Methyl acrylate 丙烯酸甲酯

CAS 96-33-3 MFCD00008627

化学结构图

96-33-3
SMILES: C=CC(=O)OC

化学属性

Mol. FormulaC4H6O2
Mol. Weight86
Refractive index1.4010 to 1.4040
Boiling Point80
Density0.956
Melting Point-75
Flash Point-1°C(lit.)
TSCAYes
Autoignition Point874 °F
Vapor Density3 (vs air)
Vapor Pressure67.5 mmHg ( 20 °C)
Solubility60 G/L (20 ºC)
Stability对光敏感
Danger-Level甲类
pH:A

别名和识别编码

Chemical NameMethyl acrylate
CAS Number96-33-3
PubChem Substance ID87561834
EC Number202-500-6
Beilstein Registry Number605396
MDL NumberMFCD00008627
Reaxys-RN605396
Merck Number6011
Synonym 2-Propensäuremethylester Propenoic acid methyl ester Methylacrylat Acrylsäure-methylester 2-Propenoic acid methyl ester METHYL ACRYLATE {Chemica 2-Propenoic acid, methyl ester 败脂酸甲酯,2-丙烯酸甲酯,丙烯酸甲酯浆料;异丁烯酸盐;甲基丙烯酸盐 methyl propenoate acrylic acid, methyl ester acrylatedemethyle Acrylsaeuremethylester Methylester kyseliny akrylove MA Methyl propenate METHYL 2-PROPENOATE Methacrylate Methyl 2-propenoate propenoic acid, methyl ester 丙烯酸甲酯(MA) acrylatedemethyle(french) 败脂酸甲酯 Methylprop-2-enoat Methyl-2-propenoat ACRYLIC ACID METHYL ESTER curithane103 丙烯酸甲酯 Methylacrylaat [sri773]methylacrylate,monomer methyl 2-propenoate Methyl propenoate 丙烯酸甲酯, 99%, STAB. WITH CA 15PPM 4-METHOXYPHENOL Acrylsäuremethylester 丙烯酸甲酯,异丁烯酸盐,甲基丙烯酸盐 AKOS BBS-00004387 Acrylic acid methyl ester Acrylate de methyle Methoxycarbonylethylene Methyl-acrylat Methyl-2-propenoate Methyl ester acrylic acid 2-Propenoicacidmethylesetr Metilacrilato Methyl acrylate 丙烯酸甲酯 METHYL ACRYLATE CH2=CHCOOCH3 2-PROPENOIC ACID METHYL ESTER 丙烯酸甲酯浆料 Curithane 103 prop-2-enoic acid methyl ester Methyl acrylate, inhibited 败脂酸甲酯,2-丙烯酸甲酯,丙烯酸甲酯浆料 Methyl prop-2-enoate METHYL PROPENOATE methyl acrylate Methyl acrylic ester
Chemical Name Translation丙烯酸甲酯
Wiswesser Line Notation1U1VO1
LabNetwork Molecule IDLN00193624
InChIInChI=1S/C4H6O2/c1-3-4(5)6-2/h3H,1H2,2H3
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分类

  • {SA} Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • {SNA} Acrylate, Acrylic Monomers, Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Monomers, Organic Building Blocks, Polymer Science, 材料科学
  • {SNA} Additional Standards, Alpha Sort, Analytical Standards, Chemical Class, Chromatography, Environmental Standards, Esters, Fatty Acids, Lipid Analytical Standards,
  • {SNA} Acrylate,

产品应用

  • 1 .高分子聚合单体。
  • 2 .有机合成。供制作涂料、纺织、皮革、粘合剂等工业用的各种树脂。

相关文献及参考

  • Short: II/25C
  • Short: II/6
  • Merck: 14,6011
  • Merck: 14,6011 Beilstein:2(4)1457

安全信息

GHS Symbol
WGK Germany2
Hazard Codes 3
Hazard statements
  • H312+H332
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H301 Toxic if swallowed 吞食有毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H332 Harmful if inhaled 吸入有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H302+H312
  • H331 Toxic if inhaled 吸入中毒
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSAT2800000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P352+P312+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P351+P338+P337+P313
  • P308+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P233
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S25 Avoid contact with eyes 避免眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
UN Number 1919
Packing GroupII
Storage condition Light Sensitive 密封阴凉避光保存。 密封阴凉避光保存。储存温度2-8°C Refrigerator (+4°C) + Flammables area
Hazard Class3
Warnings 危化品目录(2015)
{h

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 75 ppm
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,75,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 277 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 36,58,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1243 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 30,63,1948

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 254 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JDREAF Journal of Dental Research.  (International Assoc. for Dental
   Research, 734 15th St., NW, Suite 809, Washington, DC 20005)  V.1-    1919

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Fibroblast
DOSE/DURATION           : 189 ppm
REFERENCE :
   ESKHA5 Eisei Shikenjo Hokoku.  Bulletin of the Institute of Hygienic
   Sciences.  (Kokuritsu Eisei Shikenjo Kagaku, 18-1 Bushitsu Johobu,
   Setagaya-ku, Tokyo 158, Japan)  V.1-    1886-  Volume(issue)/page/year:
   (102),77,1984

