Methyl carbazate 肼基甲酸甲酯

CAS 6294-89-9 MFCD00007594

化学结构图

6294-89-9
SMILES: COC(=O)NN

化学属性

Mol. FormulaC2H6N2O2
Mol. Weight90.08
Boiling Point108 °C at 12 mmHg
Melting Point70-73°C
TSCAYes
Density1.161
Solubility可溶
Appearance 白色晶体,熔点72-76℃,沸点 108℃,可溶于水。

别名和识别编码

Chemical NameMethyl carbazate
Synonym Methyl hydrazinecarboxylate {LY} Methyl hydrazinecarboxylate {} {LY} Methyl hydrazinecarboxylate {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {} {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {} {} {} {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl hydrazinecarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl hydrazinecarbo
MDL NumberMFCD00007594
PubChem Substance ID87566129
CAS Number6294-89-9
EC Number228-560-3
Reaxys-RN1679395
Beilstein Registry Number1679395
Chemical Name Translation肼基甲酸甲酯
LabNetwork Molecule IDLN00111026
InChIInChI=1S/C2H6N2O2/c1-6-2(5)4-3/h3H2,1H3,(H,4,5)
Canonical SMILESNNC(OC)=O
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分类

  • {SNA} Building Blocks, Carbonyl Compounds, Chemical Synthesis, Hydrazides, Organic Building Blocks
  • Building Blocks, Carbonyl Compounds, Chemical Synthesis, Hydrazides, Organic Building Blocks
  • {uni_hamburg} no charge; carbamate; 1fragment

相关文献及参考

  • Short: II/19c
  • Alternatively, reaction of the diazene intermediate with MeI and LiOMe yields the ɑ-methylnitrile: J. Org. Chem., 42, 2001 (1977).
  • Can be used in a sequence for converting ketones to homologated nitriles: Org. Synth. Coll:, 6, 334 (1988):
  • Short: II/19b
  • Beilstein:3(1)46

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P350
  • P302+P352
  • P302+P352+P312+P361+P364
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301+H311+H331
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes 6.1 T;Xi Xi,T
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Danger
UN Number 2811
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时,佩带适当的呼吸器;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupIII
Hazard Class6.1
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 肼基甲酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010158 肼基甲酸甲酯 100g 360元 2011/04/16 C1098 肼基甲酸甲酯 Methyl Carbazate 25G 270元 2011/04/16 C1098 肼基甲酸甲酯 Methyl Carbazate 500G 2050元
  • 溶于水,溶于乙醇、醚和苯;实际上不溶于石油醚。
  • Acros Organics:甲氧基羰酰肼 Methyl hydrazinocarboxylate, 97%(6294-89-9)
  • TCI Shanghai:肼基甲酸甲酯 Methyl Carbazate,>;98.0%(GC)(T)(6294-89-9)
  • MSDS 信息:Methoxycarbonylhydrazine(6294-89-9).msds
  • Alfa Aesar:卡巴肼甲酯,98% Methyl carbazate, 98%(6294-89-9)
  • 下游产品:肼基甲酸乙酯
  • Sigma Aldrich:6294-89-9(sigmaaldrich)
  • MOL 文件:6294-89-9.mol

系列性分类


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