4,4'-Bis(diethylamino)benzophenone 4,4’-双(二乙胺基)二苯甲酮

CAS 90-93-7 MFCD00009044

化学结构图

90-93-7
SMILES: CCN(CC)c1ccc(C(=O)c2ccc(N(CC)CC)cc2)cc1

化学属性

Mol. FormulaC21H28N2O
Mol. Weight324.46
Melting Point89-92 °C
Density1.048
Flash Point151°(303°F)
TSCAYes
Solubility不溶
Stability对光敏感
Appearance 浅黄色均匀粉末，熔点 95°C，闪点151°C，不溶于水。
Boiling Point475.7±30.0 °C at 760 mmHg

别名和识别编码

Chemical Name4,4′-Bis(diethylamino)benzophenone
CAS Number90-93-7
PubChem Substance ID66663
EC Number202-025-4
Beilstein Registry Number14,98
MDL NumberMFCD00009044
Reaxys-RN2148611
Synonym 4,4'-Bis(diethylamino)benzophenone {LY} 4,4'-Bis(diethylamino)benzophenone {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Bis(diethylamino)benzophenone {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation4,4’-双(二乙胺基)二苯甲酮
InChIKeyVYHBFRJRBHMIQZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00202261
InChIInChI=1S/C21H28N2O/c1-5-22(6-2)19-13-9-17(10-14-19)21(24)18-11-15-20(16-12-18)23(7-3)8-4/h9-16H,5-8H2,1-4H3
Canonical SMILESO=C(C1=CC=C(C=C1)N(CC)CC)C2=CC=C(C=C2)N(CC)CC
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分类

  • {SA} Building Blocks, C15 to C38, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • {SNA} Amine Photochemical Coinitiators, Benzophenone, Materials Science, Organic Photoinitiators, Polymer Science, Polymerization Initiators, Reagents for Polymerization
  • Amine Photochemical Coinitiators, Benzophenone, Materials Science, Organic Photoinitiators, Polymer Science, Polymerization Initiators
  • {SNA} Building Blocks, C15 to C38, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

相关文献及参考

  • Beilstein: 14,II,59

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes 9
RTECSOS9545500
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R50/53
  • R51/53
  • R36 Irritating to eyes 刺激眼睛
UN Number UN3077 UN 3077 9/PG 3 3077
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Packing GroupIII
Hazard Class9

其他信息

  • 四乙基米氏酮作用:碱性染料的重要中间体，用于碱性艳蓝B、碱性艳蓝R等的生产。
  • MOL 文件:90-93-7.mol
  • 制备碱性兰7:以四乙基米氏酮 [benzophenone, 4, 4'-bis (diethylamino)] 和 N-乙基-1-萘胺为原料，将两者在三氯氧磷存在下缩合，经稀释、水解、提纯、盐析即得成品。
  • Acros Organics:4,4'-双(二乙胺基)二苯甲酮 4,4'-Bis(diethylamino)benzophenone, 99+%(90-93-7)
  • 用途三:光引发剂EMK 用作染料中间体,用于合成三芳甲烷类染料，如碱性艳蓝BO；也可作为光敏剂用于电影胶片工业；作为特种光学材料用于微电工业；还可用作橡胶交联剂。由N,N-二乙基苯胺与光气反应而得，也可采用氧化法合成。
  • F:8
  • 图谱信息:四乙基米氏酮(90-93-7)红外图谱(IR1) 四乙基米氏酮(90-93-7)质谱(MS) 四乙基米氏酮(90-93-7)核磁图( 1 HNMR) 四乙基米氏酮(90-93-7)核磁图( 13 CNMR) 四乙基米氏酮(90-93-7)红外图谱(IR2)
  • 不溶于水。
  • 下游产品:碱性蓝 7
  • 四甲基米氏酮合成方法:由N,N-二甲基苯胺与光气缩合而得。
  • MSDS 信息:4,4'-Bis(diethylamino) benzophenone(90-93-7).msds
  • Sigma Aldrich:90-93-7(sigmaaldrich)
  • Hazard Note:Irritant
  • 用途二:UV固化型涂料和油墨
  • TCI Shanghai:4,4'-双二乙氨基二苯甲酮 4,4'-Bis(diethylamino)benzophenone,>;98.0%(T)(90-93-7)
  • 上游原料:光气(无法供)
  • 敏感性:Light Sensitive
  • 用途一:用作染料中间体
  • 四乙基米氏酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1275 4,4'-双(二乙氨基)苯甲酮 4,4'-Bis(diethylamino)benzophenone 500G 1640元 2014/06/02 B1275 4,4'-双(二乙氨基)苯甲酮 4,4'-Bis(diethylamino)benzophenone 25G 190元 2014/06/02 B0139 4,4'-双(二乙氨基)二苯甲酮 4,4'-Bis(diethylamino)benzophenone 25G 242元
  • Alfa Aesar:4,4'-二(二乙氨基)苯甲酮,99% 4,4'-Bis(diethylamino)benzophenone, 99%(90-93-7)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C15 to C38 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C15 to C38 - Ketones
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymerization Initiators - Polymer Science
  4. Amine Photochemical Coinitiators - Polymerization Initiators
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Polymerization Initiators
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C13 to C14
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Polymerization Initiators
  4. Organic Photoinitiators
  5. Benzil and Benzoin Compounds
  1. Materials Science 材料科学
  2. Photopolymerization Initiators

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