Ethyl (Diethoxyphosphoryl)Formate 甲膦酸三乙酯

CAS 1474-78-8 MFCD00009108

化学结构图

1474-78-8
SMILES: CCOC(=O)P(=O)(OCC)OCC

化学属性

Mol. FormulaC7H15O5P
Mol. Weight210.16
Density1.11 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.423(lit.)
Flash Point119°C(lit.)
TSCAYes
Boiling Point135 °C at 12 mmHg

别名和识别编码

Chemical NameEthyl (Diethoxyphosphoryl)Formate
MDL NumberMFCD00009108
CAS Number1474-78-8
Synonym Ethyl (diethoxyphosphoryl)formate {LY} Ethyl (diethoxyphosphoryl)formate {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {} {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {} {} {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {} {} {} {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {} {} {} {} {} {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {} {} {} {} {} {} {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {} {} {} {} {} {} {} {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl (diethoxyphosphoryl)formate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl (diethoxyphosphoryl)formate
EC Number216-016-8
Beilstein Registry Number1781949
PubChem Substance ID65081
Reaxys-RN1781949
Chemical Name Translation甲膦酸三乙酯
LabNetwork Molecule IDLN01271284
InChIInChI=1S/C7H15O5P/c1-4-10-7(8)13(9,11-5-2)12-6-3/h4-6H2,1-3H3
Canonical SMILESCCOC(=O)P(=O)(OCC)OCC
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphonates/Phosphinates, Phosphorus Compounds
  • {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, EP Standards, EP Standards E - F, Pharmaceutical Standards, Pharmacopeia Standards

相关文献及参考

  • Claimed to have advantages over Diethyl­ carbonate, A12477 for the ɑ-carboethoxylation of ketones: Tetrahedron Lett., 2201 (1966).

安全信息

Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S37 Wear suitable gloves 戴适当手套；
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves
GHS Symbol
Signal word Warning
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P501a
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 下游产品:膦甲酸钠
  • Alfa Aesar:二乙氧基氧膦基甲酸乙酯,98% Ethyl diethoxyphosphinylformate, 98%(1474-78-8)
  • MSDS 信息:Ethyl diethoxyphosphinylformate(1474-78-8).msds
  • Sigma Aldrich:1474-78-8(sigmaaldrich)
  • MOL 文件:1474-78-8.mol
  • 甲膦酸三乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0400 二乙氧基膦酰基甲酸乙酯 Ethyl Diethoxyphosphinylformate 25G 331元 2010/05/25 B23367 二乙氧基氧膦基甲酸乙酯, 98% Ethyl diethoxyphosphinylformate, 98% 500g 2254元 2010/05/25 B23367 二乙氧基氧膦基甲酸乙酯, 98% Ethyl diethoxyphosphinylformate, 98% 25g 213元
  • TCI Shanghai:二乙氧基膦酰基甲酸乙酯 Ethyl Diethoxyphosphinylformate,>;98.0%(GC)(1474-78-8)
  • 图谱信息:甲膦酸三乙酯(1474-78-8)质谱(MS) 甲膦酸三乙酯(1474-78-8)核磁图( 13 CNMR) 甲膦酸三乙酯(1474-78-8)红外图谱(IR1) 甲膦酸三乙酯(1474-78-8)核磁图( 1 HNMR)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonates/Phosphinates - Phosphorus Compounds

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