Methyl 2-(Trimethylsilyl)Acetate 2-(三甲基硅烷基)乙酸甲酯

CAS 2916-76-9 MFCD00008450

化学结构图

2916-76-9
SMILES: COC(=O)C[Si](C)(C)C

化学属性

Mol. FormulaC6H14O2Si
Mol. Weight146.26
Refractive indexn20/D 1.414(lit.)
Boiling Point38-39 °C at 13 mmHg
Density0.891

别名和识别编码

Chemical NameMethyl 2-(Trimethylsilyl)Acetate
CAS Number2916-76-9
PubChem Substance ID76210
EC Number220-845-0
Beilstein Registry Number1098961
MDL NumberMFCD00008450
Synonym Methyl trimethylsilylacetate {LY} Methyl trimethylsilylacetate {} {LY} Methyl trimethylsilylacetate {} {} {LY} Methyl trimethylsilylacetate {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {} {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {} {} {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {} {} {} {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl trimethylsilylacetate {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation2-(三甲基硅烷基)乙酸甲酯
InChIKeyJIHUZDFFYVRXKP-UHFFFAOYSA-N
InChIInChI=1S/C6H14O2Si/c1-8-6(7)5-9(2,3)4/h5H2,1-4H3
Canonical SMILESO=C(OC)C[Si](C)(C)C
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分类

  • {uni_hamburg} no charge; ester; 1fragment
  • {SNA} Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

相关文献及参考

  • Aldrich MSDS 1 , 1319:C / Corp MSDS 1 (2), 2456:C / FT-IR 1 (2), 1114:C / FT-IR 2 (3), 4399:C / FT-NMR 1 (3), 684:B / NMR-Reference 2 (2), 1002:A / RegBook 1 (2), 2983:I / Structure Index 1 , 472:B:7 / Vapor Phase 3 , 1658:C
  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment, i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 "Nuclear Magnetic Resonance (NMR) Data" is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 ''NMR-Data'' is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei B-11 and P-31, subvolume III/35B contains the nuclei F-19 and N-15, subvolume III/35C contains the nucleus H-1, subvolume III/35D cont

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupIII
UN Number
Storage condition

系列性分类


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