Phenylthiotrimethylsilane (苯硫基)三甲基硅烷

CAS 4551-15-9 MFCD00008272

化学结构图

4551-15-9
SMILES:

化学属性

Mol. FormulaC9H14SSi
Mol. Weight182.36
Refractive index1.5320 to 1.5360
Boiling Point72 °C at 8 mmHg
Density0.963 g/mL at 25 °C(lit.)
Flash Point33°C(lit.)
TSCAYes

别名和识别编码

Chemical NamePhenylthiotrimethylsilane
Synonym Trimethyl(phenylthio)silane {LY} Trimethyl(phenylthio)silane {} {LY} Trimethyl(phenylthio)silane {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(phenylthio)silane {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00008272
CAS Number4551-15-9
PubChem Substance ID87575463
EC Number224-916-7
Beilstein Registry Number1905944
Chemical Name Translation(苯硫基)三甲基硅烷
Reaxys-RN1905944
InChIKeyVJMQFIRIMMSSRW-UHFFFAOYSA-N
LabNetwork Molecule IDLN01316396
Canonical SMILESC[Si](SC1=CC=CC=C1)(C)C
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Protected Thiols/Mercaptans, Sulfur Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existin
  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment, i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 "Nuclear Magnetic Resonance (NMR) Data" is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 ''NMR-Data'' is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei B-11 and P-31, subvolume III/35B contains the nuclei F-19 and N-15, subvolume III/35C contains the nucleus H-1, subvolume III/35D contains the nucleus C-13, subvolume III/35E contains the nucleus O-17, subvolume III/35F contains the nucleus Si-29, and subvolume III/35G contains the nucleus Se-77. More nuclei will be presented later.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Warning
Packing GroupIII
UN Number 1993 UN 1993 3/PG 3 UN1993
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R20 Harmful by inhalation 吸入有害
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Flammables area Moisture Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored u
Hazard Codes Xn
Hazard Class3
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P302+P352+P312+P362+P364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P403+P235
  • P304+P340+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+P351+P338+P337+P313

其他信息

  • 图谱信息:苯基硫三甲基硅烷 (4551-15-9)质谱(MS) 苯基硫三甲基硅烷 (4551-15-9)红外图谱(IR1)
  • Alfa Aesar:(苯硫基)三甲基硅烷,97% (Phenylthio)trimethylsilane, 97%(4551-15-9)
  • F:3-10-13-21
  • Sigma Aldrich:4551-15-9(sigmaaldrich)
  • 苯基硫三甲基硅烷 价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1378 (苯硫基)三甲基硅烷 (Phenylthio)trimethylsilane 5G 396元 2014/06/02 P1378 (苯硫基)三甲基硅烷 (Phenylthio)trimethylsilane 25G 1200元 2010/06/21 210140010 苯基硫三甲基硅烷 Phenylthiotrimethylsilane 95% 1 GR 644元
  • Acros Organics:Phenylthiotrimethylsilane, 95%(4551-15-9)
  • 敏感性:Moisture Sensitive
  • TCI Shanghai:苯硫基三甲基硅烷 (Phenylthio)trimethylsilane,>;90.0%(GC)(4551-15-9)
  • MOL 文件:4551-15-9.mol
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Protected Thiols/Mercaptans - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Protected Thiols/Mercaptans - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷

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