2-Nitrophenylhydrazine 2-硝基苯肼

CAS 3034-19-3 MFCD00007577

化学结构图

3034-19-3
SMILES: NNc1ccccc1[N+](=O)[O-]

化学属性

Mol. FormulaC6H7N3O2
Mol. Weight153.14
Melting Point91-93 °C (lit.)
TSCANo
Density1.419
Stability对光敏感
Solubility微溶于水，溶于乙醇、乙醚。

别名和识别编码

Chemical Name2-Nitrophenylhydrazine
Beilstein Registry Number512797
PubChem Substance ID3314739
CAS Number3034-19-3
EC Number221-222-6
MDL NumberMFCD00007577
Reaxys-RN512797
Synonym (2'-nitrophenyl)hydrazine (2-Nitro-phenyl)-hydrazine (2-Nitrophenyl)-hydrazin (2-Nitrophenyl)hydrazine (Contains ~30-40% water as stabilizer) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} o-Nitrophenythydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} O-NITROPHENYLHYDRAZINE {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} Hydrazine, (2-nitrophenyl)- {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} o-Nitrophenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {SNA} 2-硝基苯肼 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} 2-硝基苯基肼
Alfabeta NameNITROPHENYLHYDRAZINE 2()-
Chemical Name Translation2-硝基苯肼
Wiswesser Line NotationZMR BNW
InChIKeyFRBUNLLUASHNDJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00183531
InChIInChI=1S/C6H7N3O2/c7-8-5-3-1-2-4-6(5)9(10)11/h1-4,8H,7H2
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分类

  • Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 有机合成。

相关文献及参考

  • Beilstein:15(3)316
  • Short: EINECS
  • Short: III/35E
  • Reagent for colorimetric determination of aldehydes and ketones.

安全信息

Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P302+P352+P332+P313+P362+P364
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P403+P235
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P420 Store away from other materials. 远离其他材料。
  • P305+P351+P338+P337+P313
  • P234 Keep only in original container. 只保留在原来的容器中。
WGK Germany3
Signal word Danger
Hazard statements
  • H228 Flammable solid 易燃固体
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H242 Heating may cause a fire 加热可能会引起火灾
Hazard Codes Xi F,Xn 4.1
GHS Symbol
RTECSMV8210000
UN Number 3224 UN1325 UN 1325 4.1/PG 2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
Packing GroupII
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R5 Heating may cause an explosion 加热会引起爆炸
  • R22 Harmful if swallowed 吞咽有害
Storage condition +4°C 2-8°C Light Sensitive 避光保存。
Warnings IRRITANT 危化品目录(2015) 危险化学品
Hazard Class4.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 178 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00632

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 4 mmol/L
REFERENCE :
   AEMIDF Applied and Environmental Microbiology.  (American Soc. for
   Microbiology, 1913 I St., NW, Washington, DC 20006)  V.31-    1976-
   Volume(issue)/page/year: 44,801,1982

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 7 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 173,233,1986

其他信息

  • 溶于热水，微溶于乙醇、乙醚、苯和石油英。易燃。加热时爆炸。有刺激性。
  • Alfa Aesar:15% water(3034-19-3)" href="http://www.alfa.com/zh/GP100w.pgm?DSSTK=L02203&CAS;=3034-19-3">2-硝基苯基肼,97% 2-Nitrophenylhydrazine, 97% (dry wt.), stab. with >15% water(3034-19-3)
  • 可燃性危险特性:遇明火可燃;燃烧产生有毒氮氧化物烟雾；与氧化剂反应
  • 毒性分级:中毒
  • 类别:有毒物品
  • 2-硝基苯肼价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0413 2-硝基苯肼 2-Nitrophenylhydrazine 25G 1640元 2014/06/02 N0413 2-硝基苯肼 2-Nitrophenylhydrazine 5G 497元 2010/06/21 128830100 2-硝基苯肼 2-Nitrophenylhydrazine 97%, moistened with ca 30% water 10 GR 638元
  • 外观性质:桔红色粉末。
  • MSDS 信息:2-硝基苯肼(3034-19-3).msds
  • Sigma Aldrich:3034-19-3(sigmaaldrich)
  • 急性毒性:静脉-小鼠LD50： 178 毫克/公斤
  • F:4.6-8
  • 灭火剂:二氧化碳、泡沫、砂土、雾状水、干粉
  • Acros Organics:2-硝基苯肼 2-Nitrophenylhydrazine, moistened with ca 30% water, 97%(3034-19-3)
  • 图谱信息:2-硝基苯肼(3034-19-3)红外图谱(IR1) 2-硝基苯肼(3034-19-3)质谱(MS) 2-硝基苯肼(3034-19-3)核磁图( 13 CNMR) 2-硝基苯肼(3034-19-3)核磁图( 1 HNMR)
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • 敏感性:Light Sensitive
  • MOL 文件:3034-19-3.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Guanidines

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