4-(Dimethylamino)benzophenone 4-二甲基氨基苯并苯基酮

CAS 530-44-9 MFCD00008311

化学结构图

530-44-9
SMILES: CN(C)c1ccc(C(=O)c2ccccc2)cc1

化学属性

Mol. FormulaC15H15NO
Mol. Weight225.29
Melting Point88-90 °C
TSCAYes
Solubility不溶
Appearance 白色叶片状结晶体。熔点92-93℃。不溶于水，微溶于冷乙醇，易溶于热乙醇及乙醚。
Boiling Point250 °C at 15 mmHg

别名和识别编码

Chemical Name4-(Dimethylamino)benzophenone
MDL NumberMFCD00008311
PubChem Substance ID87568983
CAS Number530-44-9
EC Number208-478-4
Synonym 4-(Dimethylamino)benzophenone {LY} 4-(Dimethylamino)benzophenone {} {LY} 4-(Dimethylamino)benzophenone {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {} {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {} {} {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Dimethylamino)benzophenone {} {} {} {} {} {} {} {} {}
Reaxys-RN2211877
Beilstein Registry Number14(4)248
Merck Number3233
Chemical Name Translation4-二甲基氨基苯并苯基酮
LabNetwork Molecule IDLN00241035
InChIInChI=1S/C15H15NO/c1-16(2)14-10-8-13(9-11-14)15(17)12-6-4-3-5-7-12/h3-11H,1-2H3
Canonical SMILESCN(C)C1=CC=C(C=C1)C(=O)C2=CC=CC=C2
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分类

  • {SNA} Amine Photochemical Coinitiators, Benzophenone, Organic Photoinitiators, Polymer Science, Polymerization Initiators, Reagents for Polymerization, 材料科学
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ketone; 1fragment
  • Amine Photochemical Coinitiators, Benzophenone, Materials Science, Organic Photoinitiators, Polymer Science, Polymerization Initiators
  • {SNA} Amine Photochemical Coinitiators, Benzophenone, Materials Science, Organic Photoinitiators, Polymer Science, Polymerization Initiators, Reagents for Polymerization

相关文献及参考

  • Short: EINECS
  • Short: III/35B

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning {} {} {} {} {} {} {TCI}
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light

其他信息

  • 上游原料:三氯氧磷 --> 稀盐酸 --> N-甲基苯胺 --> N-苯甲酰替苯胺
  • Acros Organics:4-(Dimethylamino)benzophenone, 98%(530-44-9)
  • 对二甲氨基二苯甲酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2561 4-(二甲氨基)二苯甲酮 4-(Dimethylamino)benzophenone 5G 373元 2014/06/02 D2561 4-(二甲氨基)二苯甲酮 4-(Dimethylamino)benzophenone 25G 1150元 2010/06/21 165190100 对二甲氨基二苯甲酮 4-(Dimethylamino)benzophenone 98% 10 GR 983元
  • 用途一:有机合成中间体。
  • TCI Shanghai:4-二甲氨基二苯甲酮 4-(Dimethylamino)benzophenone,>;97.0%(GC)(530-44-9)
  • Sigma Aldrich:530-44-9(sigmaaldrich)
  • 方法一:将苯甲酰苯胺，N,N-二甲基苯胺和三氯氧磷的混合物缓缓加热，至反应开始（突然放热），即改为冷却，控制温度不超过125℃。反应平缓后，用沸水浴加热3h。将反应物冷至50℃，慢慢倾入稀盐酸中，放置3h，使水解完全，然后向反应物加水，析出对二甲氨基二苯甲酮。
  • MSDS 信息:4-(Dimethylamino)benzophenone(530-44-9).msds
  • MOL 文件:530-44-9.mol
  • 图谱信息:对二甲氨基二苯甲酮(530-44-9)红外图谱(IR2) 对二甲氨基二苯甲酮(530-44-9)核磁图( 1 HNMR) 对二甲氨基二苯甲酮(530-44-9)质谱(MS) 对二甲氨基二苯甲酮(530-44-9)核磁图( 13 CNMR) 对二甲氨基二苯甲酮(530-44-9)Raman光谱 对二甲氨基二苯甲酮(530-44-9)红外图谱(IR1)
  • Alfa Aesar:4-二甲氨基苯并苯基酮,98% 4-Dimethylaminobenzophenone, 98%(530-44-9)

系列性分类

  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymerization Initiators - Polymer Science
  4. Amine Photochemical Coinitiators - Polymerization Initiators
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones

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