2,4,6-Tris(dimethylaminomethyl)phenol 2,4,6-三(二甲氨基甲基)苯酚

CAS 90-72-2 MFCD00008330

化学结构图

90-72-2
SMILES: CN(C)Cc1ccc(O)c(CN(C)C)c1CN(C)C

化学属性

Mol. FormulaC15H27N3O
Mol. Weight265.40
Refractive index1.5160 to 1.5190
Boiling Point320.5°C at 760 mmHg
Density0.969
Vapor Density>;1 (vs air)
Vapor Pressure<;0.01 mmHg ( 21 °C)
Flash Point124°C
Melting Point316 °C

别名和识别编码

Chemical Name2,4,6-Tris(dimethylaminomethyl)phenol
Synonym 2,4,6-Tris((dimethylamino)methyl)phenol {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {} {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {} {} {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {} {} {} {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {} {} {} {} {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {} {} {} {} {} {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {} {} {} {} {} {} {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Tris((dimethylamino)methyl)phenol
CAS Number90-72-2
PubChem Substance ID7026
EC Number202-013-9
Beilstein Registry Number795751
MDL NumberMFCD00008330
Alfabeta NameTRISDIMETHYLAMINOMETHYLPHENOL 246[]()-,,
Chemical Name Translation2,4,6-三(二甲氨基甲基)苯酚
Reaxys-RN795751
Wiswesser Line Notation1N1&1R BQ C1N1&1 E1N1&1
LabNetwork Molecule IDLN00182795
InChIInChI=1S/C15H27N3O/c1-16(2)9-12-7-13(10-17(3)4)15(19)14(8-12)11-18(5)6/h7-8,19H,9-11H2,1-6H3
Canonical SMILESOC1=C(CN(C)C)C=C(CN(C)C)C=C1CN(C)C
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分类

  • {SNA} Core Bioreagents, Embedding Media, Embedding and Mounting Media, Life Science Reagents for Immunohistochemistry (IHC), Microscopy Reagents, Research Essentials, Routine Histology Stains, Tissue Processing, 分析/色谱, 分析试剂, 细胞生物学, 血液学和组织学
  • {SNA} Analytical Reagents, Analytical/Chromatography, Core Bioreagents, Embedding Media, Embedding and Mounting Media, Hematology and Histology, Life Science Reagents for Immunohistochemistry (IHC), Microscopy Reagents, Research Essentials, Routine Histology Stains, Tissue Processing
  • {SNA} Building Blocks, C9 to C20+,

相关文献及参考

  • Mitrecić D, Cunko VF, Gajović S., Semi-thin sections of epoxy resin-embedded mouse embryos in morphological analysis of whole mount in situ RNA hybridization. J. Microsc. 232 , 504-507, (2008) 摘要
  • Yamaguchi M, Okada H, Namiki Y, Smart specimen preparation for freeze substitution and serial ultrathin sectioning of yeast cells. J. Electron Microsc. (Tokyo) 58 , 261-266, (2009) 摘要
  • Bleck CK, Merz A, Gutierrez MG, et. al., Comparison of different methods for thin section EM analysis of Mycobacterium smegmatis. J. Microsc. 237 , 23-38, (2010) 摘要
  • Giagnacovo M, Cardani R, Meola G, et. al., Routinely frozen biopsies of human skeletal muscle are suitable for morphological and immunocytochemical analyses at transmission electron microscopy. Eur. J. Histochem. 54 , e31, (2010) 摘要
  • Beil. 13 ,IV,1946
  • Aldrich MSDS 1 , 1814:C / Corp MSDS 1 (2), 3529:C / FT-IR 1 (1), 1299:A / FT-IR 2 (2), 2199:D / FT-NMR 1 (2), 631:A / IR-Spectra (3), 782:C / IR-Spectra (2), 687:A / RegBook 1 (1), 1501:L / Sax 6 , 2692 / Structure Index 1 , 235:B:3 / Vapor Phase 3 , 1175:C

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302+H312
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C Xn
RTECSSN3500000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Warnings IRRITANT
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Hazard Class8
UN Number 2735
Packing GroupIII
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1200 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 37,130,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1280 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ROHM** Rohm and Haas Company Data Sheets.  (Philadelphia, PA 19105)

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {}

系列性分类


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