3-Nitroaniline Solution 间硝基苯胺标准溶液

CAS 99-09-2 MFCD00007782

化学结构图

99-09-2
SMILES: Nc1cccc([N+](=O)[O-])c1

化学属性

Mol. FormulaC6H6N2O2
Mol. Weight138
Melting Point112.0 to 114.0 deg-C
Density0.9011
TSCAYes
Boiling Point306℃
Vapor Pressure1 mmHg ( 119 °C)
Flash Point196 ºC
Solubility1.25 G/L
Stability对光敏感

别名和识别编码

Chemical Name3-Nitroaniline Solution
CAS Number99-09-2
PubChem Substance ID87573505
EC Number202-729-1
Beilstein Registry Number12,698
MDL NumberMFCD00007782
Merck Number6581
Synonym amartholfastorangerbase 3-Nitrophenylamine Amarthol Fast Orange R Base 3-NITROANILINE meta< Orange Base Irga I 1-amino-3-nitrobenzene Hiltonil Fast Orange R Base m-Aminonitrobenzene 3-nitro-Benzenamine 3-Aminonitrobenzene aniline, m-nitro- 4,4'-亚甲基联苯胺 aniline,m-nitro- Azobase MNA 5-nitroaniline 3-Nitro-phenylamine 间氨基硝基苯 m-Nitroaminobenzene benzenamine, 3-nitro C.I. 37030 Fast Orange R Base azobasemna m-Nitranilin Aniline, m-nitro- FAST ORANGE BASE R Daito Orange Base R 3-Nitroaniline m-Aminonitrobenzene 3-nitrophenylamine Orange Base IRGA I C.I. Azoic Diazo Component 7 m-Nitrophenylamine 3-硝基苯胺,98% 1-氨基-3-硝基苯 Devol Orange R Naphtoelan Orange R Base 1-AMINO-3-NITROBENZENE 3-硝基苯胺,1-氨基-3-硝基苯 3-Nitroaminobenzol 3-硝基苯胺 3-nitro-aniline Nitranilin M-NITRANILINE m-nitroaniline Diazo Fast Orange R 3-Nitro-benzenamine m-Nitroaminobenzene 3-nitro-benzenamin 3-Nitrobenzenamine LABOTEST-BB LTBB000465 3-nitroaniline 3-Nitrobenzeneamine Fast Orange R Salt Benzenamine, 3-nitro- M-NITROANILINE {A 間硝苯胺 1-Amino-3-nitrobenzene Fast Orange Base R AURORA KA-7785
Chemical Name Translation间硝基苯胺标准溶液
Wiswesser Line NotationZR CNW
LabNetwork Molecule IDLN00193204
Reaxys-RN636962
InChIInChI=1S/C6H6N2O2/c7-5-2-1-3-6(4-5)8(9)10/h1-4H,7H2
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分类

  • {SNA} Amines, Building
  • Alpha Sort, Alphabetic, Amines, Analytical Standards, Analytical/Chromatography, Aromatics, Chemical Class, Chromatography, Environmental Standards, N, N-O, NA - NI, Volatiles/ Semivolatiles
  • {SNA} Amines, Building Blocks, C6, Chemical Synthesis, Materials Science, NLO Chromophores and Intermediates, Nitrogen Compounds, Non-Linear Optical (NLO) Materials, Organic Building Blocks, Organic and Printed Electronics, Photonic and Optical Materials
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 用作染料中间体及及用于有机合成，也用于松木颜色的检验,酸碱指示剂，pH6.8(无色)-8.6(黄)。

相关文献及参考

  • Merck 14 ,6582
  • Beil. 12 ,IV,1589
  • Aldrich MSDS 1 , 1353:A / Corp MSDS 1 (2), 2550:A / FT-IR 2 (2), 2265:D / FT-IR 1 (1), 1337:A / FT-NMR 1 (2), 691:A / IR-Spectra (3), 808:B / IR-Spectra (2), 709:A / NMR-Reference 2 (1), 1139:A / RegBook 1 (1), 1557:E / Sax 6 , 2006 / Structure Index 1 , 242:A:7 / Vapor Phase 3 , 1189:B
  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oils, paraffins and polyethylenes; Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds. The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005. The calculated values of diamagnetic susceptibility of organic compounds in the present subvolume II/27B are presented along with their experimental values. They have been calculated with the use of structural parameters in structural formula by using different theoretical methods available in the literature.
  • Short: II/27C Title: Diamagnetic Susceptibility and Magnetic Anisotropy of Organic Compounds Author: Kumar, Mahendra; Gupta, Rajni Editor: Gu

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H331 Toxic if inhaled 吸入中毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes T
RTECSBY6825000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P352+P312+P361+P364
  • P304+P340+P311
  • P305+P351+P338
  • P308+P311
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
UN Number 1661 UN 1661 6.1/PG 2 UN1661
Risk Statements
  • R52/53
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupII
Storage condition 密封避光保存。
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 535 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(issue)/page/year: TR-72-62,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 450 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   VKMGA7 Voprosy Kommunal'noi Gigieny.  Problems of Communal Hygiene.  (Kiev,
   USSR)  V.6, 1966. For publisher information, see GNAMAP.
   Volume(issue)/page/year: 6,89,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 308 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 70 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   JIDHAN Journal of Industrial Hygiene.  (Cambridge, MA)  V.1-17, 1919-35. For
   publisher information, see AEHLAU.  Volume(issue)/page/year: 2,247,1920

