Triacetoxymethylsilane 甲基三乙酰氧基硅烷

CAS 4253-34-3 MFCD00008694

化学结构图

4253-34-3
SMILES: CC(=O)O[Si](C)(OC(C)=O)OC(C)=O

化学属性

Mol. FormulaC7H12O6Si
Mol. Weight220.25
Boiling Point94-95 °C at 9 mmHg
Density1.20
Melting Point40-45 °C
Flash Point85°(185°F)
TSCAYes
Refractive index1.4045-1.4055
Appearance 无色或浅黄色透明液体较底温下白色晶体
Stability对湿度敏感

别名和识别编码

Chemical NameTriacetoxymethylsilane
Synonym Triacetoxymethylsilane {LY} Triacetoxymethylsilane {} {LY} Triacetoxymethylsilane {} {} {LY} Triacetoxymethylsilane {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triacetoxymethylsilane {} {} {} {} {} {} {} {}
CAS Number4253-34-3
PubChem Substance ID77929
EC Number224-221-9
Beilstein Registry Number4(4)4208
MDL NumberMFCD00008694
Reaxys-RN1788668
Chemical Name Translation甲基三乙酰氧基硅烷
InChIKeyTVJPBVNWVPUZBM-UHFFFAOYSA-N
Wiswesser Line Notation1VO-SI-1&OV1&OV1
LabNetwork Molecule IDLN00223795
Canonical SMILESC[Si](OC(C)=O)(OC(C)=O)OC(C)=O
InChIInChI=1S/C7H12O6Si/c1-5(8)11-14(4,12-6(2)9)13-7(3)10/h1-4H3
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分类

  • {uni_hamburg} no charge; ester; 1fragment
  • {SNA} Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

产品应用

  • 合成交联性树脂,还可处理各种无机填料。

相关文献及参考

  • Beilstein:4(4)4208
  • Short: EINECS
  • Short: II/5

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H303 May be harmfully swallowed 吞食可能有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
RTECSVV4500000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P309+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
UN Number 1759 UN1759
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Moisture Sensitive 充氩保存 对湿度敏感
Packing GroupIII
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2060 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1229,1986

其他信息

  • 用途一:主要用于室温硫化硅橡胶剂及作为合成原料。
  • TCI Shanghai:甲基三乙酰氧基硅烷 Triacetoxymethylsilane,>;92.0%(GC)(4253-34-3)
  • 用途三:用作交联剂,可用于塑料、尼龙、陶瓷、铝等与硅橡胶的粘合
  • F:9-21
  • 甲基三乙酰氧基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1786 甲基三乙酰氧基硅烷 Triacetoxymethylsilane 25G 316元 2010/05/25 B23974 三乙酰氧基甲基硅烷, 96% Triacetoxy(methyl)silane, 96% 50g 1340元 2010/05/25 B23974 三乙酰氧基甲基硅烷, 96% Triacetoxy(methyl)silane, 96% 250g 4340元
  • MOL 文件:4253-34-3.mol
  • 用途二:用作合成橡胶抑制剂、添加剂
  • Alfa Aesar:三乙酰氧基甲基硅烷,96% Triacetoxy(methyl)silane, 96%(4253-34-3)
  • 甲基三乙酰氧基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 T1786 甲基三乙酰氧基硅烷 Triacetoxymethylsilane 25G 447元 2010/05/25 B23974 三乙酰氧基甲基硅烷, 96% Triacetoxy(methyl)silane, 96% 50g 1340元 2010/05/25 B23974 三乙酰氧基甲基硅烷, 96% Triacetoxy(methyl)silane, 96% 250g 4340元
  • 敏感性:Moisture Sensitive
  • Sigma Aldrich:4253-34-3(sigmaaldrich)
  • TSCA:Yes

系列性分类


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