N,N-Dimethyltrimethylsilylamine N,N-二甲基三甲基硅胺

CAS 2083-91-2 MFCD00008297

化学结构图

2083-91-2
SMILES: CN(C)[Si](C)(C)C

化学属性

Mol. Formula(CH3)3SiN(CH3)2
Mol. Weight117
Density0.732
Refractive index1.3960 to 1.3980
Flash Point-19°C(lit.)
TSCAYes
Boiling Point86°C
Solubility分解
Melting Point<0°C

别名和识别编码

Chemical NameN,N-Dimethyltrimethylsilylamine
Synonym N-Methyl-N-(trimethylsilyl)methylamine {Chemicalbook} 二甲基氨基三甲基硅烷 N-TRIMETHYLSILYDIMETHYLAMINE N,N-DIMETHYLAMINOTRIMETHYLSILANE N,n-Pentamethylsilanamine TMSDMA (Dimethylamino)trimethylsilane~N-(Trimethylsilyl)dimethylamine (DIMETHYLAMINO)TRIMETHYLSILANE N-(三甲基硅基)二甲胺 N-(三甲基硅基)二甲胺 TMSDMA 二甲基氨基三甲基硅烷 Silanamine,pentamethyl- N-(Trimethylsilyl)-dimethylamin N,N-二甲基三甲基硅胺 {Chemi CD5400 trimethylsilyldimethylamine
MDL NumberMFCD00008297
CAS Number2083-91-2
EC Number218-222-3
Beilstein Registry Number1731861
PubChem Substance ID87576488
Reaxys-RN1731861
Chemical Name TranslationN,N-二甲基三甲基硅胺
InChIKeyKAHVZNKZQFSBFW-UHFFFAOYSA-N
LabNetwork Molecule IDLN00226786
InChIInChI=1S/C5H15NSi/c1-6(2)7(3,4)5/h1-5H3
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Derivatization Reagents, Nitrogen Compounds, Organic Building Blocks, Protected Amines, Silylation Reagents, 分析/色谱, 分析试剂
  • {SNA} Analytical/Chromatography, Ion Sensor Materials, Silanizing Agents for ISE
  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Protected Amines
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Reagent for siliylation of a wide range of functional groups, without the need for added base, useful for amino acids: J. Chromat. Sci., 7, 704 (1969). In the presence of the hindered ligand 2-(Di-tert-butyl­phosphino)­biphenyl­, L19758, Pd-catalyzed cross-coupling reactions with aryl halides to give substituted N,N-dimethylanilines have been effected: Chem. Commun., 1976 (2004).
  • Short: II/25D
  • Short: III/20a

安全信息

Packing GroupII
UN Number 2733
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition Moisture Sensitive Flammables area
GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard Codes F,C
Hazard Class3/8

其他信息

  • 图谱信息:N,N-二甲基三甲基硅胺(2083-91-2)核磁图( 13 CNMR) N,N-二甲基三甲基硅胺(2083-91-2)核磁图( 1 HNMR) N,N-二甲基三甲基硅胺(2083-91-2)红外图谱(IR1)
  • MOL 文件:2083-91-2.mol
  • 敏感性:Moisture Sensitive
  • 下游产品:三(二甲胺基)膦
  • TCI Shanghai:N,N-二甲基三甲基硅胺 N-(Trimethylsilyl)dimethylamine,>;95.0%(GC)(2083-91-2)
  • Alfa Aesar:N-(三甲基硅基)二甲胺,96% N-(Trimethylsilyl)dimethylamine, 96%(2083-91-2)
  • F:1-10
  • N,N-二甲基三甲基硅胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30231880 N，N-二甲基三甲基硅胺 10ml 297元 2011/04/16 T0591 N-(三甲基硅烷基)二甲胺 N-(Trimethylsilyl)dimethylamine 25ML 639元 2010/06/21 209970100 N,N-二甲基三甲基硅胺 N,N-Dimethyltrimethylsilylamine 97% 10 ML 383元
  • Sigma Aldrich:2083-91-2(sigmaaldrich)
  • Acros Organics:N,N-Dimethyltrimethylsilylamine, 97%(2083-91-2)
  • TSCA:Yes

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Ion Sensor Materials
  3. Silanizing Agents for ISE - Ion Sensor Materials
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Protected Amines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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