Tris(trimethylsilyl) phosphate 三（三甲基硅基）磷
CAS 10497-05-9 MFCD00008267
化学结构图
SMILES: C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C
化学属性
| Mol. Formula | C9H27O4PSi3 |
|---|---|
| Mol. Weight | 314.54 |
| Refractive index | 1.4070 to 1.4110 |
| Boiling Point | 236°C(lit.) |
| Density | 0.945 g/mL at 25 °C(lit.) |
| Melting Point | 3-4 °C(lit.) |
| Flash Point | 24°C(lit.) |
别名和识别编码
| Chemical Name | Tris(trimethylsilyl) phosphate |
|---|---|
| Synonym | {uni_hamburg} phosphoric acid tris-trimethylsilyl ester 三(三甲基硅基)磷 Tris-(trimethylsilyl)fosfat 磷酸三(三甲基硅基)酯 phosphoric acid tris-(trimethylsilyl) ester tris(trimethylsilyl)phosphate Silanol, trimethyl-, phosphate (3:1) Tris-(trimethylsilyl)-phosphat tris(trimethylsilyl) phosphate Phosphoric acid tris(trimethylsilyl) ester phosphoric acid tris-trimethylsilanyl ester |
| CAS Number | 10497-05-9 |
| PubChem Substance ID | 87575343 |
| EC Number | 234-028-1 |
| Beilstein Registry Number | 4(4)4017 |
| MDL Number | MFCD00008267 |
| Reaxys-RN | 1794624 |
| Chemical Name Translation | 三（三甲基硅基）磷 |
| Wiswesser Line Notation | 1-SI-1&1&-OPO&O-SI-1&1&1&O-SI-1&1&1 |
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分类
- Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
- {uni_hamburg} no charge; 1fragment
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
相关文献及参考
- Beil. 4 ,IV,4017
- Corp MSDS 1 (2), 3537:A / FT-NMR 1 (3), 700:B / RegBook 1 (2), 2995:D / Sax 6 , 2215 / Structure Index 1 , 474:B:6 / Vapor Phase 3 , 1664:A
- Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment, i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 "Nuclear Magnetic Resonance (NMR) Data" is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 ''NMR-Data'' is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei B-11 and P-31, subvolume III/35B contains the nuclei F-19 and N-15, subvolume III/35C contains the nucleus H-1, subvolume III/35D contains the nucleus C-13, subvolume III/35E contains the nucleus
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+P242+P243
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- R11 Highly flammable 非常易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 3440 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1233,1986
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