Benzyltrimethylammonium Hydroxide 苄基三甲基氢氧化铵

CAS 100-85-6 MFCD00008281

化学结构图

100-85-6
SMILES: C[N+](C)(C)Cc1ccccc1.[OH-]

化学属性

Mol. FormulaC10H17NO
Mol. Weight167
Density0.925
TSCAYes
Refractive indexn20/D 1.43
Flash Point11°C(lit.)
Boiling Point65°
Appearance 苄基三甲基氢氧化铵(100-85-6)为无色至淡黄色透明液体，沸点65°C，相对密度 0.95，折光系数 n 20/D 1.43，闪点 15°C
Stability易吸潮，对空气敏感
pH:A

别名和识别编码

Chemical NameBenzyltrimethylammonium Hydroxide
CAS Number100-85-6
Alfabeta NameBENZYLTRIMETHYLAMMONIUMHYDROXIDEINMETHANOL %40()
MDL NumberMFCD00008281
EC Number202-895-5
Beilstein Registry Number12,1020
Synonym n,n,n-trimethyl-benzenemethanaminiuhydroxide BENZYLTRIMETHYLAMMONIUM HYDROXIDE, 40 WT . % SOLUTION IN WATER Benzyl trimethylammonium hydroxide, 40% w/w in methanol Benzenemethanaminium, N,N,N-trimethyl-, hydroxide Benzenemethanaminium,N,N,N-trimethyl-,hydroxide BENZYLTRIMETHYLAMMONIUM HYDROXIDE (20%,AQUEOUS:40%,MEOH:10%,PROPYLENE GLYCOL SOLUTION) 2-苄氧基萘 N,N,N-三甲基甲铵氢氧化物苯;苯甲基三甲基氢氧化铵 Triton(rg B 三甲基苄基氢氧化铵 TRITON B n,n,n-trimethylbenzenemethanaminiumhydroxide BENZYLTRIMETHYLAMMONIUM HYDROXIDE Benzyltrimethylammo BENZYLTRIMETHYLAMMONIUM HYDROXIDE SOL., ~40% IN WATER sumquat2311 苯甲基三甲基氢氧化铵 Triton B BENZYLTRIMETHYLAMMONIUM HYDROXIDE SOL.,
PubChem Substance ID87563485
Reaxys-RN3917256
Chemical Name Translation苄基三甲基氢氧化铵
Wiswesser Line Notation1K1&1&1R &Q
LabNetwork Molecule IDLN00163380
InChIInChI=1S/C10H16N.H2O/c1-11(2,3)9-10-7-5-4-6-8-10;/h4-8H,9H2,1-3H3;1H2/q+1;/p-1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Chemical Synthesis, Organic Bases, Synthetic Reagents
  • {SNA} Acids & Bases, Bases, Chemical Synthesis, Organic Bases, Synthetic Reagents

相关文献及参考

  • Beilstein: 12,IV,2162
  • Triton. is a registered trademark of Rohm and Haas Co.
  • Useful base catalyst or reagent for many reactions. For use in the Michael addition of nitro-compounds to ɑß-unsaturated esters, see: Org. Synth. Coll., 4, 652 (1963). For C-methylation of 2-Methyl­cyclohexane-1,3-dione, A11218, see: Org. Synth. Coll., 8, 312 (1993).

安全信息

Warnings IRRITANT
Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S4 Keep away from living quarters 远离生活区；
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P330+P331+P310
  • P302+P350
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupII
UN Number 2924 3267 UN2924
RTECSBO8575000
Storage condition Flammables area 充氩保存 Air Sensitive
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H301+H311+H331
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H370 Causes damage to organs 导致器官损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US) Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,T C
Hazard Class3/8 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 35 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 28,367,1926

其他信息

  • MOL 文件:100-85-6.mol
  • 毒性分级:高毒
  • 爆炸物危险特性:强碱; 对皮肤, 眼睛和黏膜有腐蚀作用
  • 类别:腐蚀物品
  • 敏感性:Air Sensitive
  • Alfa Aesar:苄基三甲基氢氧化铵,40%w/wsoln.inmethanol Benzyltrimethylammonium hydroxide, 40% w/w in methanol(100-85-6)
  • F:9-23
  • TCI Shanghai:氢氧化苄基三甲铵(10%的水溶液) Benzyltrimethylammonium Hydroxide (10% in Water)(100-85-6)
  • 苄基三甲基氢氧化铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1070 苄基三甲基氢氧化铵(10%的水溶液) Benzyltrimethylammonium Hydroxide (10% in Water) 25ML 150元 2014/06/02 B1070 苄基三甲基氢氧化铵(10%的水溶液) Benzyltrimethylammonium Hydroxide (10% in Water) 500ML 844元 2014/06/02 B0378 苄基三甲基氢氧化铵(40%的水溶液) Benzyltrimethylammonium Hydroxide (40% in Water) 25ML 1500元
  • 急性毒性:皮下-小鼠 LDL0: 35 毫克/公斤
  • 图谱信息:苄基三甲基氢氧化铵(100-85-6)质谱(MS)
  • Sigma Aldrich:100-85-6(sigmaaldrich)
  • 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物和氨烟雾
  • 下游产品:2,3,4,5-四氢-5-甲基-1H-吡啶并[4,3-b]吲哚-1-酮 --> 5,6-二氢-4-(2-甲基-2-苯基肼基)-2-1H-吡啶酮 --> 2,4-哌啶二酮 --> 3-肼基丙酰胺 --> N-2-氰乙基吡咯
  • MSDS 信息:Benzyltrimethylammonium hydroxide(100-85-6).msds
  • 储运特性:库房通风低温干燥; 与酸分开存放
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • Acros Organics:苯甲基三甲基氢氧化铵 Benzyltrimethylammonium hydroxide, 40 wt% solution in methanol(100-85-6)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Acids - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Bases - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amine Salts - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quaternary Ammonium Compounds 季铵化合物

相关产品推荐