1,3-Benzenedimethanamine 间苯二甲胺

CAS 1477-55-0 MFCD00008119

化学结构图

1477-55-0
SMILES: NCc1cccc(CN)c1

化学属性

Mol. FormulaC8H12N2
Mol. Weight136.20
Density1.032
Refractive index1.5690 to 1.5740
Boiling Point247 °C at 760 mmHg
Vapor Pressure15 mmHg ( 145 °C)
Flash Point>110°C
Melting Point14 °C
SolubilityMISCIBLE
Appearance 无色液体,有杏仁味。久露空气中呈黄色。相对密度1.055,沸点248℃,折射率1.5700,粘度与苯二甲酸二丁酯近似。溶于水和有机溶剂。
Stability易吸潮
pH:A

别名和识别编码

Chemical Name1,3-Benzenedimethanamine
CAS Number1477-55-0
EC Number216-032-5
Beilstein Registry Number1099911
MDL NumberMFCD00008119
Synonym m-Xylylenediamine {LY} m-Xylylenediamine m-xylenediamine m-xylylenediamine {} {LY} m-Xylylenediamine {} {} {LY} m-Xylylenediamine {} {} {} {LY} m-Xylylenediamine {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} m-Xylylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} m-Xylylenedi
PubChem Substance ID15133
Reaxys-RN1099911
Chemical Name Translation间苯二甲胺
LabNetwork Molecule IDLN00224686
InChIInChI=1S/C8H12N2/c9-5-7-2-1-3-8(4-7)6-10/h1-4H,5-6,9-10H2
Canonical SMILESNCC1=CC(CN)=CC=C1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines

产品应用

  • MXDA特殊的结构决定其有多种优异的物理和化学性能而被广泛使用。MXDA及其环氢化物可作为环氧树脂固化剂,常温固化性能优异,耐热性、耐水性、耐化学腐蚀性能好,而且能得到透明的表面极为精整的良好固化树脂,粘度低,操作性能好。同时MXDA是重要的精细化工中间体,可与二元酸合成聚酰胺,可以合成聚氨酯的单体间二甲苯二异氰酸酯,其苯环氢化物还可用于合成二异氰酸酯。目前已在橡胶交联剂、农药、纤维稳定剂、表面活性剂等的合成方面使用。

相关文献及参考

  • Beilstein:13,186

安全信息

Signal word
GHS Symbol
WGK Germany2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R52/53
  • R34 Causes burns 会导致灼伤
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R23 Toxic by inhalation 吸入有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P317
  • P301+P330+P331
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P308+P311
  • P308+P316
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P333+P313
  • P333+P317
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H302+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H330 Fatal if inhaled 吸入致命
  • H331 Toxic if inhaled 吸入中毒
  • H332 Harmful if inhaled 吸入有害
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSPF8970000
Hazard Codes T T,C C
UN Number
Packing GroupII
Hazard Class8
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, pro
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
   Industrial Hygienists, Inc., 1986  Volume(issue)/page/year: 5,638,1986

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 700 ppm/1H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
   Industrial Hygienists, Inc., 1986  Volume(issue)/page/year: 5,638,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 930 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
   Industrial Hygienists, Inc., 1986  Volume(issue)/page/year: 5,638,1986

其他信息

  • F:2-9
  • 方法一:由间、对二甲苯的混合物作原料,经空气和氨进行氨氧化反应生成间、对苯二甲腈。再经水洗、烘干后,在4.5MPa压力和90℃下,在乙醇和氢氧化钾溶剂中进行催化加氢。反应液除去触媒,回收乙醇,减压蒸馏即得间、对混合苯二甲胺。
  • 上游原料:对二甲苯 --> 粗苯 --> 对苯二腈 --> 苯二甲胺
  • 1,3-苯二甲胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0127 间苯二甲胺 m-Xylylenediamine 25G 213元 2014/06/02 D0127 间苯二甲胺 m-Xylylenediamine 500G 902元 2010/06/21 141021000 1,3-苯二甲胺 m-Xylylenediamine 99% 100 ML 335元
  • MSDS 信息:1,3-Bis(aminomethyl)benzene(1477-55-0).msds
  • 无色透明具有杏仁味的液体,易吸收空气中的二氧化碳生成白色固体
  • 蒸气压:15 mm Hg ( 145 °C)
  • Acros Organics:间苯二甲胺/1 3-双(氨甲基)苯 m-Xylylenediamine, 99%(1477-55-0)
  • TCI Shanghai:1,3-间苯二甲胺 m-Xylylenediamine,>;98.0%(GC)(1477-55-0)
  • MOL 文件:1477-55-0.mol
  • 用途三:MXDA特殊的结构决定其有多种优异的物理和化学性能而被广泛使用。MXDA及其环氢化物可作为环氧树脂固化剂,常温固化性能优异,耐热性、耐水性、耐化学腐蚀性能好,而且能得到透明的表面极为精整的良好固化树脂,粘度低,操作性能好。同时MXDA是重要的精细化工中间体,可与二元酸合成聚酰胺,可以合成聚氨酯的单体间二甲苯二异氰酸酯,其苯环氢化物还可用于合成二异氰酸酯。目前已在橡胶交联剂、农药、纤维稳定剂、表面活性剂等的合成方面使用。
  • 图谱信息:1,3-苯二甲胺(1477-55-0)红外图谱(IR2) 1,3-苯二甲胺(1477-55-0)核磁图( 13 CNMR) 1,3-苯二甲胺(1477-55-0)红外图谱(IR1) 1,3-苯二甲胺(1477-55-0)核磁图( 1 HNMR) 1,3-苯二甲胺(1477-55-0)质谱(MS)
  • Sigma Aldrich:1477-55-0(sigmaaldrich)
  • 用途一:用于制环氧树脂固化剂、光敏塑料、橡胶助剂、聚氨酯树脂及涂料等
  • 用途二:主要用于制造耐热、无毒、水下施工、加热快速固化的高性能环氧树脂固化剂,是聚氨酯树脂、合成功能性环氧树脂的原料,也用于橡胶助剂、光敏塑料、农药、涂料、尼龙制品、纤维整理剂、防锈剂、螯合剂、润滑剂、纸加工等方面也有应用。

系列性分类


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