Dimethyl Phenylphosphonite 二甲氧基苯基膦

CAS 2946-61-4 MFCD00008352

化学结构图

2946-61-4
SMILES: COP(OC)c1ccccc1

化学属性

Mol. FormulaC8H11O2P
Mol. Weight170.15
Refractive index1.5270 to 1.5310
Density1.072 g/mL at 25 °C(lit.)
Flash Point>110°(230°F)
TSCANo
Boiling Point102°C/15mmHg(lit.)
Appearance colorless liq.
Stabilityair sensitive, moisture sensitive

别名和识别编码

Chemical NameDimethyl Phenylphosphonite
Synonym Dimethyl phenylphosphonite {LY} Dimethyl phenylphosphonite {} {LY} Dimethyl phenylphosphonite {} {} {LY} Dimethyl phenylphosphonite {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {} {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {} {} {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl phenylphosphonite {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {
MDL NumberMFCD00008352
CAS Number2946-61-4
PubChem Substance ID76277
EC Number220-960-6
Beilstein Registry Number1073018
Chemical Name Translation二甲氧基苯基膦
InChIKeyLMZLQYYLELWCCW-UHFFFAOYSA-N
Reaxys-RN1073018
LabNetwork Molecule IDLN01071224
InChIInChI=1S/C8H11O2P/c1-9-11(10-2)8-6-4-3-5-7-8/h3-7H,1-2H3
Canonical SMILESCOP(C1=CC=CC=C1)OC
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors

相关文献及参考

  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {}
Hazard Codes C
UN Number 1760 UN 1760 8/PG 2
Hazard Class8
Packing GroupII

其他信息

  • 图谱信息:二甲基苯基膦酸盐(2946-61-4)核磁图( 13 CNMR) 二甲基苯基膦酸盐(2946-61-4)质谱(MS) 二甲基苯基膦酸盐(2946-61-4)红外图谱(IR1)
  • 敏感性:Air Sensitive
  • MOL 文件:2946-61-4.mol
  • 二甲基苯基膦酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 A14006 二甲基苯基膦酸盐 Dimethyl phenylphosphonite, 98% 5g 599元 2010/05/25 A14006 二甲基苯基膦酸盐 Dimethyl phenylphosphonite, 98% 25g 2394元 2010/05/25 A14006 二甲基苯基膦酸盐 Dimethyl phenylphosphonite, 98% 1g 183元
  • Sigma Aldrich:2946-61-4(sigmaaldrich)
  • Alfa Aesar:二甲基苯基膦酸盐 Dimethyl phenylphosphonite, 98%(2946-61-4)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus

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