Isobutyl vinyl ether 异丁基乙烯基醚

CAS 109-53-5 MFCD00008934

化学结构图

109-53-5
SMILES: C=COCC(C)C

化学属性

Mol. FormulaC6H12O
Mol. Weight100
Density0.768
Refractive index1.3950 to 1.3980
Flash Point-15°C(lit.)
Melting Point-112
Boiling Point82-83
Solubility微溶于水，溶于醇、醚。
Vapor Density3.45 (vs air)
Vapor Pressure68 mmHg ( 20 °C)

别名和识别编码

Chemical NameIsobutyl vinyl ether
MDL NumberMFCD00008934
CAS Number109-53-5
EC Number203-678-8
Beilstein Registry Number1560159
Synonym 1-(Ethenyloxy)-2-methylpropane 1-(ethenyloxy)-2-methyl-propan 1-(乙烯氧基)-2-甲基丙烷 1-(乙烯氧基)-2-甲基丙烷,异丁氧基乙烯 1-Ethenyloxy-2-methylpropan 2-Methyl-1-vinyloxypropane 2-methyl-1-propyl vinyl ether 2-methyl-1-propylvinylether Ethenyl2-methylpropylether Isobutoxyethene Isobutyl-vinylether Vinoflex MO 400* Vinyl isobutyl ether Vinyl isobutyl ether); 1-(Ethenyloxy)-2-methyl-propane Vinyl-isobutyläther Vinylisobutylether ether,isobutylvinyl isobutoxy-ethene isobutyl-vinyl ether 乙烯基异丁醚 异丁基乙烯基醚 异丁基乙烯醚
PubChem Substance ID7992
Reaxys-RN1560159
Chemical Name Translation异丁基乙烯基醚
Wiswesser Line Notation1Y1O1U1
LabNetwork Molecule IDLN00224297
InChIInChI=1S/C6H12O/c1-4-7-5-6(2)3/h4,6H,1,5H2,2-3H3
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分类

  • {SNA} Monomers, Polymer Science, Vinyl Ethers, 材料科学
  • {uni_hamburg} no charge; ether; 1fragment
  • {SNA} Materials Science, Monomers, Polymer Science, Vinyl Ethers

产品应用

  • 用于有机合成，可用于聚合和共聚生产聚乙烯基醚，用于涂料、助剂、增塑剂等。

相关文献及参考

  • Beilstein:1(4)2054
  • Short: III/35E
  • Short: III/38B
  • Short: IV/10A

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R52/53
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard Codes 3 F;Xi
UN Number 1304
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSKO1300000
Storage condition 0-10 Flammables area 0-10°C 储存温度2-8℃，充氩保存
Packing GroupII
Hazard Class3
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 16000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 20 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 17 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

其他信息

  • 用途一:用于聚合和共聚生产聚乙烯基醚，也用于涂料助剂
  • 毒性分级:低毒
  • 检测方法:GC,NMR
  • 灭火剂:干粉、干砂、干石粉、二氧化碳、泡沫
  • 类别:易燃液体
  • 蒸气密度:3.45 (vs air)
  • MOL 文件:109-53-5.mol
  • 用途三:用于有机合成，可用于聚合和共聚生产聚乙烯基醚，用于涂料、助剂、增塑剂等。
  • 急性毒性:口服- 大鼠 LD50:17000 毫克/ 公斤; 吸入- 大鼠 LC50:16000 PPM/ 4小时
  • MSDS 信息:异丁基乙烯基醚(109-53-5).msds
  • TCI Shanghai:异丁基乙烯基醚(含稳定剂氢氧化钾) Isobutyl Vinyl Ether (stabilized with KOH),>;99.0%(GC)(109-53-5)
  • F:9
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生刺激烟雾
  • 用途二:氯醚树脂是一种氯乙烯(VCM)和乙烯基异丁醚(109-53-5)的共聚物。
  • 乙烯基异丁醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0099 异丁基乙烯基醚(含稳定剂氢氧化钾) Isobutyl Vinyl Ether (stabilized with KOH) 25ML 165元 2014/06/02 I0099 异丁基乙烯基醚(含稳定剂氢氧化钾) Isobutyl Vinyl Ether (stabilized with KOH) 500ML 588元 2010/06/21 302672500 乙烯基异丁醚 Isobutyl vinyl ether 99.5%, stabilized 250 ML 347元
  • 图谱信息:乙烯基异丁醚(109-53-5)红外图谱(IR1) 乙烯基异丁醚(109-53-5)Raman光谱 乙烯基异丁醚(109-53-5)红外图谱(IR2) 乙烯基异丁醚(109-53-5)核磁图( 1 HNMR) 乙烯基异丁醚(109-53-5)质谱(MS) 乙烯基异丁醚(109-53-5)核磁图( 13 CNMR)
  • 参考价格:乙烯基异丁醚（109-53-5）28500元/吨
  • Acros Organics:乙烯基异丁基醚 Isobutyl vinyl ether, stabilized, 99.50%(109-53-5)
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • 蒸气压:68 mm Hg ( 20 °C)
  • 外观性质:无色液体。
  • Sigma Aldrich:109-53-5(sigmaaldrich)
  • 危险类别:乙烯基异丁醚（109-53-5）属于第三类易燃液体。
  • 水中溶解度:　0.7 g/l (25°C) 。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Vinyl Ethers - Monomers
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Analytical Reagents
  1. Functional Group 官能团索引
  2. enol ether

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