Triethyl methanetricarboxylate, 98% 甲烷三羧酸三乙酯

CAS 6279-86-3 MFCD00009150

化学结构图

6279-86-3
SMILES: CCOC(=O)C(C(=O)OCC)C(=O)OCC

化学属性

Mol. FormulaC10H16O6
Mol. Weight232.23
Density1.095 g/mL at 25 °C(lit.)
Boiling Point281.3°C at 760 mmHg
Melting Point25-26°C
Refractive indexn20/D 1.424(lit.)
Flash Point>110°(230°F)
TSCANo
Solubility不溶

别名和识别编码

Chemical NameTriethyl methanetricarboxylate, 98%
MDL NumberMFCD00009150
CAS Number6279-86-3
EC Number228-477-2
Beilstein Registry Number2(4)2360
PubChem Substance ID80471
Synonym Triethyl methanetricarboxylate {LY} Triethyl methanetricarboxylate {} {LY} Triethyl methanetricarboxylate {} {} {LY} Triethyl methanetricarboxylate {} {} {} {LY} Triethyl methanetricarboxylate {} {} {} {} {LY} Triethyl methanetricarboxylate {} {} {} {} {} {LY} Triethyl methanetricarboxylate {} {} {} {} {} {} {LY} Triethyl methanetricarboxylate {} {} {} {} {} {} {} {LY} Triethyl methanetricarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl methanetricarboxylate {} {} {} {} {} {} {} {} {} {LY} Triethyl methanetricarboxylate {} {} {} {} {} {} {} {} {} {} {LY} Triethyl methanetricarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl methanetricarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl methanetricarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl methanetricarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl methanetrica
Reaxys-RN1793645
Chemical Name Translation甲烷三羧酸三乙酯
InChIKeyAGZPNUZBDCYTBB-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009105
InChIInChI=1S/C10H16O6/c1-4-14-8(11)7(9(12)15-5-2)10(13)16-6-3/h7H,4-6H2,1-3H3
Canonical SMILESCCOC(=O)C(C(=O)OCC)C(=O)OCC
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分类

  • {SNA} Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

相关文献及参考

  • Methanetricarboxylates have been used as "blocked" malonic esters, restricting reaction with alkyl halides to monoalkylation. The unwanted carboxyl group can be removed by treatment with Na alkoxide, LDA or BCl3: J. Org. Chem., 44, 3492 (1979). Adds to Michael acceptors under phase-transfer conditions, providing a useful 2-carbon chain extension method: Synthesis, 1125 (1990):
  • The tricarboxylate also undergoes free-radical addition to the terminal position of alkenes: Angew. Chem. Int. Ed., 5, 586 (1966). Arylation with electron-rich aromatics is promoted by Mn(III): Synthesis, 567 (1991).
  • Under similar conditions, diethyl malonate gives only 36% yield.

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MOL 文件:6279-86-3.mol
  • Acros Organics:Triethyl methanetricarboxylate, 98%(6279-86-3)
  • Alfa Aesar:甲烷三羧酸三乙酯,98% Triethyl methanetricarboxylate, 98%(6279-86-3)
  • 甲烷三羧酸三乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1481 甲烷三甲酸三乙酯 Triethyl Methanetricarboxylate 5G 325元 2014/06/02 T1481 甲烷三甲酸三乙酯 Triethyl Methanetricarboxylate 25G 993元 2010/06/21 139630250 甲烷三羧酸三乙酯 Triethyl methanetricarboxylate 98% 25 ML 1080元
  • MSDS 信息:Triethyl methanetricarboxylate (6279-86-3).msds
  • Sigma Aldrich:6279-86-3(sigmaaldrich)
  • TCI Shanghai:甲烷三甲酸三乙酯 Triethyl Methanetricarboxylate,>;95.0%(GC)(6279-86-3)
  • 海关编码:29171990

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C10 to C11 - Esters
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C10 to C11 - Esters
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters

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