Tetraethylenepentamine 四乙烯五胺(支链异构体和环状化合物混合物)

CAS 112-57-2 MFCD00008168

化学结构图

112-57-2
SMILES: NCCNCCNCCNCCN

化学属性

Mol. FormulaC8H23N5
Mol. Weight189
Density0.998
Refractive indexn20/D 1.505(lit.)
Autoignition Point610 °F
Vapor Density6.53 (vs air)
Boiling Point340
Vapor Pressure<;0.01 mmHg ( 20 °C)
Melting Point-40
Flash Point163°C(lit.)
Solubility可溶
pH:A

别名和识别编码

Chemical NameTetraethylenepentamine
CAS Number112-57-2
EC Number203-986-2
Beilstein Registry Number506966
MDL NumberMFCD00008168
Synonym TETRAETHYLENPENTAMINE tetraethylenepentamine 1,2-Ethanediamine, N-(2-aminoethyl)-N'-[2-[(2-aminoethyl)amino]ethyl]- 1,11-Diamino-3,6,9-triazaundecane; 1,4,7,10,13-Pentaazatridecane; 3,6,9-Triaza-1,11-undecanediamine; 3,6,9-Triazaundecamethylenediamine Tetraäthylenpentamin 四亚乙基五胺 Bis(-2-aminoethyl)ethylenediamine deh26 Tetraethylenepentaminie 四伸乙五胺 Tetraethylenpentamin N1-{2-[2-(2-Amino-ethylamino)-ethylamino]-ethyl 四乙烯戊胺 {C n-(2-aminoethyl)-n’-[2-[(2-aminoethyl)amino]ethyl]-2-ethanediamine 1,2-Ethanediamine, N-(2-aminoethyl)-N'-[2-[(2-aminoethyl)amino]ethyl]- 3,6,9-Triaza-1,11-diaminoundecane D.E.H. 26 1,11-Diamino-3,6,9-triazaundecane TETRAEN 三缩四乙二胺 N1-{2-[2-(2-Amino-ethylamino)-ethylamino]-ethyl}-ethane-1,2-diamine 1,11-diamino-3,6,9-triazaundecane n-(2-aminoethyl)-n’-(2-((2-aminoethyl)amino) n-(2-aminoethyl)-n-(2-((2-aminoethyl)amino)ethyl-1,2-ethanediamine) 3,6,9-triazaundecamethylenediamine 3,6,9-triaza-1,11-undecanediamine 四乙基戊胺 四乙烯五胺 TEP 四乙五胺 TEPA 四亚乙基五胺 bis-(2-(2-amino-ethylamino)-ethyl)-amine Tetraethylene pentamine 2-Ethanediamine,N-(2-aminoethyl)-N’-[2-[(2-aminoethyl)amino]ethyl]-1 TETRAETHYLENEPENTAMINE Tetraethylpentylamine DEH 26 1,4,7,10,13-PENTAAZATRIDECANE Tetren 3,6,9-Triazaundecane-1,11-diamine 四乙撑五胺 3,6,9-Triazaundecan-1,11-diamin 1,4,7,10,13-Pentaazatridecane TETRENE
PubChem Substance ID8197
Reaxys-RN506966
Chemical Name Translation四乙烯五胺(支链异构体和环状化合物混合物)
Wiswesser Line NotationZ2M2M2M2Z
LabNetwork Molecule IDLN00198681
InChIInChI=1S/C8H23N5/c9-1-3-11-5-7-13-8-6-12-4-2-10/h11-13H,1-10H2
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Nitrogen Compounds, Organic Building Blocks, Polyamines

相关文献及参考

  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/1b Title: Densities of Liquid Systems: Densities of Binary Aqueous Systems and Heat Capacities of Liquid Systems Author: D'Ans, J.; Surawski, H.; Synowietz, C. Editor: Schäfer, Kl.

安全信息

Signal word Danger
GHS Symbol
WGK Germany2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R51/53
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSKH8585000
Hazard Codes 8 C,N
UN Number 2320 UN 2320 8/PG 3
Packing GroupIII
Hazard Class8
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 660 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,60,1949

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03522

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 205 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ICHAA3 Inorganica Chimica Acta.  (Elsevier Sequoia SA, POB 851, CH-1001
   Lausanne 1, Switzerland) V.1-    1967-  Volume(issue)/page/year: 91,L51,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3990 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 3/20/1973

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 8(Suppl
   7),1,1986

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 250 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 320,31,1994

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 10 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 320,31,1994

Restrict 危险品

其他信息

  • 爆炸物危险特性:对皮肤,角膜有腐蚀性
  • MOL 文件:112-57-2.mol
  • 防护措施:本品为强碱性、腐蚀性液体。可刺激皮肤、粘膜而引起皮肤过敏和支气管哮喘等症。长期接触会引起白血球减少、血压降低、支气管扩张等。经口LD50为3.99g/kg。应避免直接与人体接触，溅及皮肤时，迅速用水或硼酸溶液冲洗，再涂以硼酸软膏。发现中毒，应立即脱离现场，呼吸新鲜空气或送医院诊治。
  • 可燃性危险特性:可燃; 受热分解有毒氧化氮气体
  • Sigma Aldrich:112-57-2(sigmaaldrich)
  • 用途一:用于合成树脂，也用作添加剂、固化剂、促进剂等
  • 外观性质:黄色或橙红色粘稠液体。
  • 四亚乙基五胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80123828 四乙烯五胺 500ml 44元 2011/04/16 T0098 四亚乙基五胺(俗称) Tetraethylenepentamine (so called) 25G 125元 2011/04/16 T0098 四亚乙基五胺(俗称) Tetraethylenepentamine (so called) 500G 343元
  • 类别:腐蚀物品
  • 下游产品:二乙烯三胺 --> 三乙烯二胺 --> 三乙烯四胺 --> 烷基磷酸咪唑啉盐 --> TDAE-无氰镀锌添加剂 --> EQD-3添加剂 --> 换离子稳定剂
  • 灭火剂:雾状水、泡沫、二氧化碳、干粉
  • 蒸气压:<;0.01 mm Hg ( 20 °C)
  • 蒸气密度:6.53 (vs air)
  • 常规方法:用0.5kg玻璃瓶、5kg聚乙烯塑料桶、200kg铁桶包装。本品应密封贮存，存放处应通风、防潮、防热，与酸类物品隔离。宜用带篷的汽车或火车运输，并按“铁路危规号96009”办理。
  • 储运特性:库房通风低温干燥; 与酸类及氧化剂分开存放。
  • 急性毒性:腹注- 大鼠 LD50: 205 毫克/ 公斤
  • F:21
  • TCI Shanghai:四亚乙基五胺(俗称) Tetraethylenepentamine (so called),>;95.0%(N)(112-57-2)
  • 毒性分级:高毒
  • MSDS 信息:四乙撑五胺(112-57-2).msds
  • Acros Organics:四乙烯基五胺 Tetraethylenepentamine, tech.(112-57-2)
  • 刺激数据:皮肤- 兔子 5 毫克/ 24小时 重度; 眼- 兔子 100 毫克/ 24小时 中度
  • 用途二:用于电流终点法的络合滴定铜、锌和镍, 酸性物质的皂化, 合成橡胶和树脂气体提纯脱水剂。也用作添加剂、固化剂、促进剂等。
  • 海关编码:29212900
  • 图谱信息:四亚乙基五胺(112-57-2)红外图谱(IR2) 四亚乙基五胺(112-57-2)红外图谱(IR1)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Oximes

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