N,N,N',N'-Tetramethyldiaminomethane N,N,N′,N′-四甲基甲二胺

CAS 51-80-9 MFCD00008328

化学结构图

51-80-9
SMILES: CN(C)CN(C)C

化学属性

Mol. FormulaC5H14N2
Mol. Weight102.18
Refractive index1.3990 to 1.4030
Boiling Point84°C
Density0.749 g/mL at 25 °C(lit.)
Flash Point2°C(lit.)
TSCAYes
Melting Point-55°
pH:A

别名和识别编码

Chemical NameN,N,N',N'-Tetramethyldiaminomethane
Synonym ((CH3)2N)2CH2 2,4-Dimethyl-2,4-diazapentane 2-hydroxy-3-amino-5-chlorobenzoate BIS(DIMETHYLAMINO)METHANE Bis(dimethylamino methane) Bis(dimethylamino)methane, N,N,Nμ,Nμ-Tetramethylmethanediamine Bis(dimethylamino)methane~N,N,NN-Tetramethyldiaminomethane Bis-(dimethylamino)-methan Dimethyl[(dimethylamino)methyl]amine METHANEDIAMINENNNNTETRAMETHYL Methylenebis(dimethylamine) Methylenediamine, N, Methylenediamine, N,N,N',N'-tetramethyl- N',N'-tetramethylmethylenebisamine N,N N,N'-Methylenebis(dimethylamine) N,N,N',N'-Tetramethyl diaminomethane N,N,N',N'-Tetramethyl-methane diamine N,N,N',N'-Tetramethyldiaminomethane N,N,N',N'-Tetramethylmethanedi
CAS Number51-80-9
PubChem Substance ID87576781
EC Number200-124-7
Beilstein Registry Number4,54
MDL NumberMFCD00008328
Reaxys-RN1731946
Chemical Name TranslationN,N,N′,N′-四甲基甲二胺
Wiswesser Line Notation1N1&1N1&1
LabNetwork Molecule IDLN00222579
InChIInChI=1S/C5H14N2/c1-6(2)5-7(3)4/h5H2,1-4H3
Canonical SMILESCN(C)CN(C)C
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Caution! The product of double lithiation has been reported to explode on drying: Org. Process Res. Dev., 7, 1029 (2003).
  • Has been used as a convenient source of the Mannich intermediate: J. Org. Chem., 33, 1719 (1968). For an example (dimethylaminomethyleneation of ferrocene), see: Org. Synth. Coll., 5, 434 (1973). Reaction with o-hydroxy ɑ-aryl acetophenones leads directly to isoflavanones: Synth. Commun., 29, 3895 (1999):
  • Short: II/25D

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,C
RTECSPA6700000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger {} {} {} {} {} {} {TCI}
UN Number 2733 UN 2733 3/PG 2 UN2733
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
Packing GroupII
Hazard Class3/8
Storage condition Flammables area 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : >316 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EESADV Ecotoxicology and Environmental Safety.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1977-  Volume(issue)/page/year:
   6,149,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 220 mg/kg
TOXIC EFFECTS :
   Tumorigenic - active as anti-cancer agent
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 16,734,1966

其他信息

  • 四甲基甲烷二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 T0969 N,N,N',N'-四甲基甲二胺 N,N,N',N'-Tetramethyldiaminomethane 500ML 3700元 2011/04/16 T0969 N,N,N',N'-四甲基甲二胺 N,N,N',N'-Tetramethyldiaminomethane 25ML 446元 2010/06/21 138401000 四甲基甲烷二胺 N,N,N',N'-Tetramethyldiaminomethane 99% 100 ML 1464元
  • 下游产品:盐酸氟西汀B
  • Sigma Aldrich:51-80-9(sigmaaldrich)
  • TCI Shanghai:N,N,N',N'-四甲基甲二胺 N,N,N',N'-Tetramethyldiaminomethane,>;98.0%(GC)(T)(51-80-9)
  • Acros Organics:N,N,N',N'-四甲基二氨基甲烷 N,N,N',N'-Tetramethyldiaminomethane, 99%(51-80-9)
  • 四甲基甲烷二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0969 N,N,N',N'-四甲基甲二胺 N,N,N',N'-Tetramethyldiaminomethane 500ML 3510元 2014/06/02 T0969 N,N,N',N'-四甲基甲二胺 N,N,N',N'-Tetramethyldiaminomethane 25ML 423元 2010/06/21 138401000 四甲基甲烷二胺 N,N,N',N'-Tetramethyldiaminomethane 99% 100 ML 1464元
  • MOL 文件:51-80-9.mol
  • 图谱信息:四甲基甲烷二胺(51-80-9)红外图谱(IR2) 四甲基甲烷二胺(51-80-9)核磁图( 1 HNMR) 四甲基甲烷二胺(51-80-9)质谱(MS) 四甲基甲烷二胺(51-80-9)红外图谱(IR1)
  • Alfa Aesar:N,N,N',N'-四甲基亚甲二胺,99% N,N,N',N'-Tetramethylmethylenediamine, 99%(51-80-9)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Hydrazides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Hydrazides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Oximes
  1. Functional Group 官能团索引
  2. aminal

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