4-Fluoro-2-Methylaniline 4-氟-2-甲基苯胺

CAS 452-71-1 MFCD00007832

化学结构图

452-71-1
SMILES: Cc1cc(F)ccc1N

化学属性

Mol. FormulaC7H8FN
Mol. Weight125.15
Boiling Point206.9°C at 760 mmHg
TSCAT
Refractive index1.5350 to 1.5380
Density1.126
Flash Point88°C(lit.)
Appearance 淡黄色液体。沸点90℃-92℃(16mmHg),闪点87℃,折光率1.5370,比重1.126。
Melting Point14.2 °C
pH:A

别名和识别编码

Chemical Name4-Fluoro-2-Methylaniline
CAS Number452-71-1
Alfabeta NameFLUOROMETHYLANILINE 42---
MDL NumberMFCD00007832
Synonym 4-Fluoro-2-methylaniline {LY} 4-Fluoro-2-methylaniline {} {LY} 4-Fluoro-2-methylaniline {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {} {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {} {} {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluoro-2-methylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluoro-2-meth
PubChem Substance ID87570166
EC Number207-208-2
Beilstein Registry Number1931798
Reaxys-RN1931798
Chemical Name Translation4-氟-2-甲基苯胺
InChIKeyKMHLGVTVACLEJE-UHFFFAOYSA-N
Wiswesser Line NotationZR DF B1
LabNetwork Molecule IDLN00112223
InChIInChI=1S/C7H8FN/c1-5-4-6(8)2-3-7(5)9/h2-4H,9H2,1H3
Canonical SMILESCC1=CC(F)=CC=C1N
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分类

  • {SNA} Amines, Aryl Fluorinated Building Blocks, Building Blocks, C7, C7-C8, Chemical Synthesis, Fluorinated Building Blocks, Nitrogen Compounds, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • Amines, Aryl Fluorinated Building Blocks, Building Blocks, C7, C7-C8, Chemical Synthesis, Fluorinated Building Blocks, Nitrogen Compounds, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

相关文献及参考

  • Beil. 12 ,IV,1786
  • FT-IR 2 (2), 2063:C / FT-NMR 1 (2), 498:C / RegBook 1 (1), 1407:C / Structure Index 1 , 218:C:8 / Vapor Phase 3 , 1136:C

安全信息

Warnings IRRITANT, TOXIC
GHS Symbol
WGK Germany3
Hazard Codes Xn Xn,T,Xi T
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302+H312+H332
  • H227 Combustible liquid 可燃液体
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSCY0500000
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P312+P362+P364
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P403+P235
  • P304+P340+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P305+P351+P338+P337+P313
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
UN Number UN2810
Packing GroupIII
Hazard Class6.1
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2 umol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 77,317,1980

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 图谱信息:4-氟-2-甲基苯胺(452-71-1)核磁图( 1 HNMR)
  • Sigma Aldrich:452-71-1(sigmaaldrich)
  • 用途一:是合成农药、医药和染料的中间体
  • TSCA:T
  • MSDS 信息:2-Amino-5-fluorotoluene(452-71-1).msds
  • MOL 文件:452-71-1.mol
  • TCI Shanghai:4-氟邻甲苯胺 4-Fluoro-2-methylaniline,>;98.0%(GC)(T)(452-71-1)
  • Hazard Note:Toxic/Irritant
  • 下游产品:
  • 4-氟-2-甲基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0398 4-氟-2-甲基苯胺 4-Fluoro-2-methylaniline 5G 331元 2014/06/02 F0398 4-氟-2-甲基苯胺 4-Fluoro-2-methylaniline 25G 999元 2010/06/21 369840250 4-氟-2-甲基苯胺 4-Fluoro-2-methylaniline 97% 25 GR 1646元
  • Acros Organics:4-Fluoro-2-methylaniline, 99+%(452-71-1)
  • Alfa Aesar:4-氟-2-甲基苯胺,97% 4-Fluoro-2-methylaniline, 97%(452-71-1)
  • 用途二:医药、农药、液晶材料中间体。

系列性分类


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