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 6500 ug/L
REFERENCE :
   GMCRDC Gann Monograph on Cancer Research.  (Plenum Pub. Corp., 233 Spring
   St., New York, NY 10013) No. 11-    1971-  Volume(issue)/page/year:
   27,95,1981

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 37500 ug/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 135,189,1984

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 14 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11,49,1988

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 22 mg/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 8(Suppl
   6),4,1986

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 22 mg/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For

Restrict 危险品

其他信息

  • {Chem
  • 防护措施:丙烯酸甲酯毒性中等,对眼、皮肤、粘膜有较强的刺激和腐蚀作用,并可经皮肤吸收而引起中毒,大鼠经口LD50
  • 毒性分级:中毒
  • 图谱
  • 下游产品:2-膦酸丁烷-1,2,4-三羧酸 --> 无纺布胶 --> BT型改性丙烯酸树脂涂饰剂系列 --> CSF系列改性丙烯酸树脂乳液 --> 1-甲基-4-哌啶酮盐酸盐 --> 防油、防水涂饰剂 --> 全候性系列树脂 --> AC防霉涂饰剂 --> 桃醛 --> 十四醛三聚物 --> 丙烯酸 2-乙基己酯 -->
  • 职业标准:TWA 35 毫克/ 立方米
  • 防护措施:丙烯酸甲酯毒性中等,对眼、皮肤、粘膜有较强的刺激和腐蚀作用,并可经皮肤吸收而引起中毒,大鼠经口LD50为300mg/kg。兔口服LD50为280mg/kg。慢性中毒症状为头痛、嗜睡、手脚痉挛等。工作场所最高容许浓度为35mg/m3。操作场所应加强通风。操作人员应佩戴胶手
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1
  • 图谱信息:丙烯酸甲
  • MSDS 信息:丙烯酸甲酯(96-33-3).msds
  • 爆炸物危险特性:与空气混合可爆
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 图谱信息:丙烯酸甲酯(96-33-3)质谱(MS) 丙烯酸甲酯(96-33-3)红外图谱(IR1) 丙烯酸甲酯(96-33-3)核磁图( 13 CNMR) 丙烯酸甲酯(96-33-3)Raman光谱 丙烯酸甲酯(96-33-3)核磁图( 1 HNMR)
  • {Chemi
  • Acros Organics:甲基丙烯酸酯 Methyl acrylate, stabilized, 99%(96-33-3)
  • 蒸气密度:3 (vs air)
  • 刺激数据:眼睛- 兔子 100 毫克 重度; 皮肤- 兔子 10 毫克/ 24小时
  • Alfa Aesar:丙烯酸甲酯,99%,stab.withca15ppm4-methoxyphenol Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol(96-33-3)
  • 上游原料:甲醇 --> 马来酸酐 --> 环氧丙烷 --> 甘油 --> 丙烯酸 --> 卡波姆树脂 --> 丙烯酰胺 --> 蓖麻油 --> 丙烯醛 --> 苯甲酸 --> 丙
  • 用途四:丙烯酸甲酯是有机合成中间体及合成高分子的单体,由丙烯酸甲酯合成共聚橡胶具有良好的耐高温及耐油性能。与丙烯腈共聚可改变聚丙烯腈纤维的可纺性、耐塑料及染色性。与甲基丙烯酸甲酯、乙酸乙烯或苯乙烯共聚是性能良好的涂料和地板上光剂。此外,在医药制造、皮革加工、造纸、粘合剂制造、油漆等工业中也有其日益广泛的用途。
  • 上游原料:甲醇 --> 马来酸酐 --> 环氧丙烷 --> 甘油 --> 丙烯酸 --> 卡波姆树脂 --> 丙烯酰胺 --> 蓖麻油 --> 丙烯醛 --> 苯甲酸 --> 丙二醇 --> 植物油 --> 季戊四醇 --> 聚醚 --> 乙烯酮 --> 菜籽油
  • 有辛辣气味,是一种催泪剂。易燃,微溶于水。水中溶解度在20℃时为6g/100ml;40℃时5克/100ml,水在丙烯甲酯中溶解度为1.8ml/100g。能溶于醇和醚。在贮存过程中易聚合,光、热和过氧化物能加速其聚合作用。纯粹的单体在低于10℃时不聚合。通常加入对苯二酚单甲醚0.1%作阻聚剂。易燃。中等毒,
  • 有辛辣气味,是一种催泪剂。易燃,微溶于水。水中溶解度在20℃时为6g/100ml;40℃时5克/100ml,水在丙烯甲酯中溶解度为1.8ml/100g。能溶于醇和醚。在贮存过程中易聚合,光、热和过氧化物能加速其聚合作用。纯粹的单体在低于10℃时不聚合。通常加入对苯二酚单甲醚0.1%作阻聚剂。易燃。中等毒,半数致死量(大鼠,经口)0.3g/kg。有催泪性。对呼吸系统和皮肤有刺激性。易
  • 用途三:主要用于涤/棉、涤/腈等混纺织物经纱上浆
  • 蒸气压:67.5 mm Hg ( 20 °C)

系列性分类


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