2-(Dimethylamino)Ethyl Methacrylate 2-(二甲氨基)甲基丙烯酸乙酯

CAS 2867-47-2 MFCD00008589

化学结构图

2867-47-2
SMILES: C=C(C)C(=O)OCCN(C)C

化学属性

Mol. FormulaC8H15NO2
Mol. Weight157
Density0.933
Refractive index1.4380 to 1.4410
Vapor Density5.4 (vs air)
Boiling Point182-192
Vapor Pressure<;1 mmHg ( 25 °C)
Flash Point68°C(lit.)
TSCAYes
Melting Pointca -30°
Solubility分解
Stability对湿度和光线敏感

别名和识别编码

Chemical Name2-(Dimethylamino)Ethyl Methacrylate
Synonym 2-(DIMETHYLAMINO)ETHYL METHACRYLATE 2-(N,N 2-Dimethylaminoethyl-methacrylat 2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester 2-dimethylaminoethyl methacrylate Dimethylaminoethyl methacrylate Methacrylic acid 2-(dimethylamino)ethyl ester beta-(Dimethylamino)ethyl methacrylate {} {} {} {} {Chem 甲基丙烯酸-2(二甲氨基)乙酯,N,N-二甲氨基甲基丙烯酸乙酯 甲基丙烯酸二甲氨基乙酯
MDL NumberMFCD00008589
CAS Number2867-47-2
EC Number220-688-8
Beilstein Registry Number1757048
PubChem Substance ID17869
Reaxys-RN1757048
Chemical Name Translation2-(二甲氨基)甲基丙烯酸乙酯
Wiswesser Line Notation1UY1&VO2N1&1
LabNetwork Molecule IDLN00223199
InChIInChI=1S/C8H15NO2/c1-7(2)8(10)11-6-5-9(3)4/h1,5-6H2,2-4H3
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分类

  • {uni_hamburg} no charge; ester; 1fragment
  • {SNA} Acrylic Monomers, Amine Photochemical Coinitiators, Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters, Materials Science, Methacrylate, Monomers, Organic Building Blocks,
  • {SNA} Acrylic Monomers, Amine Photochemical Coinitiators, Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters, Methacrylate, Monomers, Organic Building Blocks, Polymer Science, Polymerization Initiators, Reagents for Polymerization, 材料科学

相关文献及参考

  • Short: IV/20C
  • Short: EINECS
  • Short: IV/8A
  • Beilstein:4(3)649

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P330+P331+P310
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302+H312
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSOZ4200000
Packing GroupII
UN Number 2522 UN2522
Hazard Codes 6.1 T Xn Xn;Xi
Storage condition 储存温度2-8℃ 0-6°C
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1800 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,55,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 620 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,55,1982

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 20800 nL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 63,376,197

其他信息

  • 海关编码:29221980
  • MOL 文件:2867-47-2.mol
  • Sigma Aldrich:2867-47-2(sigmaaldrich)
  • 急性毒性:吸入-大鼠 LC50: 0.62 克/立方米/4小时; 腹注-小鼠 LD50: 25 毫克/公斤
  • 检测方法:GC,NMR
  • Acros Organics:甲基丙烯酸 2-(二甲氨基)乙酯 2-(Dimethylamino)ethyl methacrylate, stabilized, 99%(2867-47-2)
  • 类别:有毒物品
  • 毒性分级:剧毒
  • 灭火剂:干粉, 泡沫, 砂土
  • Alfa Aesar:2-(二甲基氨)乙基甲基丙烯酸盐,97%,stab.withca0.2%4-methoxyphenol 2-(Dimethylamino)ethyl methacrylate, 97%, stab. with ca 0.2% 4-methoxyphenol(2867-47-2)
  • 能与水及酯、酮、醇、醚、烃、氯代烃等多种有机溶剂互溶。
  • 存储注意事项:光敏感;湿度敏感
  • 用途一:用于制备聚合物、净化污水
  • 蒸气压:<;1 mm Hg ( 25 °C)
  • 储运特性:库房通风低温干燥; 与氧化剂, 食品分开储运
  • 下游产品:微波法合成的阳离子高吸水性树脂
  • 甲基丙烯酸二甲氨乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0082 甲基丙烯酸2-(二甲氨基)乙酯(含稳定剂MEHQ) 2-(Dimethylamino)ethyl Methacrylate (stabilized with MEHQ) 25ML 206元 2014/06/02 M0082 甲基丙烯酸2-(二甲氨基)乙酯(含稳定剂MEHQ) 2-(Dimethylamino)ethyl Methacrylate (stabilized with MEHQ) 500ML 664元 2010/06/21 215840050 甲基丙烯酸二甲氨乙酯 2-(Dimethylamino)ethyl methacrylate 99%, stabilized 5 GR 399元
  • F:19
  • 用途二:甲基丙烯二甲氨乙酯可用于制造高性能涂料(如高级内墙涂料,耐磨马路划线漆,)粘合剂。用于电子、印刷、纺织、建筑等行业。
  • 图谱信息:甲基丙烯酸二甲氨乙酯(2867-47-2)核磁图( 1 HNMR) 甲基丙烯酸二甲氨乙酯(2867-47-2)Raman光谱 甲基丙烯酸二甲氨乙酯(2867-47-2)质谱(MS) 甲基丙烯酸二甲氨乙酯(2867-47-2)核磁图( 13 CNMR) 甲基丙烯酸二甲氨乙酯(2867-47-2)红外图谱(IR1)
  • 蒸气密度:5.4 (vs air)
  • 可燃性危险特性:可燃; 燃烧产生有毒氧化氮气体; 水解
  • TCI Shanghai:甲基丙烯酸二甲氨乙酯 2-(Dimethylamino)ethyl Methacrylate (stabilized with MEHQ),>;98.5%(GC)(2867-47-2)
  • 外观性质:无色液体,具有催泪性气味。
  • MSDS 信息:甲基丙烯酸二甲氨乙酯(2867-47-2).msds

系列性分类