D-(-)-TARTARIC ACID DIISOPROPYL ESTER D-(-)-酒石酸二异丙酯

CAS 62961-64-2 MFCD00008876

化学结构图

62961-64-2
SMILES: CC(C)OC(=O)[C@@H](O)[C@H](O)C(=O)OC(C)C

化学属性

Mol. FormulaC10H18O6
Mol. Weight234
Density1.119
Refractive index1.4380 to 1.4400
Flash Point110°(230°F)
TSCAYes
Boiling Point275

别名和识别编码

Chemical NameD-(-)-TARTARIC ACID DIISOPROPYL ESTER
Synonym (-)-Diisopropyl D-tartrate D-(-)-Tartaric acid diisopropyl ester D-(-)-酒石酸二异丙酯 D-Tartaric acid diisopropyl ester
MDL NumberMFCD00008876
PubChem Substance ID87577153
Beilstein Registry Number5265431
EC Number263-771-4
CAS Number62961-64-2
Reaxys-RN4313086
Chemical Name TranslationD-(-)-酒石酸二异丙酯
LabNetwork Molecule IDLN00188258
InChIKeyXEBCWEDRGPSHQH-YUMQZZPRSA-N
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Chiral Resolution Reagents, Chiral Resolving Reagents, Epoxidation, Esters, Organic Building Blocks

相关文献及参考

  • For the use of esters of tartaric acid as chiral auxiliaries in the Sharpless enantioselective epoxidation of allylic alcohols, see tert-Butyl­ hydroperoxide, A13926. For a review the use of tartrate esters as chiral auxiliaries, e.g. in the Simmons-Smith cyclopropanantion reaction and in 1,3-dipolar cycloaddition reactions, see: Synlett, 1075 (2003).

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Signal word Warning
GHS Symbol
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Deprotonation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Epoxidation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Epoxidation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acids - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Epoxides 环氧化物

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