Dimethylphenylsilane 二甲基苯基硅烷

CAS 766-77-8 MFCD00008257

化学结构图

766-77-8
SMILES: C[SiH](C)C1C=CC=CC=1

化学属性

Mol. FormulaC8H12Si
Mol. Weight136.27
Refractive index1.4970 to 1.5010
Boiling Point157 °C at 744 mmHg
Density0.889
Flash Point35°C
TSCAYes
Melting Point-124 °C
Stability对湿度敏感

别名和识别编码

Chemical NameDimethylphenylsilane
Synonym Dimethylphenylsilane {LY} Dimethylphenylsilane {} {LY} Dimethylphenylsilane {} {} {LY} Dimethylphenylsilane {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethylphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00008257
CAS Number766-77-8
PubChem Substance ID87568636
EC Number212-170-5
Beilstein Registry Number16(4)1360
Reaxys-RN2204906
Chemical Name Translation二甲基苯基硅烷
InChIKeyZISUALSZTAEPJH-UHFFFAOYSA-N
LabNetwork Molecule IDLN00010991
Canonical SMILESC[SiH](C)C1=CC=CC=C1
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分类

  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Others
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Other Organosilicon

产品应用

  • F-- 和 H+-催化的酮还原;硅烷化试剂;用于烯醇醚合成的试剂。

相关文献及参考

  • Beilstein:16(4)1360
  • For a review of silane reductions, see: Org. Prep. Proced. Int., 12, 13 (1980).
  • For an example of reduction of a ß-keto amide to a ß-hydroxy amide, see: Org. Synth. Coll., 8, 326 (1993).
  • Reagent for the highly diastereoselective reduction of ketones to alcohols, in the presence of TBAF or TFA: J. Am. Chem. Soc., 106, 4629 (1984); J. Org. Chem., 53, 5415 (1988):
  • Short: III/35C4
  • Short: III/35F
  • Silylation of hydroxyl groups gives DMPS ethers under very mild conditions using TBAF catalysis: Tetrahedron Lett., 35, 8413 (1994). See also Chlorodimethyl­phenyl­silane, A15638 and Appendix 4.

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H318 Causes serious eye damage 严重伤害眼睛
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P403+P235
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P302+P352+P332+P313+P362+P364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P305+P351+P338+P337+P313
  • P303+P361+P353
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P337+P313
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P241+P242+P243
Signal word
Packing GroupIII
UN Number 1993
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
  • R36 Irritating to eyes 刺激眼睛
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Hazard Codes 3
Hazard Class3
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物

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