Phenyltriethoxysilane 苯基三乙氧基硅烷

CAS 780-69-8 MFCD00009065

化学结构图

780-69-8
SMILES: CCO[Si](OCC)(OCC)C1C=CC=CC=1

化学属性

Mol. FormulaC12H20O3Si
Mol. Weight240.37
Density0.996
Refractive index1.4580 to 1.4630
Vapor Density>;1 (vs air)
Boiling Point112-113 °C at 10 mmHg
Flash Point42.8°C
TSCAYes
Solubility不溶
Stability对湿度敏感
Appearance 无色透明液体，气味温和
Melting Point<-50 °C

别名和识别编码

Chemical NamePhenyltriethoxysilane
Synonym Triethoxy(phenyl)silane {LY} Triethoxy(phenyl)silane {} {LY} Triethoxy(phenyl)silane {} {} {LY} Triethoxy(phenyl)silane {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethoxy(phenyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number780-69-8
EC Number212-305-8
Beilstein Registry Number2940602
MDL NumberMFCD00009065
PubChem Substance ID87574882
Chemical Name Translation苯基三乙氧基硅烷
Reaxys-RN2940602
Wiswesser Line Notation2O-SI-R&O2&O2
LabNetwork Molecule IDLN00202620
Canonical SMILESCCO[Si](OCC)(C1=CC=CC=C1)OCC
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分类

  • {SA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Trialkoxysilanes
  • {SNA} Chemical Synthesis, Materials Science, Micro/NanoElectronics, Organometallic Reagents, Organosilicon, Silanes, Silicon, Solution Deposition Precursors, Trialkoxysilanes
  • {SNA} Chemical Synthesis, Materials Science, Micro/NanoElectronics, Nanomaterials, Organometallic Reagents, Organosilicon, POSS Precursors and Intermediates, RSi(OR&#8243;)3, Self Assembly & Contact Printing, Self-Assembly Materials, Silanes, Silsesquioxanes: POSS Nanohybri
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Beilstein:16,911
  • Short: IV/18A
  • Short: III/35E
  • Short: III/38A

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R10 Flammable 易燃
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
Hazard statements
  • H303+H313
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSVV4900000
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Flammables area Moisture Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored u
Hazard Codes Xn 3
UN Number 1993
Packing GroupIII
Hazard Class3.2 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2830 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3180 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

其他信息

  • Sigma Aldrich:780-69-8(sigmaaldrich)
  • 海关编码:29310095
  • 图谱信息:苯基三乙氧基硅烷(780-69-8)核磁图( 13 CNMR) 苯基三乙氧基硅烷(780-69-8)质谱(MS) 苯基三乙氧基硅烷(780-69-8)红外图谱(IR1) 苯基三乙氧基硅烷(780-69-8)核磁图( 1 HNMR)
  • 上游原料:乙醚 --> 镁 --> 溴苯 --> 硅酸四乙酯
  • 苯基三乙氧基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0735 三乙氧基苯基硅烷 Triethoxyphenylsilane 500ML 1200元 2014/06/02 P0735 三乙氧基苯基硅烷 Triethoxyphenylsilane 25ML 163元 2010/06/21 174640010 苯基三乙氧基硅烷 Phenyltriethoxysilane 98% 1 KG 1405元
  • 蒸气密度:>;1 (vs air)
  • MOL 文件:780-69-8.mol
  • Alfa Aesar:苯基三乙氧基硅烷,98% Phenyltriethoxysilane, 98%(780-69-8)
  • TCI Shanghai:苯基三乙氧基硅烷 Triethoxyphenylsilane,>;99.0%(GC)(780-69-8)
  • F:10-21
  • MSDS 信息:Phenyltriethoxysilane(780-69-8).msds
  • 用途一:用作制备高分子有机化合物的原料
  • 敏感性:Moisture Sensitive
  • Acros Organics:苯基三乙氧基硅烷 Phenyltriethoxysilane, 98%(780-69-8)
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Trialkoxysilanes - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Trialkoxysilanes - Organosilicon
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Self Assembly &amp; Contact Printing - Micro/NanoElectronics
  4. Self-Assembly Materials - Self Assembly &amp; Contact Printing
  5. Silanes - Self-Assembly Materials
  1. Materials Science 材料科学
  2. Nanomaterials - Materials Science
  3. Silsesquioxanes: POSS&reg; Nanohybrids - Nanomaterials
  4. POSS&reg; Precursors and Intermediates - Silsesquioxanes: POSS&reg; Nanohybrids
  5. RSi(OR&Prime;)3 - POSS&reg; Precursors and Intermediates
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Silicon - Solution Deposition Precursors
  5. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Siloxanes 硅氧烷

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