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 5 mg/disc
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 170,11,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 ug/plate
REFERENCE :
   IJCMDW International Journal of Cosmetic Science.  (Blackwell Scientific
   Pub. Inc., 52 Beacon St., Boston, MA 02108)  V.1-    1979-
   Volume(issue)/page/year: 7,277,1985

Warnings 危险化学品

其他信息

  • 图谱信息:3-硝基苯胺(99-09-2)红外图谱(IR2) 3-硝基苯胺(99-09-2)核磁图( 1 HNMR) 3-硝基苯胺(99-09-2)红外图谱(IR1) 3-硝基苯胺(99-09-2)核磁图( 13 CNMR) 3-硝基苯胺(99-09-2)质谱(MS)
  • 方法一:以硝基苯为原料，以硝酸和硫酸配成混酸进行硝化生成间二硝基苯，经亚硫酸精制，得间二硝基苯成品。用硫磺和硫化钠为原料，制取多硫化钠，用多硫化钠将间二硝基苯还原成间硝基苯胺，反应产物经重结晶、过滤得成品。原料消耗定额：硝基苯1319kg/t、硝酸845kg/t、硫酸2050kg/t、硫化钠707kg/t、硫磺271kg/t。
  • MOL 文件:99-09-2.mol
  • TCI Shanghai:3-硝基苯胺 3-Nitroaniline,>;98.0%(GC)(99-09-2)
  • 3-硝基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80089726 3-硝基苯胺（易制爆） 100g 81.7元 2010/06/21 128361000 3-硝基苯胺 3-Nitroaniline 99+% 100 GR 601元 2010/06/21 128365000 3-硝基苯胺 3-Nitroaniline 99+% 500 GR 1084元
  • 上游原料:硫酸 --> 硝酸 --> 硫磺 --> 亚硫酸钠 --> 硫化钠 --> 硝基苯 --> 1,3-二硝基苯 --> 多硫化钠 --> 硫化钙
  • 类别:有毒物品
  • 急性毒性:口服-大鼠LD50： 535 毫克/公斤；口服-小鼠LD50： 308 毫克/公斤
  • 下游产品:间溴苯胺 --> 3-氟苯胺 --> 1,3-二氟苯 --> 3-甲磺酰氨基苯胺 --> 5-氨基喹啉 --> 间氨基乙酰苯胺 --> 3-羟基-N-(3-硝基苯基)-2-萘甲酰胺 --> 3-硝基苯酚 --> 分散红 74 --> 分散黄 5G --> 媒介黄 1 --> 3-硝基联苯 --> N-[5-[二(2-乙酰氧基)乙基]氨基]-2-[(2-氯-4-硝基苯基)偶氮]苯基丙酰胺 --> 间硝基乙酰替苯胺
  • 外观性质:亮黄色针状结晶。
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • Acros Organics:3-硝基苯胺 3-Nitroaniline, 99+%(99-09-2)
  • 海关编码:29214210
  • 可燃性危险特性:遇明火可燃;燃烧产生有毒氮氧化物烟雾；与氧化剂反应
  • 用途二:用作医药及染料中间体
  • 用途四:用作染料中间体及及用于有机合成，也用于松木颜色的检验,酸碱指示剂，pH6.8(无色)-8.6(黄)。
  • 蒸气压:1 mm Hg ( 119 °C)
  • 色指数:37030
  • 用途五:用作染料中间体及及用于有机合成，也用于松木颜色的检验,酸碱指示剂，pH6.8(无色)-8.6(黄)。 用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。
  • Alfa Aesar:3-硝基苯胺,98% 3-Nitroaniline, 98%(99-09-2)
  • 1g溶于约20ml乙醇、18ml乙醚、11.5ml甲醇、880ml水。与无机酸生成水溶性盐。易溶于甲醇，能溶于无机酸、醇、氯仿、醚和苯，微溶于水。低毒，半数致死量(大鼠，经口)535mg/kg。有刺激性。
  • 毒性分级:高毒
  • F:8
  • MSDS 信息:间硝基苯胺(99-09-2).msds
  • 用途一:用于有机合成及松木颜色的检验，也用作染料中间体
  • 用途三:主要用作有机合成中间体和染料中间体。可用作冰染染料橙色基R和制取色酚AS-BS。将间硝基苯胺与环氧乙烷进行羟乙基化，可制得3-硝基-N，N-二乙醇基苯胺。
  • 灭火剂:二氧化碳、泡

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. C6 - Amines
  1. C10 - Amines
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. N - Alphabetic
  5. NA - NI - N
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Volatiles/ Semivolatiles - Environmental Standards
  6. Alpha Sort - Volatiles/ Semivolatiles
  7. N-O - Alpha Sort
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C11 to C38
  1. Materials Science 材料科学
  2. Organic Nonlinear Optical Materials