Tris(2-Aminoethyl)Amine 三(2-氨基乙基)胺

CAS 4097-89-6 MFCD00008177

化学结构图

4097-89-6
SMILES: NCCN(CCN)CCN

化学属性

Mol. FormulaC6H18N4
Mol. Weight146.23
Density0.976
Refractive index1.4950 to 1.4990
Vapor Density5 (vs air)
Boiling Point114 °C at 15 mmHg
Vapor Pressure0.02 mmHg ( 20 °C)
Flash Point>110°(230°F)
TSCAYes
Melting Point-16 °C
Appearance saline suspension
Stability对空气敏感，易吸湿

别名和识别编码

Chemical NameTris(2-Aminoethyl)Amine
Synonym N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N1-Bis(2-aminoethyl)ethane-1,2-diamine {} {} {} {} {} {} {}
CAS Number4097-89-6
EC Number223-857-4
Beilstein Registry Number4(2)695
MDL NumberMFCD00008177
PubChem Substance ID77731
Chemical Name Translation三(2-氨基乙基)胺
Reaxys-RN1739626
InChIKeyMBYLVOKEDDQJDY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00199022
InChIInChI=1S/C6H18N4/c7-1-4-10(5-2-8)6-3-9/h1-9H2
Canonical SMILESNCCN(CCN)CCN
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分类

  • {SNA} Amine Monomers, Materials Science, Monomers, Polymer Science, Primary Amines
  • {SA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Amine Monomers, Monomers, Polymer Science, Primary Amines, 材料科学

产品应用

  • 可作为穴状配体的结构单元和有机非离子超强碱的前体。

相关文献及参考

  • Beilstein:4(2)695
  • Reagent for rapid cleavage of the Fmoc group in peptide synthesis, particularly recommended in conjunction with Fmoc-protected acid chlorides as the active species: J. Org. Chem., 55, 1673 (1990). For a review of peptide synthesis via amino ac
  • Short: III/35B
  • Short: IV/20C
  • Short: EINECS
  • Reagent for rapid cleavage of the Fmoc group in peptide synthesis, particularly recommended in conjunction with Fmoc-protected acid chlorides as the active species: J. Org. Chem., 55, 1673 (1990). For a review of peptide synthesis via amino acid halides, see: Acc. Chem. Res., 29, 268 (1996). For peptide reagents, see Appendix 6.
  • Reaction with aryl isocyanates and isothiocyanates gives tris-urea and -thiourea derivatives which have been evaluated as phosphate and sulfate receptors: Chem. Lett., 759 (1995).

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P302+P350
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P340
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H310 Fatal in contact with skin 皮肤接触致命
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSKH8587082
Packing GroupII
UN Number UN 2922 8/PG 2 UN2922 2922
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
Hazard Codes T,Xi T
Hazard Class8/6.1

其他信息

  • 三(2-氨基乙基)胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1243 三(2-氨乙基)胺 Tris(2-aminoethyl)amine 25ML 524元 2011/04/16 T1243 三(2-氨乙基)胺 Tris(2-aminoethyl)amine 500ML 9199元 2010/06/21 314791000 三(2-氨基乙基)胺 Tris(2-aminoethyl)amine 96% 100 ML 1637元
  • TCI Shanghai:三(2-氨乙基)胺 Tris(2-aminoethyl)amine,>;98.0%(T)(4097-89-6)
  • Alfa Aesar:三（2-氨乙基）胺,97% Tris(2-aminoethyl)amine, 97%(4097-89-6)
  • MOL 文件:4097-89-6.mol
  • Sigma Aldrich:4097-89-6(sigmaaldrich)
  • 敏感性:Hygroscopic
  • 蒸气压:0.02 mm Hg ( 20 °C)
  • 蒸气密度:5 (vs air)
  • 上游原料:氢氧化钠 --> 盐酸 --> 甲醇 --> 氢氧化铵 --> 次氯酸钠 --> 1,2-二氯乙烷 --> 丙烯酰胺 --> 直接红 28
  • Acros Organics:三（2-氨乙基）胺 Tris(2-aminoethyl)amine, 96%(4097-89-6)
  • F:3-10-23

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates - Nitrogen Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Amine Monomers - Monomers
  5. Primary Amines - Amine Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Amine Monomers

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