource: DOI:10.1007/b58835 RefComment: VIII, 525 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24B contains an introduction and tables of rotational and centrifugal distortion constants of asymmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • {uni_
  • For use of vinyl sulfones in the Diels-Alder reaction, see: J. Am. Chem. Soc., 102, 853 (1980); Tetrahedron Lett., 23, 5127 (1982); J. Org. Chem., 48, 141 (1983).

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T+ T+,T,Xi
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H310 Fatal in contact with skin 皮肤接触致命
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSWR6825000
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P350
  • P302+P352
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number UN2810 UN 2810 6.1/PG 1 2810
Risk Statements
  • R27 Very toxic in contact with skin 与皮肤接触极毒
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupI
Hazard Class6.1
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 570 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 32 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 1 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 245,191,1990

其他信息

  • 图谱信息:甲基乙烯砜(3680-02-2)核磁图( 1 HNMR) 甲基乙烯砜(3680-02-2)核磁图( 13 CNMR) 甲基乙烯砜(3680-02-2)质谱(MS) 甲基乙烯砜(3680-02-2)红外图谱(IR1)
  • 甲基乙烯砜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 306730100 甲基乙烯砜 Methyl vinyl sulfone 98%, stabilized 10 GR 1834元 2010/06/21 306730010 甲基乙烯砜 Methyl vinyl sulfone 98%, stabilized 1 GR 288元 2010/06/21 306730500 甲基乙烯砜 Methyl vinyl sulfone 98%, stabilized 50 GR 7328元
  • Acros Organics:甲基乙烯基砜 Methyl vinyl sulfone, stabilized, 98%(3680-02-2)
  • Sigma Aldrich:3680-02-2(sigmaaldrich)
  • Alfa Aesar:甲基乙烯砜,98%,stab.with200ppm4-t-butylphenol Methyl vinyl sulfone, 98%, stab. with 200ppm 4-tert-butylphenol(3680-02-2)
  • MOL 文件:3680-02-2.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfones - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonates/Sulfinates

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