2-Chloro-4-nitroaniline 2-氯-4-硝基苯胺

CAS 121-87-9 MFCD00007665

化学结构图

121-87-9
SMILES: Nc1ccc([N+](=O)[O-])cc1Cl

化学属性

Mol. FormulaC6H5ClN2O2
Mol. Weight173
Density1.494
Autoignition Point971 °F
Melting Point105-108
Flash Point193°(379°F)
TSCAYes
Boiling Point200°C(lit.)
Solubility0.23 G/L (20 ºC)
Stability对湿度敏感

别名和识别编码

Chemical Name2-Chloro-4-nitroaniline
CAS Number121-87-9
Alfabeta NameCHLORONITROANILINE 24---
MDL NumberMFCD00007665
Synonym 1-Amino-2-chloro-4-nitrobenzene 2-/-4-CHLORONITROANILIN 2-CHLORO-4-NITRO-PHENYLAMINE 2-Chloro-4-nitro-phenylamine 2-chloro-4-nitro-aniline 4-CHLORO-2-NITROANILINE, 1000MG, NEAT 4-氨基-3-氯硝基苯 o-Chloro-p-nitroaniline Aniline, 2-chloro-4-nitro- Benzenamine, 2-chloro-4-nitro- Benzenamine,2-chloro-4-nitro- LABOTEST-BB LT00030789 O-CHLORO-P-NITRO ANILINE o-chloro-nitroaniline orthoChloro-p-Nitroaniline
EC Number204-502-2
Beilstein Registry Number638657
PubChem Substance ID87565376
Chemical Name Translation2-氯-4-硝基苯胺
Reaxys-RN638657
Wiswesser Line NotationZR BG DNW
LabNetwork Molecule IDLN00173441
InChIInChI=1S/C6H5ClN2O2/c7-5-3-4(9(10)11)1-2-6(5)8/h1-3H,8H2
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Amines, Building Blocks, C6, Chemical Synthesis, Materials Science, NLO Chromophores and Intermediates, Nitrogen Compounds, Non-Linear Optical (NLO) Materials, Organic Building Blocks, Organic and Printed Electronics, Photonic and Optical Materials
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines,

相关文献及参考

  • Short: EINECS
  • Short: III/5a
  • Beilstein:12,732
  • Short: III/35B

安全信息

Warnings IRRITANT 危化品目录(2015) 危险化学品
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24 Avoid contact with skin 避免皮肤接触;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R51/53
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSBX1400000
Packing GroupIII
UN Number 2237
Hazard Codes 6.1 Xn,N Xn;N
Storage condition 密封保存。
Hazard Class6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 6,138,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6430 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 25(8),50,1981

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Behavioral - changes in motor activity (specific assay)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   CBCCT* "Summary Tables of Biolo

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

其他信息

  • MSDS 信息:2-氯-4-硝基苯胺(121-87-9).msds
  • Acros Organics:2-氯-4-硝基苯胺 2-Chloro-4-nitroaniline, 99%(121-87-9)
  • 图谱信息:2-氯-4-硝基苯胺(121-87-9)红外图谱(IR1) 2-氯-4-硝基苯胺(121-87-9)核磁图( 13 CNMR) 2-氯-4-硝基苯胺(121-87-9)质谱(MS)
  • Sigma Aldrich:121-87-9(sigmaaldrich)
  • 下游产品:4-氨基-2-氯三氟甲苯 --> 2-氯-4-硝基三氟甲苯 --> 2-氯-4-氨基苯胺 --> 2-氯-1-碘-4-硝基苯 --> 分散红玉S-2GFL --> 颜料红 4 --> 分散大红S-3GFL --> 氯硝柳胺 --> 分散橙 44 --> 2-氯-1,4-苯二胺硫酸盐 --> 分散黄SE-5R
  • 用途三:染料和颜料的中间体,主要用于生产颜料银硃R及分散染料红GFL、分散红B等,也用于生产灭钉螺农药。以及用作医药中间体,如制取血防-67糊剂。
  • 外观性质:黄色结晶粉末。
  • 可燃性危险特性:明火可燃; 与氧化剂反应; 高热或接触酸放出氯化物及氮氧化物气体
  • Alfa Aesar:2-氯-4-硝基苯胺,98+% 2-Chloro-4-nitroaniline, 98+%(121-87-9)
  • 毒性分级:中毒
  • 2-氯-4-硝基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0214 2-氯-4-硝基苯胺 2-Chloro-4-nitroaniline 25G 111元 2014/06/02 C0214 2-氯-4-硝基苯胺 2-Chloro-4-nitroaniline 500G 657元 2010/06/21 146510050 2-氯-4-硝基苯胺 2-Chloro-4-nitroaniline 99% 5 GR 273元
  • 溶于乙醇、乙醚、苯和二硫化碳,溶解度: 0.23 g/l水 (20°C) ,微溶于水、50%乙酸和强酸,不溶于石油醚。
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • 用途一:用作有机颜料及分散染料的中间体
  • 用途二:用于有机合成,也用作染料中间体
  • 类别:有毒物质
  • 急性毒性:口服- 大鼠 LD50:6430 毫克/ 公斤; 口服- 小鼠 LD50:1250 毫克/ 公斤
  • 方法一:对硝基苯胺加盐酸和次氯酸钠进行氯化反应。反应产物经过滤、洗涤、干燥,得成品。原料消耗定额:对硝基苯胺928kg/t、次氯酸钠(10%)5600kg/t、30%盐酸5600kg/t。
  • MOL 文件:121-87-9.mol
  • 上游原料:盐酸 --> 氯 --> 次氯酸钠 --> 4-硝基苯胺
  • 灭火剂:雾状水、泡沫、二氧化碳、砂土
  • TCI Shanghai:2-氯-4-硝基苯胺 2-Chloro-4-nitroaniline,>;98.0%(GC)(121-87-9)

系列性分类


相关产品推荐